Synthetic high-resolution near-IR spectra of the Sun for planetary data reductions made from ATMOS/Spacelab-3 and Atlas-3 data

We have constructed synthetic solar spectra for the 2302-4800 cm⁻¹ (2.08-4.34 μm) range, a spectral range where planetary objects mainly emit reflected sunlight, using ATMOS (Atmospheric Trace Molecule Spectroscopy)/Spacelab-3 and Atlas-3 spectra, of which resolution is 0.01 cm⁻¹. We adopted Voigt line profiles for the modeling of line shapes based on an atlas of line identifications compiled by Geller [Geller, M., 1992. Key to Identification of Solar Features. A High-Resolution Atlas of the Infrared Spectrum of the Sun and the Earth Atmosphere from Space. NASA Reference Publ. 1224, vol. III. NASA, Washington, DC, pp. 1-22], who derived solar line positions and intensities from contaminated high-resolution solar spectra obtained by ATMOS/Spacelab-3. Because the ATMOS spectra in these wavelength ranges are compromised by absorption lines of molecules existing in Earth's high-altitude atmosphere and in the compartment of the spacecraft, the direct use of these high-resolution solar spectra has been inconvenient for the data reductions of planetary spectra. We compared the synthetic solar spectra with the ATMOS spectra, and obtained satisfactory fits for the majority of the solar lines with the exception of abnormal lines, which do not fit with Voigt line profiles. From the model fits, we were able to determine Voigt line parameters for the majority of solar lines; and we made a list of the abnormal lines. We also constructed telluric-line-free solar spectra by manually eliminating telluric lines from the ATMOS spectra and filling the gaps with adjacent continua. These synthetic solar spectra will be useful to eliminate solar continua from spectra of planetary objects to extract their own intrinsic spectral features.     

Forearc serpentinite mélange from the Hongseong suture, South Korea

The signature of a prolonged subduction–accretion history from Paleozoic to Early Mesozoic is preserved within the dismembered serpentinite mélanges within the Hongseong suture. Here we present major and trace element data from the mafic fragments/blocks within the Baekdong serpentinite mélange revealing their arc-like tholeiite affinity within a suprasubduction zone tectonic setting. Chromian spinel compositions from the Baekdong hydrated mantle peridotite (serpentinite) are characterized by high Cr# (0.53–0.67) and Fe²⁺/Fe³⁺ ratio, medium Mg# (0.42–0.55), and Al₂O₃ contents (17–25 wt.%) indicating a forearc tectonic environment for the hydrated mantle peridotite. The estimated melting degree (> 17.6%) and FeO/MgO of the parental melt (0.9–1.3) are consistent with that of forearc magmas. SHRIMP zircon U–Pb ages from a high-grade mafic rock and an anorthosite from the study area give protolith ages of ~ 310 Ma and ~ 228 Ma, respectively. Zircons from an associated orthogneiss block within the mélange yield a Neoproterozoic crystallization age of ~ 748 Ma. These results, together with the recent SHRIMP zircon ages from other dismembered serpentinite mélanges within the Wolhyeonri complex, suggest that Paleozoic to Early Mesozoic subduction and subsequent collision events led to the exhumation of the hydrated forearc mantle peridotites from a metasomatized mantle wedge. The Hongseong region preserves important clues to a long-lived subduction system related to global events associated with the final amalgamation of the Pangaea supercontinent.     

