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81.
82.
We report the detection of HCN on Jupiter. Three R-branch lines of the ν2 fundamental of HCN near 13.5 μm were observed in absorption, from which the HCN column density is inferred to be 5 × 10?3 cm-am with an uncertainty of a factor of 2. If emission from the stratosphere exists, then the derived column density is only a lowe limit. We suggest that the Jovian HCN most likely originates from the photolysis of CH4 and NH3 in the lower stratosphere and upper troposphere. In addition, an upper limit of 2.5 × 10?2 cm-am was established for the column density of HCN on Saturn. 相似文献
83.
Sinkhole collapse in the area of Maryland Interstate 70 (I-70) and nearby roadways south of Frederick, Maryland, has been posing a threat to the safety of the highway operation as well as other structures. The occurrence of sinkholes is associated with intensive land development. However, the geological conditions that have been developing over the past 200 million years in the Frederick Valley control the locations of the sinkholes. Within an area of approximately 8 km2, 138 sinkholes are recorded and their spatial distribution is irregular, but clustered. The clustering indicates the existence of an interaction between the sinkholes. The point pattern of sinkholes is considered to be a sample of a Gibbsian point process from which the hard-core Strauss Model is developed. The radius of influence is calculated for the recorded sinkholes which are most likely to occur within 30 m of an existing sinkhole. The stochastic analysis of the existing sinkholes is biased toward the areas with intensive land use. This bias is adjusted by considering (1) topography, (2) proximity to topographic depressions, (3) interpreted rock formation, (4) soil type, (5) geophysical anomalies, (6) proximity to geologic structures, and (7) thickness of overburden. Based on the properties of each factor, a scoring system is developed and the average relative risk score for individual 30-m segments of the study area is calculated. The areas designated by higher risk levels would have greater risk of a sinkhole collapse than the areas designated by lower risk levels. This risk assessment approach can be updated as more information becomes available. 相似文献
84.
Sinkhole collapse is one of the main limitations on the development of karst areas, especially where bedrock is covered by
unconsolidated material. Studies of sinkhole formation have shown that sinkholes are likely to develop in cutter (enlarged
joint) zones as a result of subterranean erosion by flowing groundwater. Because of the irregular distribution of pinnacles
and cutters on the bedrock surface, uncertainties arise when "hit-or-miss" borehole drilling is used to locate potential collapse
sites. A high-resolution geophysical technique capable of depicting the details of the bedrock surface is essential for guiding
the drilling program. Dipole-dipole electrical resistivity tomography (ERT) was used to map the bedrock surface at a site
in southern Indiana where limestone is covered by about 9 m of clayey soils. Forty-nine transects were conducted over an area
of approximately 42,037 m2. The electrode spacing was 3 m. The length of the transects varied from 81 to 249 m. The tomographs were interpreted with
the aid of soil borings. The repeatability of ERT was evaluated by comparing the rock surface elevations interpreted from
pairs of transects where they crossed each other. The average difference was 2.4 m, with a maximum of 10 m. The discrepancy
between interpreted bedrock-surface elevations for a transect intersection may be caused by variations in the subsurface geology
normal to the transect. Averaging the elevation data interpreted from different transects improved the ERT results. A bedrock
surface map was generated using only the averaged elevation data at the transect junctions. The accuracy of the map was further
evaluated using data from four exploratory boreholes. The average difference between interpreted and actual bedrock surface-elevations
was less than 0.4 m. The map shows two large troughs in the limestone surface: one coinciding with an existing sinkhole basin,
while the other is in alignment with a small topographic valley. Because sinkholes were observed at the same elevation interval
in similar valleys in the vicinity, the delineated trough may have implications for future land use at the site.
Received: 4 January 1999 · Accepted: 8 March 1999 相似文献
85.
Aaron J. Beck Yoko Tsukamoto Antonio Tovar-Sanchez Miguel Huerta-Diaz Henry J. Bokuniewicz Sergio A. Sañudo-Wilhelmy 《Applied Geochemistry》2007
Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO3, PO4, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO4 and NO3 (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 102– 8.2 × 103 μmol d−1). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 103 μmol d−1 (inland, freshwater well) vs. 2.1 × 105 μmol d−1(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean. 相似文献
86.
Susan Ringrose Cornelis Vanderpost Wilma Matheson 《Applied geography (Sevenoaks, England)》1998,18(4):331-354
The critical need to consider all options in the search for groundwater in semi-arid areas has promoted work on the possible association of near-surface groundwater and vegetation characteristics using a combination of remote-sensing data and geographic information systems (GIS) techniques. Two vegetative criteria (dense woody cover and abundance of deep-rooting species) are identified as being indicative of near-surface groundwater, and their spatial distribution is tested against the location of aquifers in southeast Botswana. Vegetative criteria classes were combined in a GIS environment with the distribution of geomorphic units and bedrock geology to determine the degree of coincidence with assumed or known aquifers. Results indicate that the distribution of dense woody vegetation as mapped from Thematic Mapper imagery has some potential in identifying especially surficial but also bedrock near-surface groundwater sources in mostly naturally vegetated semi-arid areas. Dense woody cover classes tend to select aquifers in topographically higher areas while classes comprising some deep-rooting species tend to select low-lying aquifers such as those occurring in fossil valleys. Deep-rooting species, however, are less successful as a vegetative criterion. Although various technical refinements are suggested, this work shows that vegetative criteria mapping can however be used in conjunction with conventional geological/geophysical techniques to enhance the prospects for groundwater location in relatively undisturbed semi-arid areas. 相似文献
87.
