Biodegradation of starch blended polyvinyl chloride films by isolated Phanerochaete chrysosporium PV1

The accumulation of plastics in the environment is raising great concerns with respect to long-term environmental, economic and waste management problems. The aim of the present research was to investigate the biodegradability of starch blended polyvinyl chloride films in soil burial and controlled laboratory experiments using selective fungal isolates. Clear surface aberrations as color change and minor disintegration in polyvinyl chloride films were observed after 90 days and later confirmed through scanning electron microscopy. The fungal strains showing prominent growth and adherence on plastic films were isolated. One of the strains showing maximum activity was selected and identified as Phanerochaete chrysosporium PV1 by rDNA sequencing. Fourier transform infrared spectroscopy and nuclear magnetic resonance analyses indicated considerable structural changes and transformation in films in terms of appearance of new peaks at 3,077 cm^?1 (corresponding to alkenes) and decrease in intensity of peaks at 2,911 cm^?1 (C–H stretching). It was supported with a significant decrease in the molecular weight of polymer film from 80,275 to 78,866 Da (treated) through Gel permeation chromatography in shake flask experiment. Moreover, the biodegradation of starch blended polyvinyl chloride films was confirmed through release of higher CO₂ (7.85 g/l) compared to control (2.32 g/l) in respirometric method. So fungal strain P. chrysosporium PV1 has great potential for use in bioremediation of plastic waste.     

Weather regimes over Senegal during the summer monsoon season using self-organizing maps and hierarchical ascendant classification. Part II: interannual time scale

The aim of this work is to define over the period 1979–2002 the main synoptic weather regimes relevant for understanding the daily variability of rainfall during the summer monsoon season over Senegal. “Interannual” synoptic weather regimes are defined by removing the influence of the mean 1979–2002 seasonal cycle. This is different from Part I where the seasonal evolution of each year was removed, then removing also the contribution of interannual variability. As in Part I, the self-organizing maps approach, a clustering methodology based on non-linear artificial neural network, is combined with a hierarchical ascendant classification to compute these regimes. Nine weather regimes are identified using the mean sea level pressure and 850?hPa wind field as variables. The composite circulation patterns of all these nine weather regimes are very consistent with the associated anomaly patterns of precipitable water, mid-troposphere vertical velocity and rainfall. They are also consistent with the distribution of rainfall extremes. These regimes have been then gathered into different groups. A first group of four regimes is included in an inner circuit and is characterized by a modulation of the semi-permanent trough located along the western coast of West Africa and an opposite modulation on the east. This circuit is important because it associates the two wettest and highly persistent weather regimes over Senegal with the driest and the most persistent one. One derivation of this circuit is highlighted, including the two driest regimes and the most persistent one, what can provide important dry sequences occurrence. An exit of this circuit is characterised by a filling of the Saharan heat low. An entry into the main circuit includes a southward location of the Saharan heat low followed by its deepening. The last weather regime is isolated from the other ones and it has no significant impact on Senegal. It is present in June and September, and missing in July and August, meaning that this is a weather regime more specific of the intermediate seasons than the summer. It is included in a large-scale pattern covering the northern latitudes of Europe. The correspondence between these “interannual” synoptic weather regimes and the “pure” synoptic regimes defined in Part I has been established. By selecting a high statistical significance level for these correspondences, each of five out of nine “interannual” weather regimes has a close correspondence with one “pure” synoptic weather regime, one out of them have links with two “pure” regimes, and the last three regimes have no significant correspondence in terms of “pure” regimes. However when considering more moderate links, two out of these three regimes show a connection with a “pure” regime, and the last one remains isolated. The ensemble of the weather regimes occurrences can explain a significant part of interannual variability of summer rainfall amount over Senegal, especially linked to the driest and the wettest weather regimes occurrences. It is also shown that Senegal rainfall state is very sensitive to a small displacement or deformation of the weather regime patterns.     

Use of treated wastewater for managed aquifer recharge in highly populated urban centers: a case study in Addis Ababa,Ethiopia

Fast population growth and rapid industrialization, on one hand, and lack of sewerage network and poor living condition, on the other, have led to the deterioration of surface and ground water quality in the city of Addis Ababa. The urban wastewater is discharged largely into streams that drain the city. Only less than 3% join the wastewater treatment facilities. Due to sporadic rainfall that causes shortage in groundwater recharge, managed aquifer recharge (MAR) experiment was tested on soil column collected from Akaki Well Field which is located in the southern part of the city using water from the Big Akaki River that crosses the same well field and effluent from Kaliti Wastewater Treatment Plant. Water quality analysis for 17 different parameters was done for both the inflow and outflow water samples and soils were tested for electrical conductivity and cation exchange capacity. The results indicate improved water quality as a result of higher attenuation/filtration capacity of the vadose zone in the well field due to the presence of vertisols. The main geochemical processes that have acted in the soil column could be cation exchange, dissolution, precipitation, oxidation, nitrification, die off etc. that are responsible for the effectiveness of vadose zone for MAR.