Adsorption Kinetics,Isotherms, and Desorption of Monocrotophos and Dichlorvos on Various Indian Soils

Pesticide sorption on to the soil has a significant role in deciding the fate and behavior of pesticides in soil and aquatic environment. The present study investigates the adsorption of monocrotophos (MCP) and dichlorvos (DDVP) on the three soils of Malwa region of Punjab, India under different conditions. Batch adsorption experiments were preformed in replicates using 2 g of air‐dried soil and varying concentrations of pesticides and 20 mL of 0.01 M CaCl₂ as background electrolyte. The results revealed high adsorption of MCP and DDVP in soil B with k_f‐values 0.1261 and 0.0498 and n‐values 2.7345 and 1.831, respectively. The adsorption isotherms obtained were analyzed and the data was subjected to classical Langmuir, Freundlich, and Temkin models. The experimental data best fitted to the logarithm form of Freundlich and Temkin model. Kinetics analyses were performed using pseudo‐first order, pseudo‐second order, and intraparticle diffusion models. The regression results showed that the experimental data fitted very well with the pseudo‐second order kinetic model as correlation coefficient value is very closer to 1 and also followed the intraparticle diffusion model, whereas, diffusion is not only the rate controlling step. The percentages desorption with tap and distilled water is 32–64% for MCP and 25–48% for DDVP.     

Reduction in chlorophenolic compounds during bleaching of rice straw pulp by replacing elemental chlorine with chlorine dioxide

Speedy running down of forest cover has put great stress on paper industry for finding new fibrous raw materials. Rice straw is an abundantly available lignocellulosic material especially in wood-short countries and can be utilized as an alternate fibre resource by paper mills. Bleaching is a crucial step in papermaking that involves the chemical reactions to reduce the colour of the pulp and makes it brighter for manufacturing writing and printing grade paper. Contrary to this, bleaching results into the formation of toxic, biorefractory and carcinogenic chlorolignin compounds that pose serious health hazards to aquatic life and human beings. A study was carried out using rice straw soda-AQ pulp for bleaching with sequence based on elemental chlorine (CE_OPHH). Further, to reduce the wastewater pollution load, emphasis was given on replacement of elemental chlorine with chlorine dioxide at the first bleaching stage (C_D10E_OPHH C_D30E_OPHH and C_D50E_OPHH) and elemental chlorine-free (ECF) bleaching (DE_OPD). The study revealed that generation of chlorophenolic compounds was the highest in CE_OPHH sequence followed by C_D10E_OPHH C_D30E_OPHH and C_D50E_OPHH, i.e. 6047, 4765, 4247 and 3864 mg/t, respectively. In DE_OPD bleaching sequence, the generation of chlorophenolic compounds in wastewater was reduced to 421 mg/t. ECF bleaching had major impacts on reduction in chloroguaiacols (97%) and chlorophenols (92%) that were in the highest quantity in effluents of CE_OPHH bleaching sequence. DE_OPD bleaching was found to be a promising option for pulp and paper industry for cutting down the generation of chlorophenolic compounds in bleaching effluents.     

Delineation of potential fluoride contamination zones in Birbhum,West Bengal,India, using remote sensing and GIS techniques

Birbhum district in West Bengal, India, is one of the most severely affected districts by fluoride-contaminated groundwater. Fluoride content as high as 20.4 mg/L has been reported. Several cases of fluoride-related disorder such as dental fluorosis and skeletal fluorosis have been reported to be endemic in the district. Proper management of groundwater is very crucial. This contribution has been carried out for delineating potential fluoride-contaminated zones (PFCZ) in Birbhum district with the implementation of weighted overlay analysis in GIS environment. Twelve different potentially influential environmental parameters are integrated and evaluated. The final output map was categorised into two subclasses, i.e. ‘low’ and ‘high’, where the low region represents fluoride concentration of 1.5 mg/L and below and the high region represents fluoride concentration above 1.5 mg/L. The outcome reveals that approximately 24.35% of the study area falls under PFCZ, whereas about 75.65% of the study area falls under the safe zone with respect to potential fluoride contamination. On validation of the PFCZ, the reported fluoride contamination data in groundwater shows an overall 87.50% accuracy in prediction via superimposition method and 89.06 and 85.85% success and prediction rates, respectively, when validated with success and prediction rates.     