Holocene sediments in Lake Winnipeg are expressed in the lower Lake Agassiz sequence which is unconformably overlain by the Lake Winnipeg sequence. Nine sites, covering the North and South basins and the connecting Narrows, were selected for analysis of Holocene changes in thecamoebian faunae. Only the Lake Winnipeg sequence contains thecamoebians. This study indicates that biologic productivity and consequently the type of organic material in the sediments is the main control on thecamoebian taxa in Lake Winnipeg. Other factors controlling the distribution of thecamoebians are water chemistry and turbidity. Inorganic sediment geochemistry and water temperature do not appear to significantly influence the thecamoebian fauna of Lake Winnipeg. Variations in the abundance of key thecamoebian species along a north-south transect divide Lake Winnipeg into three distinct areas. The North Basin has remained relatively unchanged since the retreat of Lake Agassiz as indicated by the domination of Difflugia manicata throughout its history. This species appears to prefer Cyanophyta and diatoms as its food source. In the Narrows harsh conditions created by turbid waters and lack of algal food taxa result in Centropyxis aculeata replacing Difflugia manicata as the dominant species. In the South Basin three thecamoebian assemblages are recognized. Cucurbitella tricuspis, indicative of eutrophic conditions, dominates the most recent sediments of the South Basin. The underlying sediments are characterized by Difflugia globulus. In Lake Winnipeg this species is not a cold climate (arctic) indicator as suggested elsewhere but instead seems to prefer sediments containing green and yellow-green algal material. A Centropyxis-Arcella Assemblage occurs only at the base of the southernmost core where it is indicative of an early phase of hyposaline conditions as developed in shallow pools during the southward transgression of Lake Winnipeg. This study illustrates the usefulness of thecamoebians as paleolimnological indicators. Environmental changes are more significant in the restricted South Basin resulting in distinct thecamoebian assemblages. In contrast, the North Basin provided a stable environment throughout the late Holocene reflected in only subtle faunal changes. 相似文献
88.
89.
Plagiogranites as late-stage immiscible liquids in ophiolite and mid-ocean ridge suites: An experimental study 总被引:1,自引:0,他引:1
Chemical studies of two ophiolite suites and of selected mid-oceanic rift (MOR) regions indicate the presence of certain magmatic compositions: basalt, Fe-enriched basalt, and sodium granite (plagiogranite). There is a notable lack of evidence for melts of intermediate composition (i.e. 50–60 wt.% SiO2). To determine possible relationships between basic rocks (basalts and gabbros) and acidic rocks (plagiogranites) a primitive basalt was fractionated at low pressure, under anhydrous conditions, and at different oxygen fugacities near the iron-wustite buffer and slightly above the quartz-fayalite-magnetite buffer. Samples of this basalt were taken to slightly above liquidus temperatures and then cooled at rates ranging from 1 to 2°C/hr. A liquid line of descent characterized by an Fe enrichment was delineated by quenching these experiments from a final temperature in the range of 1200 to 1000°C and analyzing the residual liquid (glass). After 95% crystallization of olivine, plagioclase, calcium pyroxene, and ilmenite, the residual liquid was an Fe-enriched basalt. This Fe-enriched basalt became immiscible at a temperature of about 1010°C. The immiscible phases produced were a more Fe-enriched basaltic liquid and a granitic liquid. The granitic liquid is similar in composition to the naturally occurring plagiogranites found in small volumes in ophiolites and in certain MOR regions. It is therefore concluded that silicate liquid immiscibility could be the petrogenetic process responsible for producing plagiogranite in some MOR regions and in some ophiolites. On the other hand, plagiogranites in ophiolites and MOR rock suites having andesitic and dacitic composition rocks may have evolved under conditions more closely approximating equilibrium crystallization and/or they may have evolved at high water pressures. The available experimental data suggest that amphibole would crystallize early and yield SiO2-enriched liquids at depths greater than 4.5 km for PH2O's in the range 0.6–1.0 Ptotal.The major problem in interpreting any of the natural plagiogranites as products of silicate liquid immiscibility is the fact that neither the Fe-enriched conjugate liquid or its crystalline equivalent has been described in the ophiolite or MOR literature. The identification of this Fe-rich conjugate magma is essential in any rock suite if a completely convincing case for silicate liquid immiscibility is to be made. 相似文献
90.
Keith C.C. Bancroft Susan B. Kendall Michael M. Rhead Gerard Hentic 《Marine pollution bulletin》1979,10(8):238-239
Hydrocarbon fractions in crude oil were separated by a new charge-transfer polymer in place of silver ions in Argentation TLC. The charge-transfer plates are cheaper than their silver nitrate equivalents, do not discolour, and store well. The polymer/silica gel mix can be re-used. 相似文献