Geochemistry of Thermal－Mineral Waters in Siping＇an District， Shanxi Province， China

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安徽大别山北部红刚玉岩石的成因

大别山北部红刚玉矿产在太古代大别山群黑云角门外长片麻岩以及超基性岩中。赋存红刚玉的刚玉黑云二长片麻岩的原始岩石为富铝泥质岩,在角门岩相变质条件下,通过两种脱硅方式,即变质分异作用和超基性岩侵位,形成刚玉黑云二长片麻岩。它们形成的温压条件：Ｔ＝５００℃～７００℃,Ｐ＝０．４～０．７ＧＰａ。刚玉形成的可能的化学机制是白云母在缺硅条件下的分解。     

浙江省东部土壤元素地球化学特征及意义

为了研究土壤和稻米元素地球化学分布特征及影响稻米中重金属质量分数的主要因素,对浙江省东部农田根系土-稻谷样品进行了采集和分析。结果表明：各研究区均有重金属元素质量分数高于区域地球化学背景值,尤其是温州南郊地区的Hg、台州泽国地区Cd、绍兴北郊地区的Hg,其质量分数分别是背景值的6倍、5倍及9倍;7个研究区中,只有嘉兴新胜地区的As质量分数超过背景值。其原因是这些地区工业化进程迅速,人为活动频繁,污染较严重。绍兴北郊、嘉兴新丰、嘉兴新胜和桐乡崇福地区稻米中As、Cd、Cr、Hg、Se和Pb质量分数均未超过标准限值。稻米对重金属元素的吸收富集主要受土壤有机质、pH、土壤阳离子交换量和黏粒组成等土壤理化性质的影响：土壤有机碳越丰富越有利于稻米对As、Cd、Cr和Ni的吸收;稻米对As、Cd、Mn和Ni的富集系数随着pH上升而下降;土壤阳离子交换量和黏粒组成与水稻As、Cu、Hg、Mn、Pb、Se和Zn的富集系数呈显著负相关。     

汶川地震映秀-北川地表破裂带虹口乡段精细填图、位移特征和地震构造分析

同震地表破裂带是地震破裂最直观的表现。地表破裂带的精细填图对理解地震破裂过程及发震机理有着重要意义。我们对5.12汶川地震映秀-北川同震破裂带南部的虹口乡区段开展了较为精细的填图工作,该区段地表破裂带的平面几何和同震位移特征沿走向均显示出公里尺度的横向变化和复杂性。根据同震破裂不连续性特征可把地表破裂分为4段,自南向北依次为深溪沟段、庙坝段、高原新村段和八角庙段。其中,深溪沟段和八角庙段同震垂直位错较大,达.5～6m;庙坝段同震垂直位移量普遍较低,1～2m或更低;  在高原新村附近,地表破裂带分为近平行的南北两支,北支以右旋走滑为主,南支以南东盘逆冲抬升为主,这与与映秀-北川同震破裂总体北西盘抬升的性质相反。本文对高原新村附近的反向陡坎进行了深入的探讨,并综合前人的研究结果,认为是破裂在从深部往上扩展的过程中,在浅表部位顺着发育在虹口东南部的大鱼洞-龙溪飞来峰后缘的具南东倾向的断面继承而成。与北川沙坝附近的反向陡坎一样,说明老断裂带构造几何特征对单次地震破裂的扩展有牵引作用。最后,讨论了八角庙有切割关系的两组断层擦痕的地震学和地质学意义,指出可能指示了映秀-北川断裂面上局部区段震前的初始应力水平较低。     

