Seasonal variation in the biochemical composition of red seaweed (<Emphasis Type="Italic">Catenella repens</Emphasis>) from Gangetic delta,northeast coast of India

The biochemical composition of red seaweeds, Catenella repens was investigated in this present study along with subsequent analysis of relevant physico-chemical variables. In this study, the relationship between the nutritive components of this species and the ambient environmental parameters was established. Protein content varied from 2.78 ± 0.30% of dry weight (stn.3) to 16.03 ± 0.96% of dry weight (stn.1) with highest values during monsoon. The protein levels were positively correlated with dissolved nitrate content and negatively correlated with water temperature (except stn.3) and salinity. Carbohydrate content of this species varied significantly (p < 0.05) during pre-monsoon between stations and the values showed positive relationship with salinity and surface water temperature. In contrast to carbohydrate, lipid concentration was lowest in values and varied very slightly between seasons and stations. Astaxanthin content of the seaweed species was greater in pre-monsoon than monsoon and post-monsoon in all the selected stations. Compared with the three seasons, samples of red seaweed collected in pre-monsoon has high carbohydrate-astaxanthin in contrast to protein-lipid which showed high values during monsoon. Statistical analysis computed among the environmental and biochemical parameters suggests the potential role played by the abiotic parameters on biosynthetic pathways of seaweed. This paper also highlights the influence of the nutritional quality of water that can be used for mass cultivation of Catenella repens.     

Analytical solutions of tracer transport in fractured rock associated with precipitation-dissolution reactions

Precipitation-dissolution reactions are important for a number of applications such as isotopic tracer transport in the subsurface. Analytical solutions have been developed for tracer transport in both single-fracture and multiple-fracture systems associated with these reactions under transient and steady-state transport conditions. These solutions also take into account advective transport in fractures and molecular diffusion in the rock matrix. For studying distributions of disturbed tracer concentration (the difference between actual concentration and its equilibrium value), effects of precipitation-dissolution reactions are mathematically equivalent to a “decay” process with a decay constant proportional to the corresponding bulk reaction rate. This important feature significantly simplifies the derivation procedure by taking advantage of the existence of analytical solutions for tracer transport associated with radioactive decay in fractured rock. It is also useful for interpreting tracer breakthrough curves, because the impact of a decay process is relatively easy to analyze. Several illustrative examples are presented, which show that the results are sensitive to fracture spacing, matrix diffusion coefficient (fracture surface area), and bulk reaction rate (or “decay” constant), indicating that the relevant flow and transport parameters may be estimated by analyzing tracer signals.     

Timescales of disequilibrium melting in the crust: constraints from modelling the distribution of multiple trace elements and a case study from the Lesser Himalayan rocks of Sikkim

A numerical code has been developed to track the distribution of trace elements in crustal rocks undergoing melting. The model handles diffusion with moving boundaries and accounts for the processes of diffusion, dissolution and precipitation in a partially molten system. Among the various input parameters for modelling, source composition (i.e. modal abundance) variations, diffusion coefficients and partition coefficients are found to exert a significant control on the melt chemistry. The other inputs such as melt reaction stoichiometry, kinetics of melting and grain size of protolith have lesser influence. Exploration of the general behaviour indicates that for systems in which disequilibrium melting of the kind considered in this paper occurs, trace element concentrations may be used to constrain the composition of the protolith or the timescales of melting, depending on the specific circumstances. After exploring some general features of melting in a pelitic system, the model is applied to calculate trace element distributions in migmatites from the Lesser Himalayan rocks in Sikkim, India. We focus on the distribution of trace elements during the initial stages of melt formation. These partially molten rocks show disequilibrium distribution of trace elements, and the numerical code is capable of quantitatively reproducing many of the observed patterns. The results of the modelling indicate that the observed melts in this zone were formed within 50,000 years and that segregation of melts (into leucosome and restite) was complete between 50,000 and 250,000 years. These short timescales may point to deformation-enhanced melt segregation at least on a hand specimen scale. It is important to distinguish between timescales of segregation over these scales and timescales of removal of melt on an outcrop scale to form plutons—the latter, requiring higher degrees of melting and larger distances of migration, take longer.     

Runoff generation mechanisms in pastures of the Sand Mountain region of Alabama—a field investigation

Excessive application of poultry litter to pastures in the Sand Mountain region of north Alabama has resulted in phosphorus (P) contamination of surface water bodies and buildup of P in soils of this region. Since surface runoff is recognized as the primary mechanism of P transport, understanding surface runoff generation mechanisms are crucial for alleviating water quality problems in this region. Identification of surface runoff generation mechanisms is also important for delineation of hydrologically active areas (HAAs). Therefore, the specific objective of this study was to identify surface runoff generation mechanisms (infiltration excess versus saturation excess) using distributed surface and subsurface sensors and rain gauge. Results from three rainfall events (2·13–3·43 cm) of differing characteristics, and sensor data at four locations with differing soil hydraulic properties along the hillslope showed that the main surface runoff generation mechanism in this region is infiltration excess. Because of this, rainfall intensity and soil hydraulic conductivity were found to play dominant roles in surface runoff generation in this region. Further, only short periods of a few rainfall events during which the rainfall intensity is high produce surface runoff. This study indicates that perhaps subsurface flows and transport of P in subsurface flows need to be quantified to reduce P contamination of surface water bodies in this region. Current studies at this location are identifying spatial and temporal distribution of HAAs, quantifying rainfall characteristics that generate runoff, and estimating runoff volume that results from connected HAAs. Copyright © 2008 John Wiley & Sons, Ltd.     