Adsorptive attenuation of ferrocyanide from seepage water in landfill clay liners

The spent potliner (SPL) landfill liner system provides the primary attenuation mechanism that blocks the leaching of ferrocyanide. If the seepage occurs, however, the off-site leaching potential of ferrocyanide will be enhanced, resulting in contaminant dispersion. In this study, the adsorptive attenuation of ferrocyanide by two common lining materials (kaolinite and montmorillonite) was investigated under various seepage settings, such as influent concentration, liner thickness, and seepage velocity. The attenuation of ferrocyanide through both lining materials was obvious by lowering the maximum concentration and retarding the peak arrival time and was greater than that expected from batch data, likely due to the high mass-volume ratio under seepage condition. In comparison, seepage of ferrocyanide through lining material layer was retarded when (1) influent concentration was halved, (2) liner thickness was 1.5-fold, and (3) seepage velocity was halved. These experimental results strongly support the concentration-specific and rate-limited adsorptive attenuation of ferrocyanide by lining materials during the seepage process. An extended desorption front was observed for all seepage conditions; it was particularly more apparent for montmorillonite with a slow seepage velocity, further supporting that the release of adsorbed ferrocyanide from adsorbent is energetically hysteretic. Among the factors investigated in this study, the greatest retardation of ferrocyanide movement from seepage water was achieved upon doubling liner thickness. Therefore, for the design of a SPL landfill liner to minimize the leaching potential and thus the environmental risk of ferrocyanide, optimization of the liner thickness should be considered foremost.     

Adaptive second-order Volterra filtering and its application tosecond-order drift phenomena

This paper presents an adaptive second-order Volterra filter and its application to model-test data of a prototype tension leg platform (TLP). The least-squares approach of a second-order Volterra model and its adaptive filtering algorithm based on recursive least-squares are introduced. The second-order Volterra filter is applied to identify the linear and quadratically nonlinear relationship between irregular sea wave excitation and the surge response of a tension leg platform. Next, a deconvolution technique, based on the impulse invariance standard Z-transform, is utilized to recover the linear and quadratic forces exerted on the TLP     

The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study

The local configurations around sodium ions in silicate glasses and melts and their distributions have strong implications for the dynamic and static properties of melts and thus may play important roles in magmatic processes. The quantification of distributions among charge-balancing cations, including Na⁺ in aluminosilicate glasses and melts, however, remains a difficult problem that is relevant to high-temperature geochemistry as well as glass science.Here, we explore the local environment around Na⁺ in charge-balanced aluminosilicate glasses (the NaAlO₂-SiO₂ join) and its distribution using ²³Na magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy at varying magnetic fields of 9.4, 14.1, and 18.8 T, as well as triple-quantum (3Q)MAS NMR spectroscopy at 9.4 T, to achieve better understanding of the extent of disorder around this cation. We quantify the extent of this disorder in terms of changes in Na-O distance (d[Na-O]) distributions with composition and present a structural model favoring a somewhat ordered Na distribution, called a “perturbed” Na distribution model. The peak position in ²³Na MAS spectra of aluminosilicate glasses moves toward lower frequencies with increasing Si/Al ratios, implying that the average d(Na-O) increases with increasing R. The peak width is significantly reduced at higher fields (14.1 and 18.8 T) because of the reduced effect of second-order quadrupolar interaction, and ²³Na MAS NMR spectra thus provide relatively directly the Na chemical shift distribution and changes in atomic environment with composition. Chemical shift distributions obtained from ²³Na 3Q MAS spectra are consistent with MAS NMR data, in which deshielding decreases with R. The average distances between Na and the three types of bridging oxygens (BOs) (Na-{Al-O-Al}, Na-{Si-O-Al}, and Na-{Si-O-Si}) were obtained from the correlation between d(Na-O) and isotropic chemical shift. The calculated d(Na-{Al-O-Al}) of 2.52 Å is shorter than the d(Na-{Si-O-Si}) of 2.81 Å, and d(Na-{Al-O-Al}) shows a much narrower distribution than the other types of BOs. ²³Na chemical shifts in binary (Al-free) sodium silicate glasses are more deshielded and have ranges distinct from those of aluminosilicate glasses, implying that d(Na-NBO) (nonbridging oxygen) is shorter than d(Na-BO) and that d(Na-{Si-O-Si}) in binary silicates can be shorter than that in aluminosilicate glasses. The results given here demonstrate that high-field ²³Na NMR is an effective probe of the Na⁺ environment, providing not only average structural information but also chemically and topologically distinct chemical shift ranges (distributions) and their variation with composition and their effects on static and dynamic properties.     