Recent changes in the spatio-temporal characteristics of monsoon intraseasonal oscillations

Theoretical and Applied Climatology - Monsoon intraseasonal oscillations (MISOs) define a significant proportion of intraseasonal variability of the Indian summer monsoon. In the backdrop of...     

Differential Rotation in Self Gravitating Filaments

The effect of differential rotation on the equilibria of self-gravitating filaments has been examined for isothermal and logatropic equations of state (EOS). Parametric regions for existence of solutions and upper limits for (the ratio of the rotational kinetic energy to the gravitational potential energy) have been worked out for the different laws of rotation. Effect of magnetic field has also been discussed.     

Robe’s restricted problem of 2+2 bodies when the bigger primary is a Roche ellipsoid and the smaller primary is an oblate body

In this problem, one of the primaries of mass m ₁ is a Roche ellipsoid filled with a homogeneous incompressible fluid of density ρ ₁. The smaller primary of mass m ₂ is an oblate body outside the Ellipsoid. The third and the fourth bodies (of mass m ₃ and m ₄ respectively) are small solid spheres of density ρ ₃ and ρ ₄ respectively inside the Ellipsoid, with the assumption that the mass and the radius of the third and the fourth body are infinitesimal. We assume that m ₂ is describing a circle around m ₁. The masses m ₃ and m ₄ mutually attract each other, do not influence the motions of m ₁ and m ₂ but are influenced by them. We have extended the Robe’s restricted three-body problem to 2+2 body problem under the assumption that the fluid body assumes the shape of the Roche ellipsoid (Chandrashekhar in Ellipsoidal figures of equilibrium, Chap. 8, Dover, New York, 1987). We have taken into consideration all the three components of the pressure field in deriving the expression for the buoyancy force viz (i) due to the own gravitational field of the fluid (ii) that originating in the attraction of m ₂ (iii) that arising from the centrifugal force. In this paper, equilibrium solutions of m ₃ and m ₄ and their linear stability are analyzed. We have proved that there exist only six equilibrium solutions of the system, provided they lie within the Roche ellipsoid. In a system where the primaries are considered as Earth-Moon and m ₃,m ₄ as submarines, the equilibrium solutions of m ₃ and m ₄ respectively when the displacement is given in the direction of x ₁-axis or x ₂-axis are unstable.     

Reflection and refraction of SH‐waves at a corrugated interface between two monoclinic elastic half‐spaces

A problem of reflection and transmission of shear wave incident upon a corrugated interface between two monoclinic solid half‐spaces have been investigated. Rayleigh's method of approximation is used to investigate the reflection and transmission coefficients for first and second approximation of the corrugation. For a special interface, closed‐form expressions of these coefficients for the first order approximation of the corrugation are obtained. It is found that these coefficients are functions of amplitude of corrugation, elastic parameters of the media, frequency of the incident wave and angle of incidence. The numerical computations are performed for a specific model and the results obtained are presented graphically. It is found that the reflection and transmission coefficients are strongly influenced by the corrugation and the elastic properties of the media. Results of some earlier workers in this field have been reduced as particular case from the present formulation. Copyright © 2004 John Wiley & Sons, Ltd.     

Nature of magmatism and sedimentation at a Columbia active margin: Insights from combined U–Pb and Lu–Hf isotope data of detrital zircons from NW India