Alkaline Magmatism Versus Collision Tectonics in the Eastern Ghats Belt, India: Constraints from Structural Studies in the Koraput Complex

Linear domains of deformed alkaline rocks and carbonatites have recently been identified as representing sites of ancient suture zones. In peninsular India, the western margin of the Proterozoic Eastern Ghats Belt (EGB) is characterized by a series of alkaline plutons that are aligned close to the contact with the Archaean Craton. Most of the complexes were deformed and metamorphosed during a subsequent orogenic event. Unlike other plutons in the belt, the alkaline complex at Koraput reportedly escaped deformation and granulite facies metamorphism forming an anomalous entity within the zone. Multiply-deformed country rocks hosting this complex underwent syn-D_1CR granulite facies metamorphism followed by D_2CR thrusting, with pervasive shearing along a NE-SW trending foliation. A second granulite facies event followed localized D_3CR shearing. Within the Koraput Complex, strain partitioning was responsible for preserving igneous textures in the gabbroic core, but aligned magmatic amphibole needles and plagioclase laths occasionally define a S_1AC fabric. Along the margins, S_1AC is rotated parallel to a NE-trending, east-dipping S_2AC fabric in the gabbro, fringing syenodiorite and nepheline syenite bands. Locally, D_3AC shearing follows D_2AC deformation; S_2AC and S_3AC parallel S_2CR and S_3CR in the country rocks. High-grade metamorphism represented by recrystallization of amphibole and plagioclase, and breakdown of amphibole and biotite to garnet, pyroxene and K-feldspar in the complex follows D_3AC. Unlike earlier reports, therefore, the Koraput body is also deformed and metamorphosed. The aligned alkaline complexes in the EGB probably represent deformed alkaline rocks and carbonatites formed by rifting related to an earlier episode of continental break-up that were deformed during subsequent juxtaposition of the EGB with the Archaean Craton. This supports the contention that the western margin of the EGB and its contact with the Archaean Craton is a suture zone related to the Indo-Antarctica collision event.     

Rates of hydrothermal cooling of new oceanic upper crust derived from lithium-geospeedometry

Episodic emplacement and cooling of lavas and dikes at mid-ocean ridges leads to large fluctuations in hydrothermal fluxes and biological activity. However, the processes operating beneath the seafloor during these transient events such as permeability creation and dike cooling are poorly understood. We have developed a new approach to determine the cooling rate of the sheeted dike complex based on the extent of diffusion of lithium from plagioclase into clinopyroxene during cooling. We have calibrated this Li-geospeedometer using new high-temperature experiments to determine both the temperature dependence of the partitioning of Li between plagioclase and clinopyroxene and the diffusion coefficient for Li in clinopyroxene. Application of this method to lavas and dikes from ODP Hole 504B shows that cooling rates vary dramatically with depth in the upper oceanic crust. Extremely rapid cooling rates (> 450 °C hr^− 1) in the upper part of the sheeted dike complex are sufficient to power hydrothermal megaplume formation within the overlying water column.     

Some aspects of the role of intergranular fluids in the compositional evolution of metamorphic rocks

Minerals that react with each other during the progressive evolution of metamorphic terranes are not always in physical contact. As such, an “intergranular fluid” could play a major role in element transfer and chemical evolution. However, the nature of this fluid and its specific role remains somewhat elusive. Recent experiments in our laboratory shed some light on the behavior of such a fluid. Here we present a simple mathematical model which accounts for diffusion within crystals and fluid, solubility in the fluid and mass balance between the various reservoirs. The model elucidates the nature of element exchange between two minerals via the mediation of an intergranular fluid. It is shown that a coupling of thermodynamics and kinetics controls the evolution of the system and the concentration of an element in the intergranular fluid is a key parameter of interest. The results have important implications for standard tools of metamorphic petrology such as geothermometers and barometers, geospeedometry and the closure of isotopic systems. For example, homogeneity of mineral grains may be a poor criterion for equilibrium and the rim compositions of minerals showing diffusion zoning may be out of equilibrium with distant exchange partners, even in the presence of a fluid in which transport is fast.     