Correction of common lead in U-Pb analyses that do not report 204 Pb

During the Early-Middle Proterozoic era, three major lithostratigraphic unit associations, namely Hekou-Dahongshan, Dongchuan, and Kunyang-Huili Groups, were established for the metamorphosed volcanic-sedimentary rocks exposed in the southwestern Yangtze Block (SWYB). The integration of petrology, geochemistry and geochronology constrains tectonic framework and evolution of the SWYB, in which four sets of SHRIMP U-Pb zircon ages were obtained from the volcanic rocks interbedded within the Middle Proterozoic successions: 1800–1600 Ma, 1600–1300 Ma, 1300–1100 Ma, and 1100–1000 Ma. Major and trace elemental analysis indicate that four key tectonic evolutionary stages, each coinciding with the above radiometric age set, of the SWYB during the Early-Middle Mesoproterozoic. The SWYB was characterized by an east-westerly trending rift in the Hekou, Dongshan, and Dongchuan areas, and separate basin-forming events during 1800–1600 Ma and 1600–1300 Ma, respectively. In the SWYB, an intracontinental rift basin and a rift basin occurred in the Caiziyuan-Matang and Laowushan areas, respectively in 1300–1100 Ma ago. During 1100–1000 Ma, the SWYB was characterized by the closure of the Caiziyuan-Matang rift-ocean basin, collision between the Huili Blocks and Kunyang Blocks, and presence of volcanic arcs in the Tianbaoshan and Fulingpen areas. Accordingly, the SWYB represents a new basin that records the relatively complete assembly process of the Rodina during the Early-Middle Mesoproterozoic era.     

Differentiation, crustal contamination and emplacement of magmas in the formation of the Nantianwan mafic intrusion of the ~260?Ma Emeishan large igneous province, SW China

The Nantianwan mafic intrusion in the Panxi region, SW China, part of the ~260?Ma Emeishan large igneous province, consists of the olivine gabbro and gabbronorite units, separated by a transitional zone. Olivine gabbros contain olivine with Fo values ranging from 83 to 87, indicating crystallization from a moderately evolved magma. They have 0.2 to 0.9?wt?% sulfide with highly variable PGE (17?C151?ppb) and variable Cu/Pd ratios (1,500?C32,500). Modeling results indicate that they were derived from picritic magmas with high initial PGE concentrations. Olivine gabbros have negative ??Nd(t) values (?1.3 to ?0.1) and positive ??Os(t) values (5?C15), consistent with low degrees of crustal contamination. Gabbronorites include sulfide-bearing and sulfide-poor varieties, and both have olivine with Fo values ranging from 74 to 79, indicating crystallization from a more evolved magma than that for olivine gabbros. Sulfide-bearing gabbronorites contain 1.9?C4.1?wt?% sulfide and 37?C160?ppb PGE and high Cu/Pd ratios (54,000?C624,000). Sulfide-poor gabbronorites have 0.1?C0.6?wt?% sulfide and 0.2?C15?ppb PGE and very high Cu/Pd ratios (16,900?C2,370,000). Both sulfide-bearing and sulfide-poor gabbronorites have ??Nd(t) values (?0.9 to ?2.1) similar to those for olivine gabbros, but their ??Os(t) values (17?C262) are much higher and more variable than those of the olivine gabbros. Selective assimilation of crustal sulfides from the country rocks is thus considered to have resulted in more radiogenic ¹⁸⁷Os of the gabbronorites. Processes such as magma differentiation, crustal contamination and sulfide saturation at different stages in magma chambers may have intervened during formation of the intrusion. Parental magmas were derived from picritic magmas that had fractionated olivine under S-undersaturated conditions before entering a deep-seated staging magma chamber, where the parental magmas crystallized olivine, assimilated minor crustal rocks and reached sulfide saturation, forming an olivine- and sulfide-laden crystal mush in the lower part and evolved magmas in the upper part of the chamber. The evolved magmas were forced out of the staging chamber and became S-undersaturated due to a pressure drop during ascent to a shallow magma chamber. The magmas re-attained sulfide saturation by assimilating external S from S-rich country rocks. They may have entered the shallow magma chamber as several pulses so that several gabbronorite layers each with sulfide segregated to the base and a sulfide-poor upper part. The olivine gabbro unit formed from a new and more primitive magma that entrained olivine crystals and sulfide droplets from the lower part of the staging chamber. A transitional zone formed along the boundary with the gabbronorite unit due to chemical interaction between the two rock units.     

