Trends In U.S. Hazardous Materials Transportation Spills

This paper examines historical and spatial trends in hazardous materials transportation spills from 1971 to 1991. While the number of spills Inc.reased steadily during the 1970s, peaking in 1978–1979, there has been a decline in frequency sInc.e then largely due to modifications in reporting. Monetary damages have the opposite temporal pattern, with major Inc.reases recorded from 1982 onward. Death and injury statistics are more variable. Spatially, accidents are more prevalent in the Rust Belt extending from the Northeast corridor westward to the Great Lakes states, as well as in the Southeast. The greatest potential risk to the public is found in smaller, more densely populated industrial states such as New Jersey, Delaware, and Maryland. The spatial distribution, however, has not changed. Potential risk sources (e.g., chemical industry, number of hazardous waste facilities, number of railroad miles) are the best predictors of hazmat Inc.ident frequency. Mitigation efforts (statewide regulatory and/or management policies) also help explain the variability in hazmat Inc.idents.     

The making of Stars 'R' Us!

The team behind a successful project to broaden the understanding of astrochemistry – Serena Viti, Wendy Brown, Martin McCoustra, Helen Fraser, Nigel Mason and Robert Massey – recount how they went about it and what benefits resulted.     

The geomorphic dynamics and environmental history of an upper deltaic floodplain tract in the Sacramento–San Joaquin Delta,California, USA

A multi‐proxy approach was used to examine the geomorphic dynamics and environmental history of an upper deltaic ?oodplain tract in the Sacramento–San Joaquin Delta, California. Three long cores were collected from the McCormack–Williamson Tract (MWT) and these cores were analyzed for bulk density, loss‐on‐ignition, ?ne (clay and silt) content, Al concentration, magnetic susceptibility, pollen, and charcoal. Radiocarbon dates obtained for the cores were converted into calendar years and an age–depth model was constructed. Long‐term vertical accretion and sedimentation rates were estimated from the age–depth model. Cross‐core relations show that coarse sediment generally accumulates more rapidly and has greater magnetic susceptibility compared to ?ne sediment. Percentage ?ne and LOI data show a strong linear relationship that indicates ?ooding is the primary mechanism for the deposition of particular organic matter on the ?oodplain and that landscape wash load has contributed a highly consistent fraction of persistent organic matter averaging 5·5 per cent to the site. Down‐core grain size pro?les show two hydrological domains in the cores, namely millennial ?ne–coarse ?uctuations superimposed on general up‐core ?ning. Coarse sediment is viewed as channel or near‐channel overbank deposits, whereas ?ne deposits are considered to be distal overbank ?ood deposits. The coarse–?ne ?uctuations are indicative of changing depositional settings as channels migrated laterally across MWT, whereas the upward ?ning trend re?ects a combination of self‐limiting overbank deposition as ?oodplain elevation increased and decreasing competence as sea‐level rise reduced ?ood‐pulse energy slopes. MWT has been cross‐cut and incised numerous times in the past, only to have the channels abandoned and subsequently ?lled by ?ne sediment. The channels around MWT attained their modern con?guration about 4000 years ago. MWT likely came under tidal in?uence at about 2500 cal BP. Wetlands have recently developed on MWT, but they are inorganic sediment dominated. Copyright © 2004 John Wiley & Sons, Ltd.     

Mineral dissolution in the Cape Cod aquifer, Massachusetts, USA: I . Reaction stoichiometry and impact of accessory feldspar and glauconite on strontium isotopes, solute concentrations, and REY distribution

To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between ⁸⁷Sr/⁸⁶Sr and Sr concentration is observed. At all depths, the ⁸⁷Sr/⁸⁶Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-⁸⁷Sr/⁸⁶Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-⁸⁷Sr/⁸⁶Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic ⁸⁷Sr because of its young Pleistocene age. The low ⁸⁷Sr/⁸⁶Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.     

Beryllium-10 in Australasian tektites: Constraints on the location of the source crater

By using accelerator mass spectrometry we have measured the ¹⁰Be concentrations of 86 Australasian tektites. Corrected to the time of tektite production ∼0.8 My ago, the ¹⁰Be concentrations (10⁶ atom/g) range from 59 for a layered tektite from Huai Sai, Thailand, to 280 for an australite from New South Wales, Australia. The average value is 143 ± 50. When tektites are sorted by country, their average measured ¹⁰Be concentrations increase slowly with increasing distance from Southeast Asia, the probable location of the tektite producing event, from 59 ± 9 for 6 layered tektites from Laos to 136 ± 20 for 20 splash-form tektites from Australia. The lowest ¹⁰Be concentrations for tektites fall on or within a contour centered off the shore of Vietnam, south of the Gulf of Tonkin (107°E; 17°N), but also encompassing two other locations in the area of northeastern Thailand previously proposed for the site of a single tektite-producing impact. The ¹⁰Be concentrations of layered tektites show only a weak anticorrelation (R ∼ −0.3) with the numbers of relict crystalline inclusions.Loosely consolidated, fine-grained terrestrial sediments or recently consolidated sedimentary rocks are the most likely precursor materials. Dilution of sediments with other kinds of rock raises problems in mixing and is not supported by petrographic data. Sedimentary columns that have the right range of ¹⁰Be concentrations occur off the coasts of places where sedimentation rates are high relative to those in the deep sea. A single impact into such a region, 15 to 300 m thick, could have propelled near-surface, high-¹⁰Be material farthest—to Australia—while keeping the deeper-lying, low-¹⁰Be layers closer to home. We do not rule out, however, other proposed mechanisms for tektite formation.     

