Texture, microstructure and geochemistry of magnetite from the Banduhurang uranium mine, Singhbhum Shear Zone, India — implications for physico-chemical evolution of magnetite mineralization

The Singhbhum Shear Zone in eastern India is one of the largest repositories of uranium and copper in India. Besides uranium and copper, apatite-magnetite mineralization is widespread in this shear zone. This study aims at deciphering the physico-chemical evolution of magnetite mineralization in relation to progressive shearing integrating field relations, micro-textures, structures and compositions of magnetite in the Banduhurang uranium mine. Apatite-magnetite ores occur as discrete patches, tongues, and veins in the strongly deformed, fine grained quartzchlorite schist. Textures and microstructures of magnetite indicate at least three stages of magnetite formation. Coarsegrained magnetite (magnetite-1) with long, rotational, and complex strain fringes, defined by fibrous and elongate quartz, is assigned to a stage of pre-/early-shearing magnetite formation. Medium grained magnetite (magnetite-2), characterized by single non-rotational strain fringe equivalent to the youngest fringe of magnetite-1, grew likely at the mid-/late-stage of shearing. Fine grained magnetite (magnetite-3) is generally devoid of any pressure shadow. This indicates even a much later stage of formation of this magnetite, presumably towards the closing stage of shearing. Some of the magnetite-1 grains are optically heterogeneous with a dark, pitted Cr-Ti-bearing core overgrown by lighter, fresh rim locally containing pyrite, chalcopyrite, and chlorite inclusions. The cores are also locally characterized by high Al and Si content. Homogeneous magnetite-1 is optically and compositionally similar to the overgrowth of heterogeneous magnetite-1. This homogeneous magnetite-1 that grew as separate phase is contemporaneous with the overgrowth on pitted core of heterogeneous magnetite-1. Magnetite-2 is compositionally very similar to homogeneous magnetite-1, but is devoid of sulfide inclusion. Magnetite-3 is generally devoid of any silicate or sulfide inclusion and is most pure with least concentrations of trace/minor elements. The high Al and Si content in some magnetite can be explained by coupled substitution that involves substitution of Si⁴⁺ for Fe³⁺ in the tetrahedral sites and Fe²⁺ for Fe³⁺ in the octahedral sites, with a simple substitution of Al³⁺ for Fe³⁺ in the octahedral sites. The mode of occurrences of apatite-magnetite ores indicates a predominantly hydrothermal origin of most magnetite. However, the Cr-Ti-bearing magnetite-1 cores and inferred mafic nature of the original protolith indicates that some magnetite was inherited from the original igneous rock. We propose that the pre-/early-shearing hydrothermal event of magnetite formation was associated with sulfide mineralization and alteration of existing magmatic magnetite. The second stage of magnetite formation at the mid-/late-stage of shearing was not associated with sulfide formation. Finally, fine-grained compositionally pure magnetite formed at the closing stage of shearing likely due to metamorphism of Fe-rich protolith.     

Role of convective and microphysical processes on the simulation of monsoon intraseasonal oscillation

Climate Dynamics - The study explores the role of ice-phase microphysics and convection for the better simulation of Indian summer monsoon rainfall (ISMR) and monsoon intraseasonal oscillation...     

Utilities of Virtual 3D City Models Based on CityGML: Various Use Cases

Virtual 3D city models are increasingly being used to model the realms of the real world for utilization in a number of applications related to environmental simulations including, urban planning, mapping the energy characteristics of buildings, noise mapping, flood modelling, etc. Apart from geometric and appearance/textural information, these applications have a requirement for complex urban semantics. Currently, a number of 3D standards are available in CAD, BIM and GIS related domains for the storage, visualization and transfer of 3D geospatial datasets. Initially, the 3D data models (such as COLLADA, VRML, X3D, etc.) were purely graphical/geometrical in nature and mainly used for visualization purposes. With the inclusion of thematic modules in OGC CityGML, the integration of geometry and semantics in a single data model paved the way for better sharing of virtual 3D city models. In spite of the availability of a wide range of 3D data standards, there are certain differences with respect to geometry, topology, semantics, LODs, etc., which complicates the integration of 3D geodata from heterogeneous sources. This paper serves to highlights the need for the innovative solutions with respect to the urban environmental related simulations primarily based on the use of virtual 3D city models. Four use cases are studied in this context namely, (1) urban solar potential estimation using CityGML models, (2) simulation of traffic noise level mapped on building walls from the urban road segments, (3) CityGML based 3D data models interoperability, and (4) 3D indoor logistics and subsurface utilities. However, for modelling majority of use cases, CityGML does not provide explicit thematic representations but provides support for extending the CityGML schema using Application Domain Extensions. In a nutshell, the study explores the semantic modelling capabilities of the CityGML for the transformation of native 3D virtual city models to one satisfying capabilities like semantic information and support towards interoperability.     

