Petrochemistry of the silicic-mafic complexes at Vesturhorn and Austurhorn, Iceland: evidence for zoned/stratified magma

Within the Austurhorn and Vesturhorn silicic intrusions of southeastern Iceland are composite complexes that consist of pillow-like bodies of mafic and intermediate rock entirely surrounded by silicic rock. The pillows with cuspate and chilled boundaries are interpreted to indicate a liquid-liquid relationship with a silicic magma. Some pillow-like bodies have a chilled and sharp cuspate boundary, whereas others have a distinct chemical and visible gradational contact with the silicic rock. The visible scale of mixing is of the same order of magnitude as the size of the pillows enclosed in the silicic rock (mm to meters).Two important types of chemical variation in the pillows are recognized. The first type of variation occurs from mafic pillow interiors to margins and into the surrounding silicic rock. These variations are due to mechanical mixing between mafic magma and the silicic magma. The second type of chemical variation occurs between individual pillows. Large variations occur between pillows in P and Ti at nearly constant silica. These variations cannot have resulted from in situ simple magma mixing or crystal fractionation, and must have originated at depth below the present level of exposure. These compositions could have been derived from separate mafic (or intermediate) magma bodies or from a single zoned and/or stratified magma body. Because the Austurhorn, Vesturhorn, and Ardnamurchan composite complexes all exhibit similar variations in P and Ti and because these occurrences are separated in space and time, they are thought to have had similar processes occur during their evolution. The chemical variations are interpreted to have resulted from mafic magma that has underplated silicic magma and become zoned/stratified due to the effects of magma mixing and cooling-crystallization.     

Age of amphibolites associated with alpine peridotites in the Dinaride ophiolite zone,Yugoslavia

Amphibolites associated with alpine peridotites in the Central Ophiolite zone in Yugoslavia have K-Ar ages of 160–170 m.y. These amphibolites and associated peridotites underwent deep-seated metamorphism prior to tectonic emplacement into the sedimentary-volcanic assemblage of the Dinarides. The alpine peridotites and associated local rocks of the ophiolite suite are interpreted as Jurassic oceanic crust and upper mantle.     

Geochronology and sedimentology of the lower Passaic River,New Jersey

In an attempt to characterize localized rates of sediment accretion, 10 sediment cores were collected from the lower reach of the Passaic River, a major tributary of Newark Bay, New Jersey. Sediments were assayed for ²¹⁰Pb activity at predetermined depths and the rate of sediment accretion (cm yr^?1) was estimated from the least squares regression of the log of unsupported activity versus depth. Sediment accretion rates, derived from ²¹⁰Pb measurements (R_Pb) were used to predict the depth interval within the core containing sediments deposited around 1954; subsequent ¹³⁷Cs analyses were focused on this depth interval. Sediment accretion rates derived from ¹³⁷Cs measurements (R_Cs) were extrapolated from the depth of the 1954 horizon. Lead-210 derived sediment accretion rates in cores collected from a sediment bench extending along the inside bend on the southern shore of a meander in the river, ranged from 4.1 cm yr^?1 to 10.2 cm yr^?1 and averaged 6.8 cm yr^?1. The R_Cs estimates for cores from this area ranged from 3.8 cm yr^?1 to 8.9 cm yr^?1 and averaged 6.6 cm yr^?1. The R_Cs for cores collected in a more hydrologically dynamic reach of the river upstream of the sediment bench, were only 0.41 cm yr^?1 and 0.66 cm yr^?1. The results of this investigation indicate that this reach of the lower Passaic River is an area of high sediment accumulation, retaining much of the sediment load deposited from upstream and downstream sources. The rates of sediment accretion in the lower Passaic River are among the highest reported anywhere in the Newark Bay estuary.     

Gondwana breakup: no evidence for a Davie Fracture Zone offshore northern Mozambique,Tanzania and Kenya

Plate tectonic reconstructions assume a major inactive transform fault, the Davie Fracture Zone, in the West Somali Basin, along which Madagascar is thought to have migrated southwards following Gondwana breakup in the Mesozoic. Based on the interpretation of reflection seismic data, we show that the Walu Ridge offshore Kenya and the Kerimbas Basin offshore northern Mozambique are tectonically unrelated to the southward motion of Madagascar and correlate with Late Cretaceous volcanism and inversion in Kenya and the evolution of the East African Rift System respectively. Offshore Tanzania, geophysical data do not show basement structures indicating the presence of a major transform fault. These results challenge the commonly supported transform margin concept and imply a more southerly pre‐breakup position of Madagascar within Gondwana. Opening of the West Somali Basin by SW‐propagating oblique rifting and seafloor spreading is proposed.     

