Thermal properties and coal rank in rocks and coal seams of the southern Sydney Basin,new South Wales: A palaeogeothermal explanation of coalification

Measurements of thermal conductivity on 106 disc specimens of rocks from 275 m of the Permian to Triassic section of the Southern Coalfield of the southern Sydney Basin have been carried out in an effort to explain a high rank gradient in the Permian coals. The samples came from six diamond drill holes north and west of Wollongong, although one hole only provided specimens of a syenitic sill (n = 17, mean thermal conductivity = 2.36 W/m°K, s.d. 0.03). When combined with previously published data on chip specimens, with which there is good agreement, from a further four drill holes the mean thermal conductivity for the late Permian and early Triassic sandstones and shales is 3.20 W/m°K.Heat generation by Permian volcanic rocks below the coal measures (from about 1 to 3 μW/m³), and by basement granitic rocks, appears to be consistent with previously reported heat flow for the southern Sydney Basin (about 80 mW/m²). This heat flow is a relatively high value for the east coast of Australia. Younger (Mesozoic and Tertiary) intrusive and extrusive igneous rocks produce local coal-rank anomalies, but do not appear to have any regional effect.The rank of coals above the Permian volcanic rocks appears to be little affected by the presence of the igneous rocks and the coal-rank decreases towards the major area of vulcanicity. Organic matter in sedimentary rocks interbedded with the volcanic rocks is of relatively high rank but it appears that these thermal effects do not extend more than about 100 m above the base of the coal measures. The area of high rank north and northwest of Wollongong seems likely to be a regional effect associated with a combination of high heat generation in basement and the Permian rocks, and high heat flow from the basement. Greater cover on the coal measures, together with an increase in the proportion of rocks of relatively low thermal conductivity in the cover, may also influence the rank in the Permian coal.     

Structural identification using linear models and earthquake records

The problem of determining linear models of structures from seismic response data is investigated using ideas from the theory of system identification. The approach is to determine the optimal estimates of the model parameters by minimizing a selected measure-of-fit between the responses of the structure and the model. Because earthquake records are normally available from only a small number of locations in a structure, and because of noise in the records, it is necessary in practice to estimate parameters of the dominant modes in the records, rather than the stiffness and damping matrices of the linear model. A new algorithm is developed to determine the optimal estimates of the modal parameters. After tests with simulated data, the method is applied to a multi-storey building using records from the 1971 San Fernando earthquake in California. New information is obtained concerning the properties of the lower modes of the building and the time-varying character of the equivalent linear parameters.     

A Study of Ozone Laminae Using Diabatic Trajectories, Contour Advection and Photochemical Trajectory Model Simulations.

In this paper, we show that the rate of ozone loss in both polar and mid-latitudes, derived from ozonesonde and satellite data, has almost the same vertical distribution (although opposite sense) to that of ozone laminae abundance. Ozone laminae appear in the lower stratosphere soon after the polar vortex is established in autumn, increase in number throughout the winter and reach a maximum abundance in late winter or spring. We indicate a possible coupling between mid-winter, sudden stratospheric warmings (when the vortex is weakened or disrupted) and the abundance of ozone laminae using a 23-year record of ozonesonde data from the World Ozone Data Center in Canada combined with monthly-mean January polar temperatures at 30 hPa.Results are presented from an experiment conducted during the winter of 1994/95, in phase II of the Second European Stratospheric And Mid-latitude Experiment (SESAME), in which 93 ozone-enhanced laminae of polar origin observed by ozonesondes at different time and locations are linked by diabatic trajectories, enabling them to be probed twice or more. It is shown that, in general, ozone concentrations inside laminae fall progressively with time, mixing irreversibly with mid-latitude air on time-scales of a few weeks. A particular set of laminae which advected across Europe during mid February 1995 are examined in detail. These laminae were observed almost simultaneously at seven ozonesonde stations, providing information on their spatial scales. The development of these laminae has been modelled using the Contour Advection algorithm of Norton (1994), adding support to the concept that many laminae are extrusions of vortex air. Finally, a photochemical trajectory model is used to show that, if the air in the laminae is chemically activated, it will impact on mid-latitude ozone concentrations. An estimate is made of the potential number of ozone molecules lost each winter via this mechanism.     

