The iron record of asteroidal processes in carbonaceous chondrites

The valence of iron has been used in terrestrial studies to trace the hydrolysis of primary silicate rocks. Here, we use a similar approach to characterize the secondary processes, namely thermal metamorphism and aqueous alteration, that have affected carbonaceous chondrites. X‐ray absorption near‐edge structure spectroscopy at the Fe‐K‐edge was performed on a series of 36 CM, 9 CR, 10 CV, and 2 CI chondrites. While previous studies have focused on the relative distribution of Fe⁰ with respect to oxidized iron (Fe_ox = Fe²⁺ + Fe³⁺) or the iron distribution in some specific phases (e.g., Urey–Craig diagram; Urey and Craig 1953), our measurements enable us to assess the fractions of iron in each of its three oxidation states: Fe⁰, Fe²⁺, and Fe³⁺. Among the four carbonaceous chondrites groups studied, a correlation between the iron oxidation index (IOI = [2(Fe²⁺) + 3(Fe³⁺)]/[Fe_TOT]) and the hydrogen content is observed. However, within the CM group, for which a progressive alteration sequence has been defined, a conversion of Fe³⁺ to Fe²⁺ is observed with increasing degree of aqueous alteration. This reduction of iron can be explained by an evolution in the mineralogy of the secondary phases. In the case of the few CM chondrites that experienced some thermal metamorphism, in addition to aqueous alteration, a redox memory of the aqueous alteration is present: a significant fraction of Fe³⁺ is present, together with Fe²⁺ and sometimes Fe⁰. From our data set, the CR chondrites show a wider range of IOI from 1.5 to 2.5. In all considered CR chondrites, the three oxidation states of iron coexist. Even in the least‐altered CR chondrites, the fraction of Fe³⁺ can be high (30% for MET 00426). This observation confirms that oxidized iron has been integrated during formation of fine‐grained amorphous material in the matrix (Le Guillou and Brearley 2014; Le Guillou et al. 2015; Hopp and Vollmer 2018). Last, the IOI of CV chondrites does not reflect the reduced/oxidized classification based on metal and magnetite proportions, but is strongly correlated with petrographic types. The valence of iron in CV chondrites therefore appears to be most closely related to thermal history, rather than aqueous alteration, even if these processes can occur together (Krot et al. 2004; Brearley and Krot 2013).     

Particulate organic matter and ballast fluxes measured using time-series and settling velocity sediment traps in the northwestern Mediterranean Sea

Prompted by recent data analyses suggesting that the flux of particulate organic carbon sinking into deep waters is determined by fluxes of mineral ballasts, we undertook a study of the relationships among organic matter (OM), calcium carbonate, opal, lithogenic material, and excess aluminum fluxes as part of the MedFlux project. We measured fluxes of particulate components during Spring and Summer of 2003, and Spring of 2005, using a swimmer-excluding sediment trap design capable of measuring fluxes both in a time-series (TS) mode and in a configuration for obtaining particle settling velocity (SV) profiles. On the basis of these studies, we suggest that distinct OM–ballast associations observed in particles sinking at a depth of 200 m imply that the mechanistic basis of the organic matter–ballast association is set in the upper water column above the Twilight Zone, and that the importance of different ballast types follows the seasonal succession of phytoplankton. As in other studies, carbonate appears to enhance the flux of organic matter over opal. Particles must be at least half organic matter before their settling velocity is affected by ballast concentration. This lack of change in ballast composition with SV in particles with <40% OM content suggests that particle SV reaches a maximum because of the increasing importance of inertial drag. Relative amounts of OM and opal decrease with depth due to decomposition and dissolution; carbonates and lithogenic material contribute about the same amount to total mass, or increase slightly, throughout the water column. The high proportion of excess Al cannot be explained by its incorporation into diatom opal or reverse weathering, so Al is most likely adsorbed to particulate oxides. On shorter time scales, dust appears to increase particle flux through its role in aggregation rather than by nutrient inputs enhancing productivity. We suggest that the role of dust as a catalyst in particle formation may be a central mechanism in flux formation in this region, particularly when zooplankton fecal pellet production is low.     