Detrital zircons from a Palaeoproterozoic quartzite, deposited between 1.85 and 1.82 Ga in the northern Aravalli orogen of NW India, show a distinctive age peak of ca. 1.85 Ga and variable, but largely subchondritic εHf_{1.85 Ga} between ? 1.3 and ? 21.0 corresponding to hafnium model ages of 2.5 to 3.6 Ga. These data indicate an important period of reworking of ancient (Eo- to Neoarchaean), strongly heterogeneous continental crust at this time. Prevalence of ca. 1.85 Ga subduction-related granitoids, almost identical U–Pb age spectra and εHf_t of detrital zircons in ca. 1.85 Ga metasedimentary rocks in the Aravalli orogen and the inner Lesser Himalaya indicate similar sediment provenances and thus a geological connection between these two terranes during late Palaeoproterozoic. All together, the data constrain a rapid succession of sedimentation, metamorphism and subduction-related magmatic activity and support the interpretation of an active geodynamic realm along the entire north Indian margin at ca. 1.85 Ga. Comparison of detrital zircon data in conjunction with published paleomagnetic data from north India and other crustal blocks of the Columbia supercontinent, additionally, suggest a close affinity of north India with Madagascar, the Cathaysia block of South China and South Korea during Columbia times.     

Quality Assessment of Atmospheric Motion Vectors Over the Indian Ocean

Because conventional observations over the oceans are not available, especially during tropical cyclones, multi-spectral atmospheric motion vectors (AMVs) estimated from geostationary satellites are routinely assimilated in the numerical weather prediction models at different operational centres across the globe. The derived AMVs are generally validated with radiosonde observations available over land at synoptic hours; however, over the ocean there is a limited scope to assess the quality of AMVs. Over ocean, AMVs can be validated with radiosonde data available from opportunistic ships or using dropsonde data available from aircrafts. In this study, the accuracy of the AMVs derived from the geostationary satellites Kalpana-1 and Meteosat-7 is evaluated over the oceanic region. Radiosonde data available from a ship cruise held in the Bay of Bengal during the period 09 July–08 August 2012 and from the Cal/Val site situated at Kavaratti Island (72.62°E, 10.57°N) in the southern Indian Ocean are used to assess the AMV accuracy. In this study, 83 radiosonde profiles are used to validate the Kalpana-1 AMVs, to allow a better understanding of AMV errors over the Indian Ocean. The RMSVD of Kalpana-1 AMVs for the high-, mid- and low-levels are found to be 7.9, 9.4 and 5.3 m s^?1, respectively, while the corresponding RMSVD for Meteosat-7 AMVs are 9.1, 5.5 and 3.7 m s^?1. A similar accuracy is observed when the AMVs are validated against the NCEP analyses collocated with the nearest radiosonde locations. The high RMSVD and bias for Kalpana-1 AMVs at the mid-level and Meteosat-7 AMVs at the high-level are associated with the limitation of satellite winds to resolve the upper-level easterly jet in conjunction with errors in the height assignment. This study could help the numerical modellers to assign appropriate observation error over this region during the assimilation of AMVs into the NWP models.     

The preparation and characterization of vanadium-substituted goethite: The importance of temperature

Despite a close geo-chemical association between vanadium (V) and iron (Fe) in natural environments, there is little research on the substitution of V in goethite. To assess the effect of temperature on V-substitution in goethite, a series of V-substituted goethite were prepared under varying synthesis temperatures, and analysed using wet chemical and multi-spectroscopic techniques. Vanadium substitution was inversely related to synthesis temperatures and was hindered by the oxidation of V³⁺ to V^4+/5+ as indicated by X-ray absorption near-edge spectroscopy. The presence of V (V⁵⁺ > V⁴⁺ > V³⁺) at high temperature hindered the nucleation of goethite and crystal growth along particular faces resulting in large-sized and twinned crystals as shown by transmission electron microscopy. The large-sized goethite crystals released more Fe (mmoles) per unit surface area during proton-promoted dissolution than the smaller-sized crystals, which could be due to distorted V^4+/5+ local coordination environments in the mineral structure. The dissolution studies showed a heterogeneous distribution of V and/or crystal defects in goethite crystals. The results show that low synthesis temperatures preserved the oxidation state of V³⁺, which has ionic radius and hydrolytic properties similar to Fe³⁺, and hence resulted in as much as 13.3 mol per cent substitution. The structural stability of the goethite decreased upon V-substitution in order; V³⁺ > V⁴⁺ > V⁵⁺. This research provides important information about the interaction between temperature, V incorporation, and crystal structure properties of goethite for V sequestration and other potentially toxic metal cations.