The azimuthal variation of teleseismic P-wave residuals for stations in southern California

A study of teleseismic P-residuals for 13 stations in southern California reveals that these vary systematically with the azimuth of the event; the residuals generally tend to be negative in the NW and SE quadrants. This effect is greatest in the north of the region: a maximum peak-to-peak variation of 1.3 sec with residuals as low as ?0.9 sec was observed at Isabella. The delays become less negative further south in the region, and at the southernmost station, Glamis, delays of up to +0.75 sec were observed to the west. The latter may be associated with velocity decreases in the active geothermal areas of the Imperial Valley. A simple model, consisting of a region some 175 km wide and 100 km thick at a depth of approximately 100 km in which a velocity increase of up to 0.45 km/sec occurs, is proposed to account for the observed variations. This region trends NW-SE approximately parallel to the North America-Pacific plate boundary. The proposed velocity changes are consistent with a pinching out of the low-velocity (partial melting) zone under the area, such as has been proposed to explain the low heat flow in the Sierra Nevada, and may be related to the presence of an ancient (～ 30 m.y.) subduction zone under southern California.     

Fatty acids and Pb-210 geochronology of a sediment core from Buzzards Bay,Massachusetts

Four sections of a Pb-210 dated core of 62 cm length from Buzzards Bay, Massachusetts, were analyzed for fatty acids. A comparison of fatty acids extracted by Soxhlet extraction (unbound fatty acids) with fatty acids extracted by subsequent saponification extraction of the same sample (bound fatty acids) showed the former did not undergo diagenetic loss any faster than the latter. However, compositional differences between bound and unbound fatty acids were apparent in the top section of 1–2 cm and were less apparent in the 54–58 cm section. At least 14% of the bound fatty acids are esterified to non-solvent extractable material. The net conversion of fatty acids to other compounds is 32 μ/g dry weight sediment over the first 30 yr after deposition.     

Seismic reflection coefficients from mantle fault zones

Summary. Several bright reflections from structures within the mantle can be seen on BIRPS' deep seismic reflection profiles. We have calculated apparent reflection coefficients for the brightest of these events and obtain values around 0.1. It is not possible to produce such large reflections by either compositional layering or seismic anisotropy if olivine and pyroxene are the only significant minerals in the mantle. These large reflections can be produced by a mafic layer or a partially hydrated layer within normal peridotite. The brightest reflections seem to be best explained as major faults or shear zones within the mantle.     

Assessing possible changes in flood frequency due to climate change in mid‐sized watersheds in New York State,USA

The frequency of flooding is often presumed to increase with climate change because of projected increases in rainfall intensities. In this paper, using 50‐plus years of historical discharge and meteorological data from three watersheds in different physiographic regions of New York State, USA, we find that annual maximum stream discharges are associated with 20% or less of the annual maximum rainfall events. Instead of rainfall events, approximately 20% of annual maximum stream discharges are associated with annual maximum snowmelt events while 60% of annual maximum discharges are associated with moderate rainfall amounts and very wet soil conditions. To explore the potential for changes in future flood risk, we employed a compound frequency distribution that assumes annual maximum discharges can be modelled by combining the cumulative distribution functions of discharges resulting from annual maximum rainfall, annual maximum snowmelt, and occurrences of moderate rain on wet soils. Basing on a compound frequency distribution comprised of univariate general extreme value (GEV) and gamma distributions, we found that a hypothetical 20% increase in the magnitude of rainfall‐related stream discharge results in little change in 96th percentile annual maximum discharge. For the 99th percentile discharge, two waterbodies in our study had a 10% or less increase in annual maximum discharge when annual maximum rainfall‐related discharges increased 20% while the third waterbody had a 16% increase in annual maximum discharges. Additionally, in some cases, annual maximum discharges could be offset by a reduction in the discharge resulting from annual maximum snowmelt events. While only intended as a heuristic tool to explore the interaction among different flood‐causing mechanisms, use of a compound flood frequency distribution suggests a case can be made that not all waterbodies in humid, cold regions will see extensive changes in flooding due to increased rainfall intensities. Copyright © 2011 John Wiley & Sons, Ltd.     

Correspondence analysis of water quality data: Implications for fauna deaths at Stillwater Lakes, Nevada

Over the last 2 years, more than seven million fish and 16,000 birds have died from drought-induced disease and suspected poisoning at Stillwater Lakes, Nevada. Correspondence analysis of water samples taken in June and September 1986, from lakes and reservoirs near Stillwater Lakes and four background lakes/reservoirs (not associated with fauna disease and death), is attempted to investigate the correlation among sites associated with fauna deaths. This analysis identifies high correlation between some Stillwater Lakes sites and boron. A correlation between boron and arsenic is also identified. Leaching and transport of toxins to the Stillwater Lakes system is one hypothesis to explain the wildlife deaths. Other hypotheses include the direct introduction of toxins by groundwater associated with geothermal activity. A natural cause for the wildlife deaths is also suggested, a cause not associated with the introduction of toxins.     

Numerical simulation of the circulation within the Perth Submarine Canyon,Western Australia

Surface and sub-surface currents along the ocean boundary of Western Australia were simulated using Regional Ocean Modelling System (ROMS) to examine the circulation within the Perth Canyon. Two major current systems influenced the circulation within the canyon: (1) The Leeuwin current interacted weakly with the canyon as the majority of the canyon was below the depth of the Leeuwin current and (2) Leeuwin undercurrent interacted strongly with the canyon, forming eddies within the canyon at depths of 400–800 m. The results indicated that within the canyon, the current patterns changed continuously although there were some repeated patterns. Recurrent eddies produced regions where upwelling or downwelling dominated during the model runs. Deep upwelling was stronger within the canyon than elsewhere on the shelf, but vertical transport in the upper ocean was strong everywhere when wind forcing was applied. Upwelling alone appeared to be insufficient to transport nutrients to the euphotic zone because the canyon rims were deep. Increased upwelling, combined with entrapment within eddies and strong upwelling-favourable winds, which could assist mixing, may account for the high productivity attributed to the canyon. The Leeuwin current is otherwise a strong barrier to the upwelling of nutrients.     

Tomography: A window on the role of sulfur in the structure of micrometeorites

Abstract– To determine the role played by sulfides in the formation of vesicles and FeNi metal beads, we mapped the locations and tabulated the numbers of sulfides, metal beads, and vesicles in 1583 sectioned micrometeorites (MMs) using conventional microscopy and in 190 whole MMs using synchrotron computed microtomography (SCMT). Both the section and the SCMT images show that sulfides melt, coalesce, and migrate to the MMs surface. The decomposition of sulfides may occur during all these stages. Given the sulfide morphologies and compositions that we see in section, we think the breakdown of Ni sulfides produces the FeNi beads. The SCMT images show that metal beads are common in melted MMs, >50% have them. Vesicles in porphyritic and scoriaceous MMs are also probably formed as sulfides decompose. Not only do sulfides abut the vesicles but also the temperatures at which sulfides decompose overlap those at which MM surfaces first melt and temporarily seal, suggesting that S gases could produce most of these vesicles. As the vesicle shapes and patterns of distribution differ among MM classes, tomography can be used to nondestructively screen for specific types of MMs. Tomography is a powerful tool for visualizing the three‐dimensional distribution of metal beads, sulfides, mean densities, and vesicles in MMs.