Accumulation of Cu and Zn in discarded antifouling paint particles by the marine gastropod, Littorina littorea

The short-term (5 day) accumulation of Cu and Zn in different tissues of the marine gastropod, Littorina littorea, has been studied in the presence of 10 mg l⁻¹ of antifouling paint particles and pre- or simultaneously contaminated algal food (Ulva lactuca). Accumulation of Cu was observed in the head–foot, digestive gland–gonad complex and gills to extents dependent on how and when food was contaminated and administered. However, retention of Zn was only observed in the gills and only when L. littorea and U. lactuca were simultaneously exposed to paint particles. Relative to the alga, faecal material was highly enriched in Zn, suggesting that the animal is able to rapidly eliminate this metal, most likely through the formation and egestion of insoluble phosphate granules. Thus, L. littorea is a useful biomonitor of marine contamination by antifouling applications in respect of Cu but not Zn.     

The impact of scour processes on a smothered reef system in the Irish Sea

The Irish Sea, like many marine areas, is threatened by anthropogenic activities. In particular the Pisces Reef system, a series of smothered rocky reefs are subject to fishing pressures as a result of their position within a Nephrops norvegicus fishery. In an area of sediment deposition and retention the reefs modify the environment by increasing the energy of near-bottom currents which results in localised scouring. This is the first study to attempt to characterise and investigate the ecological functioning of the Pisces Reef system. A multidisciplinary approach was essential for accurate investigation of the area. To facilitate more effective management of the benthic habitats of the Reef system, this study integrates acoustic, seismic, grab sampling and video ground-truthing methods for benthic habitat discrimination. Orientation of the scour hollows also suggest that seabed features could be used to infer dominant flow regimes such as the Irish Sea Gyre. The data revealed significant geology–benthos relationships. A unique biotope was described for the reef habitat and it was demonstrated that scouring may influence community composition through disturbance mechanisms. This study provides preliminary information required for management of a unique habitat within a uniform region.     

Impact of dynamic feedbacks between sedimentation,sea-level rise,and biomass production on near-surface marsh stratigraphy and carbon accumulation

Salt marshes accrete both organic and inorganic sediments. Here we present analytical and numerical models of salt marsh sedimentation that, in addition to capturing inorganic processes, explicitly account for above- and belowground organic processes including root growth and decay of organic carbon. The analytical model is used to examine the bias introduced by organic processes into proxy records of sedimentation, namely ¹³⁷Cs and ²¹⁰Pb. We find that accretion rates estimated using ²¹⁰Pb will be less than accretion rates estimated using the ¹³⁷Cs peak in steadily accreting marshes if (1) carbon decay is significant and (2) data for ²¹⁰Pb extend below the ¹³⁷Cs peak. The numerical model expands upon the analytical model by including belowground processes such as compaction and root growth, and by explicitly tracking the evolution of aboveground biomass and its effect on sedimentation rates. Using the numerical model we explore how marsh stratigraphy responds to sediment supply and the rate of sea-level rise. It is calibrated and tested using an extensive data set of both marsh stratigraphy and measurements of vegetation dynamics in a Spartina alterniflora marsh in South Carolina, USA. We find that carbon accumulation in marshes is nonlinearly related to both the supply of inorganic sediment and the rate of sea-level rise; carbon accumulation increases with sea-level rise until sea-level rise reaches a critical rate that drowns the marsh vegetation and halts carbon accumulation. The model predicts that changes in carbon storage resulting from changing sediment supply or sea-level rise are strongly dependent on the background sediment supply: if inorganic sediment supply is reduced in an already sediment poor marsh the storage of organic carbon will increase to a far greater extent than in a sediment-rich marsh, provided that the rate of sea-level rise does not exceed a threshold. These results imply that altering sediment supply to estuaries (e.g., by damming upstream rivers or altering littoral sediment transport) could lead to significant changes in the carbon budgets of coastal salt marshes.     

The effect of chlorine and chlorine dioxide on pathogenic free‐living amoebae (PFLA) in simulated natural conditions: The presence of bacteria and organic matter

Bacteria and bovine faecal matter were introduced into cultures of pathogenic free‐living amoebae, with chlorine or chlorine dioxide. The bacteria and faeces were to simulate natural conditions for a more exacting test of disinfectant demand when compared to axenic conditions. Both chlorine and chlorine dioxide were effective disinfectants under all conditions tested. Axenically and monoxenically cultured amoebae were used, the latter exerted a greater disinfectant demand.     