A comprehensive survey of lignin geochemistry in the sedimentary organic matter along the Kapuas River (West Kalimantan, Indonesia)

In this first study of lignin geochemistry in the world’s longest river on an island, surface sediments were collected along the Kapuas River, three lakes in the upper river, a tributary in the lower river and a separate river during June-July 2007 and December 2007-January 2008. The samples were analyzed for lignin-derived phenols and bulk elemental and stable carbon isotope compositions. Λ values (the sum of eight lignin phenols, expressed as mg/100 mg organic carbon (OC)) ranged from 0.13 to 3.70. Ratios of syringyl/vanillyl (S/V) and cinnamyl/vanillyl (C/V) ranged from 0.34 to 1.18 and 0.28 to 1.40, respectively, indicating the presence of non-woody angiosperm tissues. The high vanillic acid to vanillin (Ad/Al)v (0.71-2.01) and syringic acid to syringaldehyde (Ad/Al)s (0.72-2.12) ratios indicate highly degraded lignin materials. In the upper Kapuas River, highly degraded soil materials discharged from lands that were barren as a result of deforestation activities were detected in the locations directly in those vicinities. The middle Kapuas River showed rapid organic matter degradation, probably due to the presence of fresh terrestrial and phytoplankton organic matter fueling the biogeochemical cycling. The Kapuas Kecil River, one of the two branches in the lower reach of the Kapuas River, showed higher levels and diagenesis of sedimentary organic matter due to input from anthropogenic sources and increased marine organic matter near the mouth. This study shows that different stretches along the river exhibit different levels and composition of sedimentary organic matter, as well as different carbon dynamics, which is directly attributable to the varying landscapes and quality of organic matter.     

汶川地震(Ms8.0）地表建筑体变形特征及其构造意义

通过汶川地震震区大量的实地考察已证实沿着早先活动断裂主要发育了两条地表破裂带：一条是沿着映秀－北川断裂产生的逆冲伴随右旋走滑破裂带,长275km,最大垂直位移达11m,水平位移达12m; 另一条纯逆冲性质的破裂带,沿着灌县－安县断裂发育,最大垂直位移达4m。活动断裂之上的地表破裂带是野外工作中确定地震断裂性质的重要现象。另外,在活动断裂相邻区域和远离区域的路面以及建筑体还大量存在变形现象。通常沿活动断裂产生的地表破裂是典型的同震破裂,相邻区域的地表路面及建筑体发育的变形属于次生变形,远离区域发育的变形则属于震后变形。对次生变形和震后变形测量数据的应用容易影响活动断裂特征的确定和性质的判断,因为路面等建筑体上的挤压拱起、叠置以及水平错断等现象多是受到地震过程中通过断裂活动突然释放的巨大能量作用在局部地表建筑体产生的变形。但是,分布广泛的挤压现象暗示了区域上挤压应力场环境,有利于地表同震破裂位置的推测及地震断裂性质的判断。     

Seasonal variation in nature and chemical compositions of spring water in Cuihua Mountain,Shaanxi Province,central China

Two springs (Cuihua Spring, Shuiqiuchi Spring) in Cuihua Mountain of the Qinling Mountains were observed and sampled monthly during 2004 and 2005 to trace their physical properties and chemical compositions with seasons. Although both pH values and cation (Ca²⁺, Mg²⁺, K⁺, and Na⁺) contents of Cuihua Spring are higher than those of Shuiqiuchi Spring, seasonal variations in both springs are obvious. The pH values of both spring waters are between 5.69 and 6.98, lower than that of rainwater during summer and autumn. From January to November, the pH values of both springs similarly vary from high to low and then to high again. Variations in electric conductivities of two spring waters are contrary, although their electric conductivities are positively correlative with the cation content respectively. This can be attributed to different water sources of the two springs or different acidic rocks they passed. The contents of HCO₃ ⁻, Ca²⁺, Mg²⁺, K⁺, and Na⁺ are low, indicating a low silicate weathering that the strata in this district are mainly composed of granite and schist of quartz and mica. Differing from change in spring water in karst regions of South China where abundant precipitation and dilution of rainwater cause low pH and electric conductivity in summer and autumn, the seasonal variations in the pH values and the electric conductivities of two springs in Qinling Mountains are attributed to seasonal changes in CO₂ produced by microorganisms’ activity in soil within respective year, rather than rainfall. The microorganisms’ activity in soil produces more CO₂ during summer and autumn. Therefore, the water nature of springs in silicate regions chiefly reflects the seasonal changes of CO₂ produced by the microorganisms in soil.