Variation of the gas and radiation content in the sub-Keplerian accretion disk around black holes and its impact to the solutions

We investigate the variation of the gas and the radiation pressure in accretion disks during the infall of matter to the black hole and its effect to the flow. While the flow far away from the black hole might be non-relativistic, in the vicinity of the black hole it is expected to be relativistic behaving more like radiation. Therefore, the ratio of gas pressure to total pressure (β) and the underlying polytropic index (γ) should not be constant throughout the flow. We obtain that accretion flows exhibit significant variation of β and then γ, which affects solutions described in the standard literature based on constant β. Certain solutions for a particular set of initial parameters with a constant β do not exist when the variation of β is incorporated appropriately. We model the viscous sub-Keplerian accretion disk with a nonzero component of advection and pressure gradient around black holes by preserving the conservations of mass, momentum, energy, supplemented by the evolution of β. By solving the set of five coupled differential equations, we obtain the thermo-hydrodynamical properties of the flow. We show that during infall, β of the flow could vary up to ∼300%, while γ up to ∼20%. This might have a significant impact to the disk solutions in explaining observed data, e.g. super-luminal jets from disks, luminosity, and then extracting fundamental properties from them. Hence any conclusion based on constant γ and β should be taken with caution and corrected.     

Groundwater arsenic contamination and its health effects in India

During a 28-year field survey in India (1988–2016), groundwater arsenic contamination and its health effects were registered in the states of West Bengal, Jharkhand, Bihar and Uttar Pradesh in the Ganga River flood plain, and the states of Assam and Manipur in the flood plain of Brahamaputra and Imphal rivers. Groundwater of Rajnandgaon village in Chhattisgarh state, which is not in a flood plain, is also arsenic contaminated. More than 170,000 tubewell water samples from the affected states were analyzed and half of the samples had arsenic >10 μg/L (maximum concentration 3,700 μg/L). Chronic exposure to arsenic through drinking water causes various health problems, like dermal, neurological, reproductive and pregnancy effects, cardiovascular effects, diabetes mellitus, diseases of the respiratory and gastrointestinal systems, and cancers, typically involving the skin, lungs, liver, bladder, etc. About 4.5% of the 8,000 children from arsenic-affected villages of affected states were registered with mild to moderate arsenical skin lesions. In the preliminary survey, more than 10,000 patients were registered with different types of arsenic-related signs and symptoms, out of more than 100,000 people screened from affected states. Elevated levels of arsenic were also found in biological samples (urine, hair, nails) of the people living in affected states. The study reveals that the population who had severe arsenical skin lesions may suffer from multiple Bowens/cancers in the long term. Some unusual symptoms, such as burning sensation, skin itching and watering of eyes in the presence of sun light, were also noticed in arsenicosis patients.     

Measuring daytime CO2 fluxes from the inter-tidal mangrove soils of Indian Sundarbans

The aim of this research was to measure the rate of carbon dioxide (CO₂) exchange between the soil and atmosphere in the inter-tidal forest floor of the Indian Sundarbans mangrove ecosystem and to study its response with soil temperature and soil water content. Soil CO₂ effluxes were monitored every month at two stations (between April, 2011 and March, 2012); one situated at the land–ocean boundary of the Bay of Bengal (outer part of the mangrove forest) and the other lying 55 km inshore from the coast line (inner part of the mangrove forest). The static closed chamber technique was implemented at three inter-tidal positions (landward, seaward and bare mudflats) in each station. Fluxes were measured in the daytime every half an hour by circulating chamber headspace air through a sampling manifold assembly and a closed-path non-dispersive infrared gas analyser. The fluxes ranged between 0.15 and 2.34 μmol m^?2 s^?1 during the annual course of sampling. Effluxes of higher magnitude were measured during summer; however, it abruptly decreased during the monsoon. CO₂ flux from the forest floor was strongly related to soil temperature, with the highest correlation found with temperature at 2 cm depth. No such significant relationship between soil water content and CO₂ efflux could be properly ascertained; however, excessively high soil water content was found to be the only reason which hampered the rate of effluxes during the monsoon. On the whole, landward (LW) sites of the mangrove forest emitted more than the seaward (SW) sites. Q ₁₀ values (obtained from simple exponential model) which denote the multiplicative factor by which the efflux rate increases for a 10 °C rise in temperature ranged between 2.07 and 4.05.     