The <Emphasis Type="Italic">Wind</Emphasis>/EPACT Proton Event Catalog (1996 – 2016)

We present the finalized catalog of solar energetic proton events detected by the Wind/EPACT instrument over the period 1996?–?2016. Onset times, peak times, peak proton intensity and onset-to-peak proton fluence are evaluated for the two available energy channels, at about 25 and 50 MeV. We describe the procedure utilized to identify the proton events and to relate them to their solar origin (in terms of flares and coronal mass ejections). The statistical relationships between the energetic protons and their origin (linear and partial correlation analysis) are reported and discussed in view of earlier findings. Finally, the different trends found in the first 8 years of Solar Cycles 23 and 24 are discussed.     

The Influence of the Solar Coronal Radiation on Coronal Plasma Structures,I: Determination of the Incident Coronal Radiation

Coronal structures receive radiation not only from the solar disc, but also from the corona. This height-dependent incident radiation plays a crucial role in the excitation and the ionisation of the illuminated plasma. The aim of this article is to present a method for computing the detailed incident radiation coming from the solar corona, which is perceived at a point located at an arbitrary height. The coronal radiation is calculated by integrating the radiation received at a point in the corona over all of the corona visible from this point. The emission from the corona at all wavelengths of interest is computed using atomic data provided by CHIANTI. We obtain the spectrum illuminating points located at varying heights in the corona at wavelengths between 100 and 912 Å when photons can ionise H or He atoms and ions in their ground states. As expected, individual spectral lines will contribute most at the height within the corona where the local temperature is closest to their formation temperature. As there are many spectral lines produced by many ions, the coronal intensity cannot be assumed to vary in the same way at all wavelengths and so must be calculated for each separate height that is to be considered. This code can be used to compute the spectrum from the corona illuminating a point at any given height above the solar surface. This brings a necessary improvement to models where an accurate determination of the excitation and ionisation states of coronal plasma structures is crucial.     

Factors influencing biodeposit production by the New Zealand freshwater mussel Echyridella menziesii

Laboratory experiments on the New Zealand freshwater mussel Echyridella menziesii were used to investigate the short-term effects (7–8 days) of food type on rates of biodeposition and benthic substrate respiration. Post-feeding biodeposition rates ranged from 0.34 to 1.52?mg?g^?1?h^?1 (mean?=?0.50?mg g^?1?h^?1) and were unaffected by the addition of toxin-producing Microcystis. Addition of suspended sediment (30?mg?L^?1) visibly altered substrate composition, and increased total and inorganic biodeposit production rates by 24–33% compared to mussels fed commercial phytoplankton stock. Biodeposition rates of mussels in lake bed substrates were 38% higher than those in silica sand for identical feeding regimes, suggesting that a significant proportion of material produced in this experiment could have been derived from feeding on organic matter in the lake bed sediments. Respiration rates were higher in treatments with Microcystis but were unaffected by the presence of mussels. This laboratory study suggests that biodeposition by E. menziesii is resilient to short-term exposure to Microcystis, and highlights the ability of mussels to alter benthic substrate composition by incorporating suspended sediment into substrates.     

The frequency of window damage caused by bolide airbursts: A quarter century case study

We have empirically estimated how often fireball shocks produce overpressure (∆P) at the ground sufficient to damage windows. Our study used a numerical entry model to estimate the energy deposition and shock production for a suite of 23 energetic fireballs reported by U.S. Government sensors over the last quarter century. For each of these events, we estimated the peak ∆P on the ground and the ground area above ∆P thresholds of 200 and 500 Pa where light and heavy window damage, respectively, are expected. Our results suggest that at the highest ∆P, it is the rare, large fireballs (such as the Chelyabinsk fireball) which dominate the long-term areal ground footprints for heavy window damage. The height at the fireball peak brightness and the fireball entry angle contribute to the variance in ground ∆P, with lower heights and shallower angles producing larger ground footprints and more potential damage. The effective threshold energy for fireballs to produce heavy window damage is ~5–10 kT; such fireballs occur globally once every 1–2 years. These largest annual bolide events, should they occur over a major urban center with large numbers of windows, can be expected to produce economically significant window damage. However, the mean frequency of heavy window damage (∆P above 500 Pa) from fireball shock waves occurring over urban areas is estimated to be approximately once every 5000 yr. Light window damage (∆P above 200 Pa) is expected every ~600 yr.     

Leachable particulate iron in the Columbia River,estuary, and near-field plume

This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons.