Electrokinetic Removal of Petroleum Hydrocarbon from Residual Clayey Soil Following a Washing Process

This study investigates total petroleum hydrocarbon (TPH) removal from residual clayey soil, after a washing procedure, using an electrokinetic process. Eight electrokinetic experiments were carried out to investigate the characteristics of TPH removal. When 0.1 M MgSO₄ or 0.1 M NaOH was used as an electrolyte, the electric current rapidly increased within the first 100 or 200 h, respectively. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. Therefore, the accumulated electroosmotic flow (EOF) when using 0.1 M NaOH as the anolyte‐purging solution was higher than when using 0.1 M MgSO₄. Although the energy consumption for the two purging solutions was similar, the efficiencies of TPH removal when 0.1 M MgSO₄ and 0.1 M NaOH with surfactant were used were 0 and 39%, respectively, because the electroosmotic flow rate increased with TPH removal efficiency. When 5% isopropyl alcohol (IPA) was used as a circulation solution, the electric current increased but the TPH removal was similar to that using water. In terms of energy consumption, the use of a surfactant‐enhanced electrokinetic process with NaOH as electrolyte was effective in removing TPHs from low‐permeability soil.     

Soft‐sediment deformation structures in Cretaceous non‐marine deposits of southeastern Gyeongsang Basin,Korea: Occurrences and origin

A variety of soft‐sediment deformation structures formed during or shortly after deposition occurs in the Cretaceous Seongpori and Dadaepo Formations of the southeastern Gyeongsang Basin exposed along coastal areas of southeastern Korean Peninsula for 0.5–2 km. These are mostly present in a fluvial plain facies, with interbedded lacustrine deposits. In this study, the features of different kinds of soft‐sediment deformation structures have been interpreted on the basis of sedimentology of structure‐bearing deposits, comparison with normal sedimentary structures, timing and mechanism of deformation, and triggering mechanisms. The soft‐sediment deformation structures can be classified into four morphological groups: (i) load structures (load casts, ball‐and‐pillow structures); (ii) soft‐sediment intrusive structures (dish‐and‐pillars, clastic dykes, sills); (iii) ductile disturbed structures (convolute folds, slump structures); and (iv) brittle deformation structures (syndepositional faulting, dislocated breccia). The most probable triggering mechanisms resulting in these structures were seismic shocks. These interpretations are based on the following field observations: (i) location of the study area within tectonically active fault zone reactivated several times during the Cretaceous; (ii) deformation structures confined to single stratigraphic levels; (iii) lateral continuity and occurrences of various soft‐sediment deformation structures in the deformed level over large areas; (iv) absence of depositional slope to indicate gravity sliding or slumping; and (v) similarity to the structures produced experimentally. The soft‐sediment deformation structures in the study areas are thus interpreted to have been generated by seismic shocks with an estimated magnitude of M > 5, representing an intermittent record of the active tectonic and sedimentary processes during the development and evolution of two formations from the late Early Cretaceous to the Late Cretaceous.     

Flow of a stratified fluid bounded by walls of finite thermal conductance

Abstract

A study is made of the behavior of a thermally stratified fluid in a container when the non-horizontal boundaries have finite thermal conductance. The theory of Rahm and Walin is briefly recounted. Numerical solutions to the Navier-Stokes equations for a Boussinesq fluid in a cylinder, adopting a Newtonian heat flux condition at the vertical sidewall, are presented. Results on the details of flow and temperature fields are given over ranges of the Rayleigh number Ra, the container aspect ratio H, and the sidewall conductance S. As S increases, the isotherms in the meridional plane are horizontal at small radii but they diverge at large radii. This creates temperature nonuniformilies in the horizontal direction, and convective motions result. The salient features of the interior temperature profiles are captured by the theoretical model. The velocity field is characterized by two oppositely-directed circulations. As Ra or S varies, the qualitative circulation patterns remain substantially unchanged, but the magnitudes of the convective flows differ by large amounts. The effects of the externally-imposed parameters on the flow and temperature structures are examined.     