Study of variation of aerosol optical properties over a high altitude station in Indian Western Himalayan region,palampur using raman lidar system

A Raman lidar system was operated along with the Microtops sunphotometer measurements to carry out the study of the variation of the optical properties of aerosols over Palampur (32.11° N and 76.53° E), India from 17th April to 11th May 2019. The lidar system is furnished with Raman (N₂) channel and depolarization channel allowing independent measurement of Lidar Ratio (LR) and linear depolarization ratio. The study reveals that the majority of the aerosols approximately were restricted within the planetary boundary layer (PBL) and very less loading was present in the free troposphere over the study location. The particle loading over the study period was found to be very less with aerosol backscatter coefficient (at 355 nm) ranging from ～0.13 Mm^?1sr^?1 to ～7.25 Mm^?1sr^?1 with mean value of 2.67?±?0.82 Mm^?1sr^?1 and it is well supplemented by the mean aerosol optical depth (AOD) of 0.37?±?0.13 obtained from Microtops Sunphotometer. The average lidar ratio values for 0-1 km altitude (L1) 72?±?13sr, for 1-2 km (L2) altitude 55?±?8sr, for 2-3 km (L3) 54?±?15sr were observed as suggesting dominance of the biomass burning aerosols and anthropogenic aerosols. The particle depolarization ratio (355 nm) values were found from approximately 4.8?±?2.7% to 11.5?±?1.9% with the mean value of 7?±?1.3% suggesting the presence of non-spherical particles. To trace the sources of the pollution, we derived the HYSPLIT trajectory which shows the majority of the movement was from local sources.

     

Geochemical appraisal of mine discharge and tailing at Malanjkhand copper mine,India

Geophysical investigation using Vertical Electrical Sounding (VES), Electrical Resistivity Tomography (ERT) and Seismic Refraction at a proposed conference center site along Ajibode-Labani road, Ibadan, southwestern Nigeria has been carried out. The investigation aims at characterizing and delineating the subsurface strata to understand the weathered profile at the site. Understanding the weathered profile is essential in determining the suitability of the site for engineering construction of the future conference center. A total of 25 VES and 10 ERT profiles were acquired in a systematic grid pattern using both Schlumberger andWenner configurations with Allied omega terrameter. TheVES data were processed and analyzed using WinResist and the ERT data were inverted using RES2DINV. The data were combined to form a 3-D data set of the site and RES3DINV was used to produce the depth slices. Seismic refraction data were also acquired with an ABEM seismograph and processed using SeisImager and Fajseis software. Seismic data were used in understanding the velocity distribution and thickness. The results of VES, ERT and seismic refraction show good correlation. Four sub-surface layers were delineated: top layer of reworked sand, clayey sand/ lateritic hard pan, clay/ sandy clay and fracture/ fresh basement. The 3-D model permits a pictorial view of the sub-surface in relation to materials that overlie the basement. The thickness of unconsolidated materials to bedrock varies from 2.7 m to 12.2 m which revealed inhomogeneity in weathering under the shallow sub-surface. It is found that the integrated geophysical tool is well suited to characterize and delineate sub-surface structure (weathered profile) for engineering site characterization.     

Complex vertical migration of larvae of the ghost shrimp, Nihonotrypaea harmandi, in inner shelf waters of western Kyushu,Japan

The position of meroplanktonic larvae in the water column with depth-dependent current velocities determines horizontal transport trajectories. For those larvae occurring in inner shelf waters, little is known about how combined diel and tidally-synchronized vertical migration patterns shift ontogenetically. The vertical migration of larvae of Nihonotrypaea harmandi (Decapoda: Thalassinidea: Callianassidae) was investigated in mesotidal, inner shelf waters of western Kyushu, Japan in July–August 2006. The larval sampling at seven depth layers down to 60 m was conducted every 3 h for 36 h in a 68.5-m deep area 10 km off a major coastal adult habitat. Within a 61–65-m deep area 5–7.5 km off the adult habitat, water temperature, salinity, chlorophyll a concentration, and photon flux density were measured, and water currents there were characterized from harmonic analysis of current meter data collected in 2008. The water column was stratified, with pycnocline, chlorophyll a concentration maximum, and 2% of photon flux density at 2 m, recorded at around 22–24 m. The stratified residual currents were detected in their north component, directed offshore and onshore in the upper and lower mixed layers, respectively. More than 87% of larvae occurred between 20 m and 60 m, producing a net onshore transport of approximately 1.3 km d⁻¹. At the sunset flooding tide, all zoeal-stage larvae ascended, which could further promote retention (1.4-km potential onshore transport in 3 h). The actual onshore transport of larvae was detected by observing their occurrence pattern in a shallow embayment area with the adult habitat for 24 h in October 1994. However, ontogenetic differences in the vertical migration pattern in inner shelf waters were also apparent, with the maximum mean positions of zoeae deepening with increasing stages. Zoeae I and II performed a reverse diel migration, with their minimum and maximum depths being reached around noon and midnight, respectively. Zoeae IV and V descended continuously. Zoeae III had behaviors that were intermediate to those of the earlier- and later-stage zoeae. Postlarvae underwent a normal diel migration (nocturnal ascent) regardless of tides, with the deepest position (below 60 m and/or on the bottom) during the day. These findings give a new perspective towards how complex vertical migration patterns in meroplanktonic larvae enable their retention in inner shelf waters before the final entry of postlarvae into their natal populations.