Pb and other ore metals in modern seafloor tectonic environments: Evidence from melt inclusions

Many modern seafloor tectonic environments are host to hydrothermal systems and associated polymetallic sulfide deposits. Metal transport and precipitation are controlled by magmatic processes such as pre-eruptive degassing and the hydrothermal cycle. The original availability of Pb and other ore metals in a given setting is dependent on concentrations in the original magmatic source or additional enrichment processes. We have examined the Pb budget of melt inclusions from nine modern seafloor settings representing back-arcs, mid-ocean ridges and seamounts. Melt inclusions provide information on the characteristics of parental magmas, including insights into metal budgets. Trace element data in melt inclusions hosted in plagioclase, olivine and pyroxene were obtained by laser-ablation inductively-coupled mass-spectrometry.Results from back-arcs emphasize the impact of slab-subduction and dehydration processes on the chemical characteristics of generated magmas. Volatile- and fluid-mobile element-rich melt inclusions at Manus basin and Okinawa trough reflect a robust contribution of elements from the subducting slab as evidenced by relatively low Ce/Pb ratios. At Bransfield strait, on the other hand, melt inclusions are volatile poor, and fluid-mobile element ratios are similar to mid-ocean ridge values indicating little or no contribution from the slab. High Cu concentrations at Manus basin and Okinawa trough can be explained by fluxing of ferric iron from the subducting slab benefiting the production of sulfate over sulfide.Metal budgets for seamounts located on and nearby the axis of mid-ocean ridge segments appear to be independent of any input of mantle plume material. Results from the southern Explorer ridge (strong lower mantle influence, transitional- and enriched-MORBs), Pito and Axial seamounts (moderate lower mantle influence, transitional-MORBs) and a Foundation near-ridge seamount (little to no mantle influence, normal-MORB) show that, despite similar tectonic environments and varying contributions of mantle plume material, Cu, Zn and Pb values do not vary significantly between the enriched and non-enriched magma components of a given setting.     

Quasi-biennial variations in ozone and meteorological parameters over western Europe from ozonesonde data

Quasi-biennial variations in vertical profiles of ozone, temperature, air pressure, and zonal and meridional wind velocities are analyzed from ozonesonde data obtained at the western European stations of Lindenberg, Hohenpeissenberg, and Payerne. The effect of quasi-biennial variations manifests itself variously in different variables and is nonuniform in altitude. The period of quasi-biennial variations is not constant, and the values of the mean period group mainly around 2 and 2.5 years. As in the North American region, the effects of quasi-biennial variations in different parameters of the stratosphere and troposphere over western Europe are due to a combination of the effects of the quasi-biennial oscillation (QBO) in the equatorial stratosphere, the El Niño-Southern Oscillation (ENSO), and the North Atlantic Oscillation (NAO). The observed 2.5-year variations in stratospheric ozone are related to the equatorial QBO to a larger extent in comparison with variations in other variables. It seems likely that a determining influence on variations in stratospheric wind and temperature is exerted by the ENSO. Variations in tropospheric and stratospheric parameters with a mean period of about 2 years are due to the ENSO and NAO effects.     

Suspended barite as a tracer of biological activity in the Southern Ocean

During two cruises in the Southern Ocean (INDIGO 3, Indian sector and EPOS 2, Scotia-Weddell Confluence) suspended matter samples were collected for analysis of several biogenic elements including Ba, Si and particulate organic carbon (POC).The good agreement between particulate barium in subsurface water with oxygen minimum concentrations as well as with nitrate depletions suggests that it reflects the intensity of new production over the past season. As a consequence of new production in the Southern Ocean being performed mainly by diatoms, the occurrences of barite and diatoms are related in the water column. In areas characterized by diatom-poor phytoplankton, barite does occur, but in lower concentrations.     

Relative microbial activity and mineralization associated with water masses in the lower Cook Inlet,Alaska

A study of the microbial uptake and respiration (mineralization) of radioactive glutamic acid was made in 141 surface water samples in the Cook Inlet, Alaska during three sampling periods (October, 1976; April, 1977; and November, 1977). The rate at which the test substrate was incorporated into cell material plus that respired as CO₂ was used to calculate the relative microbial activity. A northern water mass with salinities less than 31 showed high rates of relative microbial activity but low mineralization rates as indicated by respiration of¹⁴CO₂. The reverse pattern was seen in the water mass (salinity higher than 31) to the south which was more typical of coastal water. These data suggest that the organic nutrients in these two water masses are quite different either qualitatively or quantitatively. This study illustrates how the observed measurement of relative microbial activity might be helpful in defining specific water masses.(The publication of this article was unintentionally delayed owing to a fault in secretarial routine.)Published as Technical Paper No. 6009, Oregon Agricultural Experiment Station.     

The sea as a source of atmospheric phosphorus

The geochemical fractionation of phosphorus on the drop produced by bubbles bursting in seawater has been studied using a field sampling system called the Bubble Interfacial Microlayer Sampler (BIMS). The droplets from bursting bubbles were collected on filter samples in Narragansett Bay, Rhode Island during the summer of 1975. Phosphorus was found to be fractionated by the bubble-bursting process. The enrichment factor ranged from 4 to 170. Enrichment was found to increase with decreasing phosphorus concentration at 20 cm depth while it decreases with increasing wind velocity. Enrichment was independent of bubbling depth. Together these facts suggest that the sea-surface microlayer is the source of the phosphorus on the ejected drops. Organic phosphorus on the filter samples was found to be enriched relative to surface-water phosphorus by factors of 100–200, while reactive phosphorus was enriched by factors of only 6–8. This suggests that surface-active organic phosphorus compounds are the source phosphorus in the microlayer.The organic phosphorus content of samples of atmospheric particulates collected over the phosphate-rich upwelling waters near the Peru coast was found to correlate significantly with sea-salt sodium. Enrichments calculated using the average phosphorus concentration of the surface water in this area agree well with the results of the BIMS study. Thus it appears that phosphorus fractionation does occur in nature and may be important in supplying this nutrient to some coastal regions of the world.     

