The α-β phase transition in AlPO4 cristobalite: Symmetry analysis,domain structure and transition dynamics

Despite their crystallographic differences, the mechanisms of the α-β phase transitions in the cristobalite phases of SiO₂ and AlPO₄ are very similar. The β→α transition in AlPO₄ cristobalite is from cubic ( $\left( {F\bar 43m} \right)$ ) to orthorhombic (C222₁), whereas that in SiO₂ cristobalite is from cubic ( $\left( {Fd\bar 3m} \right)$ ) to tetragonal (P4₃2₁2 or P4₁2₁2). These crystallographic differences stem from the fact that there are two distinct cation positions in AlPO₄ cristobalite as opposed to one in SiO₂ cristobalite and the ordered (Al,P) distribution is retained through the phase transition. As a result, there are significant differences in their crystal structures, domain configurations resulting from the phase transition and Landau free energy expressions. A symmetry analysis of the “improper ferroelastic” transition from $F\bar 43m \to C222_1$ in AlPO₄ cristobalite has been carried out based on the Landau formalism and the projection operator methods. The six-component order parameter, η driving the phase transition transforms as the X₅ representation of $F\bar 43m$ and corresponds to the simultaneous translation and rotation of the [AlO₄] and [PO₄] tetrahedra coupled along 110. The Landau free energy expression contains a third order invariant, the minimization of which requires a first-order transition, consistent with experimental results. The tetrahedral configurations of twelve α phase domains resulting from the β→α transition in AlPO₄ cristobalite are of two types: (1) transformation twins from a loss of the 3-fold axis, and (2) antiphase domains from the loss of the translation vectors 1/2[101] and 1/2[011] (F→C). In contrast to α-SiO₂ cristobalite, the α-AlPO₄ cristobalite (C222₁) does not have chiral elements (4₃, 4₁) and hence, enantiomorphous domains are absent. These transformation domains are essentially macroscopic and static in the α phase and microscopic and dynamic in the β phase. The order parameter, η couples with the strain components, which initiates the structural fluctuations causing the domain configurations to dynamically interchange in the β phase. An analysis of the MAS NMR data (²⁹Si, ¹⁷O, ²⁷Al) on the α α-β transitions in SiO₂ and AlPO₄ cristobalites (Spearing et al. 1992, Phillips et al. 1993) essentially confirms the dynamical model proposed earlier for SiO₂ cristobalite (Hatch and Ghose 1991) and yields a detailed picture of the transition dynamics. In both cases, small atomic clusters with the configuration of the low temperature α phase persist considerably above the transition temperature, T₀. The NMR data on the β phases above T₀ cannot be explained by a softening of the tetrahedral rotational and translational modes alone, but require the onset of an order-disorder mechanism resulting in a dynamic averaging due to rapidly changing domain configurations considerably below T₀.     

Calculation of coronal line intensities for boron-like ions

New atomic data (Saha and Trefftz, 1982a) have been used to calculate line intensities of S xii for the physical conditions found in the solar corona. They are compared with similar calculations for S ix (Saha and Trefftz, 1982b) and with published work. For the density sensitive intensity ratio I ₂₂₇/I2₂₁₈ the new values give the observed ratio (Malinovski and Heroux, 1973) for an electron density of logN _e = 8.5 which is more likely than the density deduced from the values of Flower and Nussbaumer (1975), logN _e ? 7.     

