A modified light transmission visualization method for DNAPL saturation measurements in 2-D models

In this research, a light transmission visualization (LTV) method was used to quantify dense non-aqueous phase liquids (DNAPL) saturation in two-dimensional (2-D), two fluid phase systems. The method is an expansion of earlier LTV methods and takes into account both absorption and refraction light theories. Based on this method, DNAPL and water saturations can rapidly be obtained point wise across sand-packed 2-D flow chambers without the need to develop a calibration curve. A single point calibration step is, however, needed when dyed DNAPL is used to account for the change in the transmission factor at the dyed DNAPL–water interface. The method was applied to measure, for the first time, undyed DNAPL saturation in small 2-D chambers. Known amounts of DNAPL, modeled by tetrachloroethylene (PCE), were added to the chamber and these amounts were compared to results obtained by this LTV method. Strong correlation existed between results obtained based on this method and the known PCE amounts with an R² value of 0.993. Similar experiments conducted using dyed PCE showed a stronger correlation between results obtained by this LTV method and the known amounts of dyed PCE added to the chamber with an R² value of 0.999. The method was also used to measure dyed PCE saturation in a large 2-D model following sparging experiments. Results obtained from image analyses following each sparging event were compared to results obtained by two independent techniques, namely gas chromatography–mass spectrometry (GC/MS) analyses and carbon column extraction. There was a good agreement between the results obtained by this LTV method and those obtained by the two independent techniques when experiments were carried out under stable light source conditions and errors in mass balance were minor. The method presented here can be expanded to measure fluid contents in three fluid phase systems and provide a non-destructive, non-intrusive tool to investigate changes in DNAPL architecture and flow characteristics in laboratory experiments.     

Debris-flow release processes investigated through the analysis of multi-temporal LiDAR datasets in north-western Iceland

Debris flows are fast-moving gravity flows of poorly sorted rock and soil, mixed and saturated with water. Debris-flow initiation has been studied using empirical and experimental modelling, but the geomorphic changes, indicative of different triggering processes, are difficult to constrain with field observations only. We identify signatures to distinguish two different debris-flow release styles by integrating high-resolution multi-temporal remote sensing datasets and morphometric analysis. We analyse debris flows sourced above the town of Ísafjörður (Iceland). Two debris-flow triggering processes were previously hypothesised for this site: (i) slope failure, characterised by landslides evolving into debris flows; and (ii) the fire-hose effect, in which debris accumulated in pre-existing, steep-sided bedrock passages is transported by a surge of water. It is unknown which process dominates and determines the local risk. To investigate this question, we compare airborne LiDAR elevation models and aerial photographs collected in 2007 with similar data from 2013. We find that two new debris-flow tracks were created by slope failures. These are characterised by steep sliding surfaces and lateral leveed channels. Slope failure also occurred in two large, recently active tracks, creating the preparatory conditions for the fire-hose effect to mobilise existing debris. These tracks show alternating zones of fill and scour along their length, and debris stored below the source-area at rest angles >35°. Our approach allows us to identify and quantify the morphological changes produced by slope failure release process, which generated the preparatory conditions for the fire-hose effect. As debris flows are rarely observed in action and morphological changes induced by them are difficult to detect and monitor, the same approach could be applied to other landscapes to understand debris-flow initiation in the absence of other monitoring information, and can improve the identification of zones at risk in inhabited areas near hillslopes with potential for debris flows. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

'Our shared responsibility': participation in ecological projects as a means of empowering communities to contribute to coastal management processes

The objective of this project was to empower people of Blyth Valley in Northumberland (northeast England) to contribute to the management of their coastal heritage. A group of volunteers, the Links Conservation Group, working in collaboration with the environmental managers (Blyth Valley Borough Council), scientists, local specialists and other volunteers, surveyed the biodiversity, social, cultural and industrial history and profiles of the dunes, as well as their perceived value to local residents. The Group used this information to develop management plans for the dunes. The recommendations have contributed to planning processes at three levels: (i) national coastal management plans; (ii) regional plans; and (iii) plans for further action at the local community level.     