SWAT-based hydrological modelling of tropical land-use scenarios

Abstract

The Hulu Langat basin, a strategic watershed in Malaysia, has in recent decades been exposed to extensive changes in land-use and consequently hydrological conditions. In this work, the impact of Land Use and Cover Change (LUCC) on hydrological conditions (water discharge and sediment load) of the basin were investigated using the Soil and Water Assessment Tool (SWAT). Four land-use scenarios were defined for land-use change impact analysis, i.e. past, present (baseline), future and water conservation planning. The land-use maps, dated 1984, 1990, 1997 and 2002, were defined as the past scenarios for LUCC impact analysis. The present scenario was defined based on the 2006 land-use map. The 2020 land-use map was simulated using a cellular automata-Markov model and defined as the future scenario. Water conservation scenarios were produced based on guidelines published by Malaysia’s Department of Town and Country Planning and Department of Environment. Model calibration and uncertainty analysis was performed using the Sequential Uncertainty Fitting (SUFI-2) algorithm. The model robustness for water discharge simulation for the period 1997–2008 was good. However, due to uncertainties, mainly resulting from intense urban development in the basin, its robustness for sediment load simulation was only acceptable for the calibration period 1997–2004. The optimized model was run using different land-use maps over the periods 1997–2008 and 1997–2004 for water discharge and sediment load estimation, respectively. In comparison to the baseline scenario, SWAT simulation using the past and conservative scenarios showed significant reduction in monthly direct runoff and monthly sediment load, while SWAT simulation based on the future scenario showed significant increase in monthly direct runoff, monthly sediment load and groundwater recharge.

Editor D. Koutsoyiannis; Associate editor C. Perrin     

Characteristics of adjoint sensitivity to potential vorticity

Structures of adjoint sensitivities to potential vorticity for specific initial and final norm are investigated for a short-range cyclone forecast in a three-dimensional quasigeostrophic (QG) model. Moreover, adjoint sensitivities to potential vorticity are compared with nonlinear sensitivities calculated for the same cyclogenesis case in the QG model. The adjoint sensitivities using different initial and final norms (e.g., total QG disturbance energy and potential enstrophy) show approximately similar characteristics for the horizontal and vertical structures and evolutions. Consistent with previous studies, the horizontal structure of the adjoint sensitivity is smaller for the energy norm than for the potential enstrophy norm. The dynamical mechanism of cyclone development by adjoint sensitivity coincides with that of nonlinear sensitivity, with slight differences in the region of sensitivity maxima over the upstream (nascent) low for the adjoint (nonlinear) sensitivity. The adjoint sensitivities show different vertical distributions from the nonlinear sensitivities. Consistent with the sensitive regions denoted by singular vectors and error evolution in the QG model, maxima of the adjoint sensitivities are located at both the upper and lower boundaries, with prominent secondary peaks in the lower to mid-troposphere of the domain. The level of the secondary maxima changes depending on the initial and final norm used. The secondary peak is located in the lower to mid- (mid-) troposphere for the total QG disturbance energy (potential enstrophy) as the initial and final norm. Based on the correspondence in the level of the sensitivity maxima in the interior of the domain between the adjoint and nonlinear sensitivities, adjoint sensitivities may serve as an alternative to nonlinear sensitivities given the enormous computing expenses in nonlinear sensitivity calculation.     

Carbon isotope composition of Upper Cambrian to Lower Ordovician carbonate in Korea,and its bearing on the Cambrian–Ordovician boundary and Lower Ordovician paleoceanography

This study presents an example of locating Cambrian–Ordovician boundary in the lower Paleozoic carbonate succession in Korea using carbon isotope stratigraphy. The Yeongweol Unit of the lower Paleozoic Joseon Supergroup comprises the Upper Cambrian Wagok Formation and the Lower Ordovician Mungok Formation in the Cambrian–Ordovician transition interval. Conventionally, the boundary was placed at the lithostratigraphic boundary between the two formations. This study reveals that the boundary is positioned in the basal part of the Mungok Formation based on the carbon isotope stratigraphy coupled with biostratigraphic information of conodont and trilobite faunas. The δ¹³C curve of the Lower Ordovician Mungok Formation shows a similar trend to that of the coeval stratigraphic interval of Argentine Precordillera (Buggisch et al., 2003), suggesting that the δ¹³C curve of the Mungok Formation reflects the Early Ordovician global carbon cycle.     

Investigation of CO2 behavior and study on design of optimal injection into Gorae-V aquifer

This study presents the Bottom-hole pressure (BHP) behavior with different wettabilities and the optimal design scheme to effectively inject CO₂ into the Gorae-V aquifer. As a result, the injection rate and injectivity were increased as the wettability condition became more water-wet. However, the more wettability condition becomes water-wet, the more the ultimate CO₂ injection volume decreases. When the injectivity was 346 ton/day/Mpa at the Gorae-V aquifer, the aquifer can sustain CO₂ injection at a rate of 2,425 tons per day over this time period. A design for a complete CCS system was developed based on the existing off-shore pipeline in combination with new on-shore CO₂ transport infrastructure, and a pressure of 12.8 MPa is required at the CO₂ source to maintain this injection rate.     