Influence of Shear Strain on the Poisson’s Ratio of Clean Sands

In the present study, a series of resonant column tests was performed to determine the influence of confining pressure, shear strain and relative density on the dynamic properties and Poisson's ratio of poorly graded clean sand. The tests were performed on the sand specimens of size 50 × 100 mm compacted at relative densities 30, 50 and 75 %. To achieve the corresponding relative density, sand was compacted in 5 equal layers with a specific number of blows. A fixed-free type resonant column apparatus was used to determine the dynamic soil properties at various confining pressures. It has been inferred from the data that the shear modulus (\(G\)) increases with an increase in confining pressure and relative density; and decreases with an increase in shear strain. In addition, damping ratio (\(D\)) decreases with an increase in confining pressure and relative density; and increases with an increase in shear strain. In addition, Poisson’s ratio (\(\nu\)) decreases with an increase in confining pressure and relative density and increases with an increase in the shear strain. The variation of shear modulus with Poisson’s ratio is also discussed. It has been found that there has been a decrease in shear modulus with an increase in Poisson’s ratio of the soil. It is noticed that the small strain shear modulus determined from the present study closely matches with the value determined using the correlations from the literature.     

Risk characterization and surface water quality assessment of Manas River,Assam (India) with an emphasis on the TOPSIS method of multi-objective decision making

The present study centers on the investigation of surface water quality with the aid of quality indices and explores the application of a multi-objective decision-making method (TOPSIS) in arranging decisions for policy makers on the basis of overall ranking of the sampling locations. A case study has been performed on the Manas River, Assam (India). Water Quality Index (WQI) involving physico-chemical parameters, and heavy metal pollution index (HPI) and contamination index (CI) involving heavy metal influences were employed for water quality assessment. WQI graded two sampling locations “very poor” and all other locations “poor”. HPIs of all the locations were below the critical value of 100, but the CI depicted that two locations were “moderately contaminated”. Risk assessment to human health was done using hazard quotient and hazard index. Cluster analysis (CA) demonstrated site similarity by grouping the relatively more polluted and less polluted (LP) sites into two major clusters. However, there surfaced difficulty in discerning the overall water quality, as all the three quality indices included different parameters and contradicted each other. A multi-objective decision-making tool, TOPSIS was therefore employed for ranking the locations on the basis of their relative pollution levels. The novelty of the study reflects in the identification of the relatively more or relatively less polluted sites within the same cluster in CA by the application of TOPSIS. The study justifies the effectiveness of TOPSIS method in prioritizing decisions in complex scenarios for policy makers.     

Assessment and monitoring of urbanisation on Himalayan lacustrine environment-a case study in Mirik municipality area

The Mirik lake is a well-known tourist destination in the Darjeeling Himalayan region of West Bengal. In the last few decades, the lake area experienced a surge in demand for the hospitality industry with the consequences of unrestricted municipal town growth. On this perspective, this research work addresses the contemporary problems of the Mirk municipality area involving the lake system using technologies of remote sensing and GIS. In accordance with the primary objective, the detailed land use/land cover change analysis of the past twenty years shows a significant escalating trend in built-up area as it has increased from 149.85 ha in 2000 to 178.25 ha in 2020, where the lake expresses a steady reduction of its perennial part. The gradual shrinkage in the lake area may become of grave concern and therefore, this particular work tries to examine the water quality parameters of Mirik lake. Analyses have shown that the lake shrinkage may be attributed to waste disposal, landfill pollution etc., substantially contributed to the raised level of suspended sediment concentration (3724.26 mg/lit in 2020) near the boundaries. Moreover, the outcome of the developed water pollution model identifies that the western and south-western parts of the lake are the most polluted regions and confirms numerous inlets of the western side push up the level of phosphorus, nitrogen and biological oxygen demand in lake water. Such lake degradation is a real threat to the mountainous lacustrine environment, and it requires comprehensive plans for better management practices at some regular interregnum.