Long-Term Tsunami Data Archive Supports Tsunami Forecast, Warning, Research, and Mitigation

In response to the 2004 Indian Ocean tsunami, the United States began a careful review and strengthening of its programs aimed at reducing the consequences of tsunamis. Several reports and calls to action were drafted, including the Tsunami Warning and Education Act (Public Law 109–424) signed into law by the President in December 2006. NOAA’s National Geophysical Data Center (NGDC) and co-located World Data Center for Geophysics and Marine Geology (WDC-GMG) maintain a national and international tsunami data archive that fulfills part of the P.L. 109-424. The NGDC/WDC-GMG long-term tsunami data archive has expanded from the original global historical event databases and damage photo collection, to include tsunami deposits, coastal water-level data, DART? buoy data, and high-resolution coastal DEMs. These data are used to validate models, provide guidance to warning centers, develop tsunami hazard assessments, and educate the public about the risks from tsunamis. In this paper we discuss current steps and future actions to be taken by NGDC/WDC-GMG to support tsunami hazard mitigation research, to ultimately help save lives and improve the resiliency of coastal communities.     

Effects of two alternative representations of ground‐motion uncertainty on probabilistic seismic demand assessment of structures

A probabilistic representation of the entire ground‐motion time history can be constructed based on a stochastic model that depends on seismic source parameters. An advanced stochastic simulation scheme known as Subset Simulation can then be used to efficiently compute the small failure probabilities corresponding to structural limit states. Alternatively, the uncertainty in the ground motion can be represented by adopting a parameter (or a vector of parameters) known as the intensity measure (IM) that captures the dominant features of the ground shaking. Structural performance assessment based on this representation can be broken down into two parts, namely, the structure‐specific part requiring performance assessment for a given value of the IM, and the site‐specific part requiring estimation of the likelihood that ground shaking with a given value of the IM takes place. The effect of these two alternative representations of ground‐motion uncertainty on probabilistic structural response is investigated for two hazard cases. In the first case, these two approaches are compared for a scenario earthquake event with a given magnitude and distance. In the second case, they are compared using a probabilistic seismic hazard analysis to take into account the potential of the surrounding faults to produce events with a range of possible magnitudes and distances. The two approaches are compared on the basis of the probabilistic response of an existing reinforced‐concrete frame structure, which is known to have suffered shear failure in its columns during the 1994 Northridge Earthquake in Los Angeles, California. Copyright © 2007 John Wiley & Sons, Ltd.     

Pantasma: Evidence for a Pleistocene circa 14 km diameter impact crater in Nicaragua

The circa 14 km diameter Pantasma circular structure in Oligocene volcanic rocks in Nicaragua is here studied for the first time to understand its origin. Geomorphology, field mapping, and petrographic and geochemical investigations all are consistent with an impact origin for the Pantasma structure. Observations supporting an impact origin include outward‐dipping volcanic flows, the presence of former melt‐bearing polymict breccia, impact glass (with lechatelierite and low H₂O, <300 ppm), and also a possible ejecta layer containing Paleozoic rocks which originated from hundreds of meters below the surface. Diagnostic evidence for impact is provided by detection in impact glass of the former presence of reidite in granular zircon as well as coesite, and extraterrestrial ε⁵⁴Cr value in polymict breccia. Two ⁴⁰Ar/³⁹Ar plateau ages with a combined weighted mean age of 815 ± 11 ka (2 σ; P = 0.17) were obtained on impact glass. This age is consistent with geomorphological data and erosion modeling, which all suggest a rather young crater. Pantasma is only the fourth exposed crater >10 km found in the Americas south of N30 latitude, and provides further evidence that a significant number of impact craters may remain to be discovered in Central and South America.     

Simulated asteroid materials based on carbonaceous chondrite mineralogies

A set of high‐fidelity simulated asteroid materials, or simulants, was developed based on the mineralogy of carbonaceous chondrite meteorites. Three varieties of simulant were developed based on CI1 chondrites (typified by Orgueil), CM2 chondrites (typified by Murchison), and CR2/3 chondrites (multiple samples). The simulants were designed to replicate the mineralogy and physical properties of the corresponding meteorites and anticipated asteroid surface materials as closely as is reasonably possible for bulk amounts. The simulants can be made in different physical forms ranging from larger cobbles to fine‐grained regolith. We analyzed simulant prototypes using scanning electron microscopy, X‐ray fluorescence, reflectance spectroscopy at ambient conditions and in vacuum, thermal emission spectroscopy in a simulated asteroid environment chamber, and combined thermogravimetry and evolved gas analysis. Most measured properties compare favorably to the reference meteorites and therefore to predicted volatile‐rich asteroid surface materials, including boulders, cobbles, and fine‐grained soils. However, there were also discrepancies, and mistakes were made in the original mineral formulations that will be updated in the future. The asteroid simulants are available to the community from the nonprofit Exolith Lab at UCF, and the mineral recipes are freely published for other groups to reproduce and modify as they see fit.     