Tracing origins of sewage and organic matter using dissolved sterols in Masan and Haengam Bay,Korea

Masan and Haengam Bays in Korea are highly polluted and semi-enclosed. Domestic and industrial effluents are directly or indirectly discharged into the bays through sewage treatment plants (STP) and creeks. In this study, 15 dissolved sterol compounds were determined in order to understand their sources and relative contribution. Freshwater samples were taken from 13 creeks and at two STP sites on a monthly basis. Total dissolved sterol concentrations ranged from 993 to 4158 ng/L. The concentrations of sterols in winter were higher than in summer. Among the sterols analyzed, cholesterol, β-sitosterol, coprostanol and cholestanone were major compounds in creek water. Seawater samples were concurrently collected at 21 stations in Masan Bay. Total sterol concentrations ranged 118–6,956 ng/L. Inner bay showed high concentrations of sterols in summer, while outer bay showed high sterol concentrations in winter. Among the sterols, cholesterol, β-sitosterol and brassicasterol were major compounds in seawater. In order to examine the contribution of urban sewage, the concentration of coprostanol and fecal sterol ratios were calculated. Most of the creek water, inner bay and near STP outlet samples were affected by sewage. Terrestrial organic matters accounted for a high proportion of dissolved organic matter origin. Fecal origins were relatively high in the inner bay areas and in the STP outlet, while sterols of marine origin were high in the outer bay areas.     

Environmentally associated spatial changes of a macrozoobenthic community in the Saemangeum tidal flat,Korea

Estuarine tidal flats are both ecologically and economically important, hence developing methods to reliably measure ecosystem health is essential. Because benthic fauna play a central role in the food web of tidal flats, in this study we set out to quantitatively describe the intertidal zonation of macro-invertebrates and their associations with specific environmental parameters along three transects in the Saemangeum tidal flat, Korea. The abundance and biomass of intertidal fauna with respect to five environmental parameters (i.e., shore level, mud content, coarse sand content, water content, and organic content) were measured, to identify environmental factors that influence macrofaunal distribution in intertidal soft bottom habitats. A total of 75 species were identified, with dominant species showing distinct zones of distribution along all transects. The number of species recorded in each transect was found to be dependent on sediment characteristics and salinity. Cluster analysis classified the entire study area into three faunal assemblages (i.e., location groups), which were delineated by characteristic species, including (A) ‘Periserrula–Macrophthalmus’, (B) ‘Umbonium–Meretrix’, and (C) ‘Prionospio–Potamocorbula’. Four environmental variables (i.e., shore level, water content, mud content, and organic content) appeared to determine factors that distinguished the three faunal assemblages, based on the discriminant analysis. The faunal assemblage types of the sampled locations were accurately predicted from environmental variables in two discriminant functions, with a prediction accuracy of 98%. It should be noted that the zonation of benthos in the lower section (C) of Sandong had been affected by the construction of a nearby dike, while this parameter had remained essentially unchanged at the other two location groups (A–B). Overall, the zonation of benthos from the Saemangeum tidal flat was explained adequately by the measured environmental variables, implying that faunal assemblages are closely associated with certain combinations of abiotic factors. The identification of such reliable associations may facilitate the development of statistical models to predict faunal distributions based on environmental variables at both local and regional scales. The entire study area was embanked in 2006 (one year after this study), and an integrated plan was set into force to develop claimed land into industrial, residential and agricultural districts, which also included a partial restoration program of the tidal flats located near to the study area.     

FT-IR measurements of cold C3H8 cross sections at 7–15 μm for Titan atmosphere

We present absorption cross sections of propane (C₃H₈) at temperatures from 145 K to 297 K in the 690–1550 cm⁻¹ region. Pure and N₂-broadened spectra were measured at pressures from 3 Torr to 742 Torr using a Bruker IFS125 FT-IR spectrometer at JPL. The gas absorption cell, developed at Connecticut College, was cooled by a closed-cycle helium refrigerator. The cross sections were measured and compiled for individual spectra recorded at various experimental conditions covering the planetary atmosphere and Titan. In addition to the cross sections, a propane pseudoline list with a frequency grid of 0.005 cm⁻¹, was fitted to the 34 laboratory spectra. Line intensities and lower state energies were retrieved for each line, assuming a constant width. Validation tests showed that the pseudoline list reproduces discrete absorption features and continuum, the latter contributed by numerous weak and hot band features, in most of the observed spectra within 3%. Based on the pseudoline list, the total intensity in the 690–1550 cm⁻¹ region was determined to be 52.93 (±3%) × 10⁻¹⁹ cm⁻¹/(molecule cm⁻²) at 296 K; this value is within 3% of the average from four earlier studies. Finally, the merit of the pseudoline approach is addressed for heavy polyatomic molecules in support of spectroscopic observation of atmospheres of Titan and other planets. The cold cross sections will be submitted to the HITRAN database (hitran.harvard.edu), and the list of C₃H₈ pseudolines will be available from a MK-IV website of JPL (http://mark4sun.jpl.nasa.gov/data/spec/Pseudo).