基于便携式X射线荧光光谱法的深海沉积物现场成分快速检测及适用性评估

远洋粘土、硅藻软泥、铁锰结核及结壳是常见的深海沉积成因物质类型,在开展深海地质调查工作时及时获得这些物质的成分信息,对于提升海上地质调查效率和认知能力十分重要。通过便携式X射线荧光光谱法（pXRF）对菲律宾海深水区域60个样品进行分析,并结合实验室测试结果,评估pXRF能测出的24种元素含量数据的稳定性、准确性及相关性,探讨pXRF在海上地质调查工作中对于深海沉积物现场成分快速检测的适用性。通过综合对比研究发现,Ca、Cu、Fe、K、P、Pb、Sr、Zn、Zr九种元素稳定性、准确性和相关性较好,可以直接用于定性乃至定量研究工作。Al、Ba、Mn、Mo、Ni、Rb、Si、Ti、Th、V十种元素的三项指标参数等级略低,可用于含量高低判定和趋势分析等定性研究工作。Bi、Cs、Mg、Sb、Sc五种元素的测试效果较差,本法不建议使用。取样量充足且分布均匀、湿样烘干至恒量后研磨过筛、封装时充分压实平整、测试时间增长、选择合适的标准物质校正和检验、重点和异常样品增加测试次数等措施的执行有利于获得高精度的pXRF海上测试数据。未来对更多类型和数量深海样品开展pXRF现场分析,将有利于建立更精准的测试方法流程,达到现场快速揭示样品成分特征、确定底质类型及圈定矿化异常等目的,为海上关键决策的部署和实施提供参考和借鉴。     

The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

Isolation,purification and characterization of the hydrogen evolution promoting factor of hydrogenase ofSpirulina platensis

A component (s-factor) with obvious promoting effect on hydrogen evolution of hydrogenase has been isolated and extracted from a cell-free preparation ofSpirulina platensis. The effect of the s-factor in the reaction system is similar to that of Na₂S₂O₄, but is coupled with light. The s-factor has the maximum absorption peak at 620 nm in the oxidized state, at 590 nm in the reduced state. The partially purified s-factor showed two bands by SDS-PAGE and is distinctly different from phycocyanin, which has no change of oxidized state and reduced state absorption spectra, and also has no promoting effect on hydrogenase ofSpirulina platensis under the light. The research supported by the NSFC.     

山东省产业重心转移与可持续发展研究

 本文利用经济空间结构的重心研究方法,分析了山东省近八年来产业重心的转移,提出了山东省产业可持续发展战略     

�ܹ���̬���������ݴ����뾫�ȷ���

???????????????????????????????????????????б??????????????б?????????????????????????????????????????????????????????б????????????????????????????????????б??????????????????????λ???????????????????????????????????????????Ч???????????????????????     

CATASTROPHIC ECO-ENVIRONMENTAL CHANGE IN THE SONGNEN PLAIN, NORTHEASTERN CHINA SINCE 1900S

Although the Songnen Plain in the northeastern China was developed relatively late in the temperate zone of the world, its eco-environment has changed greatly. This paper analyzes the changes of land cover and the rates and trends ofdesertification during the past 100 years in the Songnen Plain. According to the macroscopic analysis, we find that the eco-environment in the plain has reached to the threshold of catastrophic change since the 1950s. The Thorn Needle Catastrophic Model was used to determine and validate this conclusion. Human activities, including large-scale construction projects, such as huge dams and dikes, and excessive grazing were the primary factors contributing to regional eco-environmental catastrophe. And irrational reclamation of the wilderness also affected the eco-environmental change. The results reveal the complex human-land interactions.     

基于水利益共享的跨境流域水资源多目标分配研究——以澜沧江-湄公河为例

以水利益共享代替分水的理念有利于充分发挥水资源效益和减少区域矛盾冲突,但由于缺乏具体可实施的分配模式一直停留在设想阶段。基于水利益共享理念,建立跨境流域水资源多目标分配指标体系,并结合澜沧江-湄公河流域跨境水资源利用现状及需求,提出澜沧江-湄公河流域跨境水资源多目标分配模型。为基于水利益共享的跨境水资源多目标分配提供了具有充分可操作性的指标体系和分配模型,有助于推进跨境流域水利益共享的实施,实现区域双边或多边在水资源利用上的共赢和发展目标。     

Influence of fines content on the anti-frost properties of coarse-grained soil

This paper aims to determine the optimal fines content of coarse-grained soil required to simultaneously achieve weaker frost susceptibility and better bearing capacity. We studied the frost susceptibility and strength properties of coarse-grained soil by means of frost heaving tests and static triaxial tests, and the results are as follows:(1) the freezing temperature of coarse-grained soil decreased gradually and then leveled off with incremental increases in the percent content of fines; (2) the fines content proved to be an important factor influencing the frost heave susceptibility and strength properties of coarse-grained soil. With incremental increases in the percent content of fines, the frost heave ratio increased gradually and the cohesion function of fines effectively enhanced the shear strength of coarse-grained soil before freeze-thaw, but the frost susceptibility of fines weakened the shear strength of coarse-grained soil after freeze-thaw; (3) with increasing numbers of freeze-thaw cycles,the shear strength of coarse-grained soil decreased and then stabilized after the ninth freeze-thaw cycle, and therefore the mechanical indexes of the ninth freeze-thaw cycle are recommended for the engineering design values; and (4) considering frost susceptibility and strength properties as a whole, the optimal fines content of 5% is recommended for railway subgrade coarse-grained soil fillings in frozen regions.     

Damming of large river by debris flow: Dynamic process and particle composition

The frequency and extent of debris flows have increased tremendously due to the extreme weather and the Wenchuan earthquake on May 12, 2008. Previous studies focused on the debris flow from gullies damming the mountain streams. In this paper, an equation for the run-out distance of debris flow in the main river is proposed based on the dynamic equation of debris flow at different slopes given by Takahashi. By undertaking field investigations and flume experiments, a new calculation method of the volume of debris flow damming large river is obtained. Using the percolation theory and the renormalization group theory it was deduced that the large particles should comprise more than 50% for forming a stable debris flow dam. Hence, the criteria of damming large river by debris flow is presented in terms of run-out distance and grain composition which was then validated through the event of damming river by debris flow at Gaojia gully, the upper reaches of the Minjiang River, Sichuan, China, on July 3, 2011.     

共和盆地黏土矿物与孢粉记录的末次冰消期以来的气候环境相位差

在青藏高原北缘共和盆地达连海钻取了40.92 m沉积柱,其¹⁴C年代有10个控制点,底部年龄最大值为14.5 cal ka BP,沉积柱为末次冰消期以来的湖泊沉积物。在沉积柱中按20 cm/70 a分辨率选出200个样品进行了黏土矿物、粒度、碳酸盐、沉积速率等非生物指标与生物指标的孢粉等多项指标的综合分析。结果表明：末次冰消期以来,达连海沉积柱中非生物指标与生物指标反映的气候和环境变化阶段的显著性不同,反映的气候环境的变化阶段也不尽一致,出现气候环境的相位差。冰消期黏土矿物非生物指标与孢粉生物指标有约1.0~1.2 ka的相位差;早、中全新世黏土矿物反映的气候变化时段较孢粉指标指示的时段滞后约1.0 ka;在晚全新世黏土矿物反映的气候变化较孢粉滞后约0.1 ka。造成黏土矿物和孢粉反映气候环境相位差的原因是孢粉和黏土矿物对气候响应的差异性、黏土矿物和孢粉搬运方式的不同、气候条件及其转换、地貌等多因素的综合影响。