http://www.sciencedirect.com/science/article/pii/S1674987114000899

The Rajahmundry Trap Basalts（RTB） are erupted through fault-controlled fissures in the Krishna-Godavari Basin（K-G Basin） of Godavari Triple Junction,occurring as a unique outcrop sandwiched between Cretaceous and Tertiary sediments along the east coast of India.Detailed geochemical studies have revealed that RTB are mid-Ti（1.74-1.92） to high-Ti（2.04-2.81） basalts with a distinct quartz tholeiitic parentage.MgO（6.2-13.12 wt.%）,Mg^#（29-50） and Zr（109-202 ppm） suggest that these basalts evolved by fractional crystallization during the ascent of the parent magma along deep-seated fractures.Moderate to high fractionation of HREE,as indicated by（Gd/Yb）N ratios（1.71-2.31） of RTB,suggest their generation through 3-5%melting of a Fe-rich mantle corresponding to the stability fields of spinel and garnet peridotite at depths of 60-100 km.Low K₂O/P₂O₅（0.26-1.26）,high TiO₂/P₂O₅（6.74-16.79）,La/Nb（0.89-1.45）,Nb/Th > 8（8.35-13）,negative anomalies at Rb reflect minimum contamination by granitic continental crust.（Nb/La）_PM ratios（0.66-1.1） of RTB are attributed to endogenic contamination resulted through recycling of subducted oceanic slab into the mantle.Pronounced Ba enrichment with relative depletion in Rb indicates assimilation of Infra- and Inter-trappean sediments of estuarine to shallow marine character.Geochemical compositions such as Al₂O₃/TiO₂（3.88-6.83）,medium to high TiO₂（1.74-2.81 wt.%）.positive Nb anomalies and LREE enrichment of these RTB attest to their mantle plume origin and indicate the generation of parent magma from a plume-related enriched mantle source with EM 1signature.Ba/Th（46-247）,Ba/La（3.96-28.51） and Th/Nb（0.08-0.13） ratios suggest that the source enrichment process was marked by recycling of subduction-processed oceanic crust and lithospheric components into the mantle.Zr/Hf（37-41） and Zr/Ba（0.51-3.24） indicate involvement of an asthenospheric mantle source.The Rajahmundry basalts show affinity towards FOZO（focal zone mantle） and PSCL（post-Archaean subcontinental lithosphere） which reflect mixing between asthenospheric and lithospheric mantle components in their source.Origin of RTB magma is attributed to plume-lithosphere interaction and the upward movement of melt is facilitated by intrabasinal deep-seated faults in the K-G Basin.     

Influence of Eurasian snow on Indian summer monsoon in NCEP CFSv2 freerun

The latest version of the state-of-the-art global land–atmosphere–ocean coupled climate forecast system of NCEP has shown considerable improvement in various aspects of the Indian summer monsoon. However, climatological mean dry bias over the Indian sub-continent is further increased as compared to the previous version. Here we have attempted to link this dry bias with climatological mean bias in the Eurasian winter/spring snow, which is one of the important predictors of the Indian summer monsoon rainfall (ISMR). Simulation of interannual variability of the Eurasian snow and its teleconnection with the ISMR are quite reasonable in the model. Using composite analysis it is shown that a positive snow anomaly, which is comparable to the systematic bias in the model, results into significant decrease in the summer monsoon rainfall over the central India and part of the Equatorial Indian Ocean. Decrease in the summer monsoon rainfall is also found to be linked with weaker northward propagation of intraseasonal oscillation (ISO). A barotropic stationary wave triggered by positive snow anomaly over west Eurasia weakens the upper level monsoon circulation, which in turn reduces the zonal wind shear and hence, weakens the northward propagation of summer monsoon ISOs. A sensitivity experiment by reducing snow fall over Eurasian region causes decrease in winter and spring snow depth, which in turn leads to decrease in Indian summer monsoon rainfall. Results from the sensitivity experiment corroborate with those of composite analysis based on long free run. This study suggests that further improvements in the snow parametrization schemes as well as Arctic sea ice are needed to reduce the Eurasian snow bias during winter/spring, which may reduce the dry bias over Indian sub-continent and hence predictability aspect of the model.     

Sea level rise and South Florida coastal forests

Coastal ecosystems lie at the forefront of sea level rise. We posit that before the onset of actual inundation, sea level rise will influence the species composition of coastal hardwood hammocks and buttonwood (Conocarpus erectus L.) forests of the Everglades National Park based on tolerance to drought and salinity. Precipitation is the major water source in coastal hammocks and is stored in the soil vadose zone, but vadose water will diminish with the rising water table as a consequence of sea level rise, thereby subjecting plants to salt water stress. A model is used to demonstrate that the constraining effect of salinity on transpiration limits the distribution of freshwater-dependent communities. Field data collected in hardwood hammocks and coastal buttonwood forests over 11 years show that halophytes have replaced glycophytes. We establish that sea level rise threatens 21 rare coastal species in Everglades National Park and estimate the relative risk to each species using basic life history and population traits. We review salinity conditions in the estuarine region over 1999?C2009 and associate wide variability in the extent of the annual seawater intrusion to variation in freshwater inflows and precipitation. We also examine species composition in coastal and inland hammocks in connection with distance from the coast, depth to water table, and groundwater salinity. Though this study focuses on coastal forests and rare species of South Florida, it has implications for coastal forests threatened by saltwater intrusion across the globe.     