Water abundance in the Tagish Lake meteorite from TGA and IR spectroscopy: Evaluation of aqueous alteration

Here, we evaluate the extent of aqueous alteration among five pristine specimens of the ungrouped Tagish Lake carbonaceous chondrite (TL5b, TL11h, TL11i, TL4, and TL10a) using thermogravimetric analysis (TGA) and infrared (IR) transmission spectroscopy. Both TGA and IR spectroscopy have proven to be reliable methods for determining the extent of aqueous alteration among different carbonaceous chondrites, in particular the CM chondrites (e.g., Garenne et al. 2014), with which Tagish Lake shares some affinities. Using these two methods, our goal is to incorporate TL4 and TL10a into the known alteration sequence of TL5b < TL11h < TL11i (Herd et al. 2011; Blinova et al. 2014a). This study highlights the compositional variability of the Tagish Lake specimens, which we ascribe to its brecciated nature. Our TGA and IR spectroscopy results are congruent with the reported alteration sequence, allowing us to introduce the TL4 and TL10a specimens in the following order: TL4 < TL5b ≤ TL10a < TL 11h < TL11i. Notably, these two specimens appear to be similar to the least altered lithologies previously reported, and the alteration of Tagish Lake is similar to that experienced by lesser altered members of the CM chondrites (>CM1.6). Based on these findings, Tagish Lake could be considered a 1.6–2.0 ungrouped carbonaceous chondrite. Visible and near‐IR reflectance measurements of Tagish Lake were also acquired in this study to revisit the Tagish Lake parent body connection. While other studies have paired Tagish Lake with D‐ and T‐type asteroid parent bodies, the reflectance spectra acquired in this study are variable among the different Tagish Lake specimens in relation to their alteration sequences; results match with spectra characteristic of C‐, X‐, Xc‐, and D‐type asteroids. The heterogeneity of Tagish Lake coupled with its low albedo makes the parent body connection a challenge.     

Isotopic fractionation of zinc in tektites

Tektites are terrestrial natural glasses produced during a hypervelocity impact of an extraterrestrial projectile onto the Earth's surface. The similarity between the chemical and isotopic compositions of tektites and terrestrial upper continental crust implies that the tektites formed by fusion of such target rock. Tektites are among the driest rocks on Earth. Although volatilization at high temperature may have caused this extreme dryness, the exact mechanism of the water loss and the behavior of other volatile species during tektite formation are still debated. Volatilization can fractionate isotopes, therefore, comparing the isotope composition of volatile elements in tektites with that of their source rocks may help to understand the physical conditions during tektite formation.For this study, we have measured the Zn isotopic composition of 20 tektites from four different strewn fields. Almost all samples are enriched in heavy isotopes of Zn compared to the upper continental crust. On average, the different groups of tektites are isotopically distinct (listed from the isotopically lightest to the heaviest): Muong-Nong type indochinites (δ^66/64Zn = 0.61 ± 0.30‰); North American bediasites (δ^66/64Zn = 1.61 ± 0.49‰); Ivory Coast tektites (δ^66/64Zn = 1.66 ± 0.18‰); the Australasian tektites (others than the Muong Nong-type indochinites) (δ^66/64Zn = 1.84 ± 0.42‰); and Central European moldavites (δ^66/64Zn = 2.04 ± 0.19‰). These results are contrasted with a narrow range of δ^66/64Zn = 0–0.7‰ for a diverse spectrum of upper continental crust materials.The elemental abundance of Zn is negatively correlated with δ^66/64Zn, which may reflect that isotopic fractionation occurred by evaporation during the heating event upon tektite formation. Simple Rayleigh distillation predicts isotopic fractionations much larger than what is actually observed, therefore, such a model cannot account for the observed Zn isotope fractionation in tektites. We have developed a more realistic model of evaporation of Zn from a molten sphere: during its hypervelocity trajectory, the molten surface of the tektite will be entrained by viscous coupling with air that will then induce a velocity field inside the molten sphere. This velocity field induces significant radial chemical mixing within the tektite that accelerates the evaporation process. Our model, albeit parameter dependent, shows that both the isotopic composition and the chemical abundances measured in tektites can be produced by evaporation in a diffusion-limited regime.