Geology, Mineralogy and Geochemistry of Carbonate Replacement-Type Lead-Zinc-Silver Deposits in Janggun Mine, Republic of Korea

INTRODUCTIONThe Janggun mine,Republic of Korea,is located in thesoutheast of the Seoul,about latitude36°5 1′N and longitude12 9°0 4′E. In this mine area is situated the Bonghwa m ineral-ized zone of the Taebaegsan mining district,Korea.The geo-logic setting of the region was described as the Samgeum riQuadrangle(Kim et al.,196 2 ) .The general and local geolo-gy near the mine area have been studied by L ee (196 7) ,Hwang and Reedman(1975 ) .This mine consists of four min-eral de…     

Flow of a double-diffusive stratified fluid in a differentially-rotating cylinder

Abstract

A study has been made of a basic state of axisymmetric flow, at large rotational Reynolds numbers, in a double-diffusive stratified fluid contained in a vertically-mounted, differentially-rotating cylindrical cavity. The aim is to describe the qualitative characteristics of the flow of a fluid, the density of which is stratified by two diffusive effects, i.e., temperature and salinity gradients. Attention is confined to situations in which the temperature and salinity gradients make opposing contributions to the overall density profile, the undisturbed stratification being gravitationally stable. Finite difference numerical solutions of the governing Navier-Stokes equations have been obtained using the Boussinesq approximation. The results are presented in a way that illustrates the explicit effects of double-diffusivity when the cavity aspect ratio, height/radius, is O(1). The principal non-dimensional parameters characterizing the flow field are identified. In the interior core, the primary dynamic balance is between the horizontal density gradient and the vertical shear of the prevailing azimuthal velocity. The effective stratification is seen to decrease as the double-diffusivity increases, even if the overall stratification parameter, St, is held constant. The solute field contains a very thin boundary layer structure at large Lewis numbers. The effective stratification increases with the Prandtl number. Results have been derived for extreme values of the cavity aspect ratio. For small cavity aspect ratios, the dominant dynamic ingredients are viscous diffusion and rotation. For large aspect ratios, the bulk of the flow field is determined by the rotating sidewall. In this case, the direct influence of the double-diffusivity is minor.     

A method of calculating the non‐linear seismic response of a building braced with viscoelastic dampers

Buildings are continually subject to dynamic loads, such as wind load, seismic ground motion, and even the load from internal utility machines. The recent trend of constructing more flexible high‐rise buildings underscores the importance of including viscoelastic dampers in building designs. Viscoelastic dampers are used to control the dynamic response of a building. If the seismic design is based only on the linear response spectrum, considerable error may occur when calculating the seismic response of a building; rubber viscoelastic dampers show non‐linear hysteretic damping that is quite different from viscous damping. This study generated a non‐linear response spectrum using a non‐linear oscillator model to simulate a building with viscoelastic dampers installed. The parameters used in the non‐linear damper model were obtained experimentally from dynamic loading tests. The results show that viscoelastic dampers effectively reduce the seismic displacement response of a structure, but transmit more seismic force to the structure, which essentially increases its seismic acceleration response. Copyright © 2003 John Wiley & Sons, Ltd.     

由多震相走时和波形作三维地震成像

本项成果包括：提出天然地震走时反演层析成像技术,采用下列方法使得处理结果得以改善：１）利用３２个地震,４０４条射线的Ｐｇ,Ｓｇ,Ｐｍ,Ｓｍ,Ｐｎ,Ｓｎ等震相增加约束条件：２）用已有精度较高的人工地震测深化结果作速度约束;３）用波形反演来修改模型,把波源,介质吸收,散射等物理特征集中反映在记录中,把诸多物理量开发出来互为约束,以修改后的模型再作反演,使解的稳定性大大提高;４）采用最优化过程,选择遗传