Recharge mechanism and processes controlling groundwater chemistry in a Precambrian sedimentary terrain: a case study from Central India

Unplanned and unsustainable extraction has created stress on groundwater resources in many parts of India. The stress symptoms are more pronounced in hard rock areas, where the aquifer potentials are comparatively low. Present research targeted an area of 3000 km² in the interstream region between the Kharun and Seonath rivers, which is one such region in Central India. In spite of being a water-stressed area, so far, little is understood about processes of recharge, amount of recharge and processes controlling chemical quality, which are key inputs for groundwater management in the area. This study presents an appraisal of recharge mechanism, recharge rate and prevailing water–rock interactions in the study area. Stable isotope composition of groundwater when compared to that of rainfall indicates monsoon rainfall as the primary source of groundwater recharge. Winter rains, which are characteristically enriched in heavier isotopes, do not contribute notably to groundwater recharge. Recharge is rapid with minor or no evaporative enrichment before recharge. Further, analysis of stable isotopes show that ‘macropore recharge’ is dominant in limestone or calcareous shale, covering more than 70% of the study area. Also apparent is the vertical connectivity amongst the aquifers. However, active intermixing of surface water and groundwater is not a predominant process. Annual groundwater recharge from rainfall, as derived from chloride mass balance, is 105.26 million cubic metre. Groundwater is predominantly of bicarbonate type, irrespective of its hydrostratigraphic (lithology) setting. Dissolution of carbonates and gypsum (occurring as veins), weathering of feldspar and ion exchange of clay minerals are amongst the most likely processes controlling the regional groundwater chemistry.     

Petrology and geochemistry of the ultramafic–mafic Mawpyut complex,Meghalaya: a Sylhet trap differentiation centre in northeastern India

The present article describes, for the first time, petrological and geochemical details of the Mawpyut differentiated complex which is related to the Sylhet trap located at Jaintia Hills district, Meghalaya, northeastern India. The Mawpyut complex occurs as an arcuate body that intrudes into the surrounding Shillong Group rocks. The complex in general contains ‘ultramafic’ and ‘mafic’ rocks, as well as minor syenitic veins that postdate the main units. The lithotypes correspond to cumulate and noncumulate units. The cumulate unit is represented by olivine clinopyroxenite, clinopyroxenite, plagioclase‐bearing ultramafic, olivine gabbronorite, mela‐gabbronorite, melagabbro, orthopyroxene gabbro, and gabbro, all with a pronounced cumulus texture. The noncumulate unit is marked by gabbro, monzonite, monzodiorite, and quartzsyenite. The use of several major and trace element variation diagrams suggests that magmatic differentiation led to the formation of cumulate and noncumulate units. In chondrite‐normalized REE diagrams the cumulate rocks show flat LREE and MREE patterns and a moderate positive Eu anomaly (in plagioclase‐bearing ultramafics) due to plagioclase cumulation. The rocks of the noncumulate unit show a strongly fractionated REE pattern and no Eu anomaly. The noncumulate mafic rocks are geochemically comparable to high‐phosphorous/high‐titanium basalts (HPT) indicative of low pressure fractional crystallization. In a primitive mantle‐normalized multielement diagram some of the cumulate rocks show pronounced negative anomalies for K and P, indicating anorogenic mafic magmatism in a within‐plate setting. The rocks of the noncumulate unit show a slight negative anomaly for Yb and a Nb–Ta trough, indicating a subduction‐related signature that perhaps is inherited from subducted sedimentary rocks incorporated during crustal contamination of the derived magma (left after crystal cumulation) with country rocks. Various trace element ratios for the cumulate mafic rocks indicate parent EMI/EMII/HIMU sources with a very limited crustal signature. The noncumulate mafic rocks (corresponding to the derived evolved magma) indicate EMI/EMII/HIMU sources with a pronounced crustal contamination. The Sr–Nd isotopic compositions of the Mawpyut samples typically plot in the continental flood basalt field, with an affinity to the EMII source. The isotopic compositions of the noncumulate rocks also clearly indicate crustal contamination. We suggest that partial melting (involving garnet in the residue) of the enriched mantle source EMI/EMII/HIMU could have derived the parental melt; this melt, in turn, underwent assimilation and fractional crystallization to produce the variety of cumulate‐noncumulate lithologies of the Mawpyut complex. Copyright © 2013 John Wiley & Sons, Ltd.     

Lidar observation of aerosol stratification in the lower troposphere over Pune during pre-monsoon season of 2006

Lidar observations of aerosol vertical distributions in the lower troposphere along with observations of horizontal and vertical winds from collocated UHF radar (Wind Profiler) over a tropical Indian station, Pune during the pre-monsoon season (March–May) of 2006 as part of an ISRO-GBP national campaign (ICARB) have been examined. Lidar vertical profiles showed high aerosol concentrations in the surface layers and a subsequent gradual decrease with height. Results showed the presence of an elevated stratified aerosol layer around 2000–3500m height which persisted throughout the months of March and April. Observed strong vertical gradients in both horizontal and vertical winds in the lower troposphere seem to be a possible cause for the formation of elevated aerosol layers. Further, high daytime temperatures accompanied by dry conditions at the surface help to enhance the aerosol loading in the lower layers over this location.