Geochemical variation in ferromanganese nodules and associated sediments from the Pacific Ocean

The major and minor element compositions of a suite of abyssal sea-floor ferromanganese nodules and associated sediments from the eastern central Pacific have been used to examine inter-element relationships and the mineralogy of the nodules, the relationship between the composition of nodules and their associated sediments and regional variations in composition with respect to likely modes of formation of such deposits. Apart from Mn and Fe, significant proportions of the total Ti, Ca, Mg, K, Ba, Sr, Th and Y and almost all the P, As, Ce, Co, Cu, Mo, Ni, Pb, Zn and Zr are present in the oxide fractions of the nodules. The Mg, Ba, Cu, Mo, Ni and Zn contents are significantly correlated with the Mn content, while Ti, P, As, Pb, Sr, Y and Zr are similarly correlated with the total Fe content.Nodules from the northeastern tropical Pacific have Mn/Fe ratios higher than those in the oxide fractions of their associated sediments, todorokite as the principal Mn phase and relatively high concentrations of minor elements associated with Mn. Nodules from the south central Pacific have Mn/Fe ratios similar to those in the oxide fractions of the associated sediments, δ-MnO₂ as the only Mn-phase, and relatively high concentrations of minor elements associated with Fe. There appears to be a smooth gradation in composition in the tropical Pacific between these two end members.The regional compositional variation is interpreted as a reflection of different sources of metals for, and different growth mechanisms of, sea-floor nodules. The oxide precipitate from sea water consists of δ-MnO₂, has a relatively low Mn/Fe ratio and minor element contents related to the total Fe and Mn(δ-MnO₂) content. The oxide precipitate forming in areas of very low sedimentation as a result of diagenetic remobilisation in the surface sediment consists of todorokite, and has a high Mn/Fe ratio and enhanced metal content in the Mn-(todorokite)phase. Available information on the morphology and compositional variation of individual nodules from the tropical Pacific corroborates these contrasting metal sources and suggests that they can be resolved on the scale of an individual oxide concretion.     

Stellar flare statistics — Physical consequences

The observational data permit us to establish clear statistical correlations between different parameters of stellar flare activity and the characteristics of quiet stars. These relations are:

1. between energies and frequencies of flares on stars of different luminosities;
2. between total radiation energies of flares and quiet stars both in X-ray and Balmer emission lines;
3. between flare decay rates just after the maxima and flare luminosities at maxima.

     

Optical interferometric observations of a transient event of 1986 March 13 in the coma of Comet Halley

During the recent apparition of Comet Halley in 1985-86 a transient ionic event in the form of a blob of H₂ O⁺ emission was recorded in thecoma at ～ 0^h UT on 1986 March 13. Observations were carried out using a special IHW filter for H₂ O⁺ emission at 7000 å/175 å, a 35 cm telescope, a Fabry-Perot interferometer and an image intensifier camera from Gurushikhar, Mt Abu. (24?39’N,72? 47’E). A Fabry-Perot inter-ferogram in Ha taken a few minutes later at the same location reveals strong hydrogen emission (Hα) associated with the blob. The velocity field in the blob is structured with relative velocities upto ～ 35km s^?1. The event is interpreted as arising due to the sector boundary crossing of the interplanetary magnetic field by the comet     

The University of Durham Southern Hemisphere VHE gamma ray telescope

The design of very high energy (VHE) gamma ray telescopes is discussed and it is shown that a triple-mirror telescope operating in threefold fast coincidence provides an effective instrument. The design, construction and operation of a large VHE gamma ray telescope with an energy threshold of 300 GeV (at the zenith) and incorporating several novel features is described. The use of a coincidence guard ring technique is shown to result in the rejection of about 50% of the off-source (proton) events which form a high background and limit the sensitivity of such telescopes.     

Photometry of the bright stars inside and outside associations in the spiral arm S5 of the andromeda galaxy

Photometry of more than 1000 bright stars of 20 associations and some fields in its vicinity is made, usingUBV plates taken with a 2-m Ritchey-Chrétien telescope of the National Observatory at the Bulgarian Academy of Sciences with limited magnitudes of about 20.6 inU andV, 21.6 inB. The colour-magnitudes of about 20.6 inU andV, 21.6 inB. The colour-magnitude and colour-colour diagrams of 12 associations and 8 fields are constructed and the brightest blue and red stars colour excesses, ages, and integrated luminosities of the associations are determined. The composite diagrams for all association and nonassociation measured stars are constructed too. Inside associations bright stars as well as non-stellar objects occur more often than outside. The brightest stars in S5 are withM _v7 and do not differ considerably from the brightest ones in the spiral arm S4 of M31. Approximately the same are the absolute magnitudes of the brightest stars in our Galaxy and M33. A small difference between the brightest stars of the latter galaxy with those of M31 is possible because the stars in M33 are younger. This is in agreement with the concept that Sc galaxies (for example M33) are younger than Sb ones (for example M31). The same could be the reason for the smaller ratio of blue to red supergiants in M33 than in M31. The age estimations of the associations in S5 together with those in S4 in M31 show that they are older than the associations in M33 which is in agreement with the above mentioned concept.