Evidence for Neotethys rooted within the Vardar suture zone from the Voras Massif, northernmost Greece

Three conflicting models are currently proposed for the location and tectonic setting of the Eurasian continental margin and adjacent Tethys ocean in the Balkan region during Mesozoic–Early Tertiary time. Model 1 places the Eurasian margin within the Rhodope zone relatively close to the Moesian platform. A Tethyan oceanic basin was located to the south bordering a large “Serbo-Pelagonian” microcontinent. Model 2 correlates an integral “Serbo-Pelagonian” continental unit with the Eurasian margin and locates the Tethys further southwest. Model 3 envisages the Pelagonian zone and the Serbo-Macedonian zone as conjugate continental units separated by a Tethyan ocean that was sutured in Early Tertiary time to create the Vardar zone of northern Greece and former Yugoslavia. These published alternatives are tested in this paper based on a study of the tectono-stratigraphy of a completely exposed transect located in the Voras Mountains of northernmost Greece. The outcrop extends across the Vardar zone, from the Pelagonian zone in the west to the Serbo-Macedonian zone in the east.Within the Voras Massif, six east-dipping imbricate thrust sheets are recognised. Of these, Units 1–4 correlate with the regional Pelagonian zone in the west (and related Almopias sub-zone). By contrast, Units 5–6 show a contrasting tectono-stratigraphy and correlate with the Paikon Massif and the Serbo-Macedonian zone to the east. These units form a stack of thrust sheets, with Unit 1 at the base and Unit 6 at the top. Unstacking these thrust sheets places ophiolitic units between the Pelagonian zone and the Serbo-Macedonian zone, as in Model 3. Additional implications are, first, that the Paikon Massif cannot be seen as a window of Pelagonian basement, as in Model 1, and, secondly, Jurassic andesitic volcanics of the Paikon Massif locally preserve a gneissose continental basement, ruling out a recently suggested origin as an intra-oceanic arc.We envisage that the Almopias (Vardar) ocean rifted in Triassic time, followed by seafloor spreading. The Almopias ocean was consumed beneath the Serbo-Macedonian margin in Jurassic time, generating subduction-related arc volcanism in the Paikon Massif and related units. Ophiolites were emplaced onto the Pelagonian margin in the west and covered by Late Jurassic (pre-Kimmeridgian) conglomerates. Other ophiolitic rocks formed within the Vardar zone (Ano Garefi ophiolite, Unit 4) in latest Jurassic–Early Cretaceous time and were not deformed until Early Tertiary time. The Vardar zone finally sutured in the Early Tertiary creating the present imbricate thrust structure of the Voras Mountains.     

Estimating severity of liquefaction-induced damage near foundation

An empirical procedure for estimating the severity of liquefaction-induced ground damage at or near foundations of existing buildings is established. The procedure is based on an examination of 30 case histories from recent earthquakes. The data for these case histories consist of observations of the damage that resulted from liquefaction, and the subsurface soil conditions as revealed by cone penetration tests. These field observations are used to classify these cases into one of three damaging effect categories, ‘no damage’, ‘minor to moderate damage’, and ‘major damage’. The potential for liquefaction-induced ground failure at each site is calculated and expressed as the probability of ground failure. The relationship between the probability of ground failure and the damage class is established, which allows for the evaluation of the severity of liquefaction-induced ground damage at or near foundations. The procedure presented herein represents a significant attempt to address the issue of liquefaction effect. Caution must be exercised, however, when using the proposed model and procedure for estimating liquefaction damage severity, because they are developed based on limited number of case histories.     

Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

Use of in situ-produced Be in carbonate-rich environments: A first attempt

We have determined the production rate of in situ-produced ¹⁰Be in calcite through measurements of ¹⁰Be and ³⁶Cl concentrations in the same calcite samples and of ¹⁰Be concentrations in depth profiles of flint from the same erosional surface. This yields a ¹⁰Be production rate in calcite of 37.9 ± 6.0 at/g/yr at sea level and high latitude, approximately sixfold higher than production in the coexisting flint. We propose that this higher rate of production may be due to high production cross sections for C spallation by cosmic rays with energies below 50 MeV. These results also open the possibility of dating burial events in carbonate-rich environments by differential radioactive decay of ¹⁰Be and ³⁶Cl.