Functional composition, but not richness, affected the performance of sessile suspension-feeding assemblages

The efficiency by which communities capture limiting resources may be related to the number of species or functional types competing therein. This is because species use different resources (i.e. complementarity effect) or because species-rich communities include species with extreme functional traits (positive selection effect). We conducted two manipulative studies to separate the effects of functional richness and functional identity on the feeding efficiency (i.e. filtration rate) of suspension-feeding invertebrates growing on vertical surfaces. In addition, one experiment tested whether the density of organisms influences the effect of functional diversity. Monocultures and complete mixtures of functional types were fed with a solution of microalgae of different sizes (6 μm–40 μm). Experiments conducted at two locations, Helgoland and Plymouth, showed that functional identity had far larger effects on filtration rate than richness. Mixtures did not outperform the average monoculture or the best-performing monoculture and this pattern was independent on density. The high efficiency of one of the functional types in consuming most microalgae could have minimised the resource complementarity. The loss or gain of particular species may therefore have a stronger impact on the functioning of epibenthic communities than richness per se.     

Fine structure of the magnetic field in M31

Abstract

The detailed magnetic field structure of M31, as deduced from radio polarization measurements, is analyzed. The field closely follows a dust lane parallel to the most conspicuous optical spiral arm, but also exhibits three-dimensional arc-like deviations from the otherwise axisymmetric configuration.     

Developing Data-Rich Video of Surface Water–Groundwater Interactions for Public Engagement

Communication of hydrologic data to the public can be improved by connecting data to the places they represent. In our example of data communication, we coupled hydrologic data with simultaneously collected video as both a scientific and public engagement tool. This note presents a method for collecting spatially and temporally dense datasets of water-quality and geophysical data on small streams and lakes, and for displaying the data in a user-friendly format using commercially available software. With this method, multiple instruments are mounted on a canoe and a controlled survey float is carried out to collect data. The data stream is georeferenced and logged using an Arduino microcontroller to provide detailed information about spatial variability. We employed these continuous data-collection methods at small streams and lakes across Wisconsin, USA. Comparison of stream-float sensor data to lab reported data, data collected by alternative sensors, and previously collected data in our study areas indicates that the low-cost temperature, electrical conductivity, pH, and dissolved oxygen sensors performed well. GoPro cameras recorded video throughout the duration of data collection. Our established water-quality and geophysical data collection methods are inexpensive, fast, and reliable, which qualify them as excellent tools for fine-scale spatial understanding of stream and lake habitats' health. Data-rich video connects point measurements of water properties to the appearance of the native environment. This method helps improve our understanding of groundwater and surface water interactions in complex hydrogeologic systems, enhance communication amongst stakeholders, and provide context when monitoring and managing sensitive habitats.     

Spring flux as an indicator of source geomorphology,substrata, and temperature conditions in springs

Hydrogeology Journal - Spring flux (m/s), defined as spring flow (m3/s) divided by the area over which groundwater emerges (m2) at a spring, provides a meaningful way to distinguish between...     

Global variations in regolith properties on asteroid Vesta from Dawn's low‐altitude mapping orbit

We investigate the depth, variability, and history of regolith on asteroid Vesta using data from the Dawn spacecraft. High‐resolution (15–20 m pixel^?1) Framing Camera images are used to assess the presence of morphologic indicators of a shallow regolith, including the presence of blocks in crater ejecta, spur‐and‐gully–type features in crater walls, and the retention of small (<300 m) impact craters. Such features reveal that the broad, regional heterogeneities observed on Vesta in terms of albedo and surface composition extend to the physical properties of the upper ~1 km of the surface. Regions of thin regolith are found within the Rheasilvia basin and at equatorial latitudes from ~0–90°E and ~260–360°E. Craters in these areas that appear to excavate material from beneath the regolith have more diogenitic (Rheasilvia, 0–90°E) and cumulate eucrite (260–360°E) compositions. A region of especially thick regolith, where depths generally exceed 1 km, is found from ~100–240°E and corresponds to heavily cratered, low‐albedo surface with a basaltic eucrite composition enriched in carbonaceous chondrite material. The presence of a thick regolith in this area supports the idea that this is an ancient terrain that has accumulated a larger component of exogenic debris. We find evidence for the gardening of crater ejecta toward more howarditic compositions, consistent with regolith mixing being the dominant form of “weathering” on Vesta.