Pattern,style and timing of British–Irish Ice Sheet advance and retreat over the last 45 000 years: evidence from NW Scotland and the adjacent continental shelf

Predicting the future response of ice sheets to climate warming and rising global sea level is important but difficult. This is especially so when fast-flowing glaciers or ice streams, buffered by ice shelves, are grounded on beds below sea level. What happens when these ice shelves are removed? And how do the ice stream and the surrounding ice sheet respond to the abruptly altered boundary conditions? To address these questions and others we present new geological, geomorphological, geophysical and geochronological data from the ice-stream-dominated NW sector of the last British–Irish Ice Sheet (BIIS). The study area covers around 45 000 km² of NW Scotland and the surrounding continental shelf. Alongside seabed geomorphological mapping and Quaternary sediment analysis, we use a suite of over 100 new absolute ages (including cosmogenic-nuclide exposure ages, optically stimulated luminescence ages and radiocarbon dates) collected from onshore and offshore, to build a sector-wide ice-sheet reconstruction combining all available evidence with Bayesian chronosequence modelling. Using this information we present a detailed assessment of ice-sheet advance/retreat history, and the glaciological connections between different areas of the NW BIIS sector, at different times during the last glacial cycle. The results show a highly dynamic, partly marine, partly terrestrial, ice-sheet sector undergoing large size variations in response to sub-millennial-scale climatic (Dansgaard–Oeschger) cycles over the last 45 000 years. Superimposed on these trends we identify internally driven instabilities, operating at higher frequency, conditioned by local topographic factors, tidewater dynamics and glaciological feedbacks during deglaciation. Specifically, our new evidence indicates extensive marine-terminating ice-sheet glaciation of the NW BIIS sector during Greenland Stadials 12 to 9 – prior to the main ‘Late Weichselian’ ice-sheet glaciation. After a period of restricted glaciation, in Greenland Interstadials 8 to 6, we find good evidence for rapid renewed ice-sheet build-up in NW Scotland, with the Minch ice-stream terminus reaching the continental shelf edge in Greenland Stadial 5, perhaps only briefly. Deglaciation of the NW sector took place in numerous stages. Several grounding-zone wedges and moraines on the mid- and inner continental shelf attest to significant stabilizations of the ice-sheet grounding line, or ice margin, during overall retreat in Greenland Stadials 3 and 2, and to the development of ice shelves. NW Lewis was the first substantial present-day land area to deglaciate, in the first half of Greenland Stadial 3 at a time of globally reduced sea-level c. 26 kabp , followed by Cape Wrath at c. 24 kabp. The topographic confinement of the Minch straits probably promoted ice-shelf development in early Greenland Stadial 2, providing the ice stream with additional support and buffering it somewhat from external drivers. However, c. 20–19 kabp , as the grounding-line migrated into shoreward deepening water, coinciding with a marked change in marine geology and bed strength, the ice stream became unstable. We find that, once underway, grounding-line retreat proceeded in an uninterrupted fashion with the rapid loss of fronting ice shelves – first in the west, then the east troughs – before eventual glacier stabilization at fjord mouths in NW Scotland by ~17 kabp. Around the same time, ~19–17 kabp , ice-sheet lobes readvanced into the East Minch – possibly a glaciological response to the marine-instability-triggered loss of adjacent ice stream (and/or ice shelf) support in the Minch trough. An independent ice cap on Lewis also experienced margin oscillations during mid-Greenland Stadial 2, with an ice-accumulation centre in West Lewis existing into the latter part of Heinrich Stadial 1. Final ice-sheet deglaciation of NW mainland Scotland was punctuated by at least one other coherent readvance at c. 15.5 kabp , before significant ice-mass losses thereafter. At the glacial termination, c. 14.5 kabp , glaciers fed outwash sediment to now-abandoned coastal deltas in NW mainland Scotland around the time of global Meltwater Pulse 1A. Overall, this work on the BIIS NW sector reconstructs a highly dynamic ice-sheet oscillating in extent and volume for much of the last 45 000 years. Periods of expansive ice-sheet glaciation dominated by ice-streaming were interspersed with periods of much more restricted ice-cap or tidewater/fjordic glaciation. Finally, this work indicates that the role of ice streams in ice-sheet evolution is complex but mechanistically important throughout the lifetime of an ice sheet – with ice streams contributing to the regulation of ice-sheet health but also to the acceleration of ice-sheet demise via marine ice-sheet instabilities.     

Scales and causes of heterogeneity in bars in a large multi‐channel river: Río Paraná, Argentina

To date, published studies of alluvial bar architecture in large rivers have been restricted mostly to case studies of individual bars and single locations. Relatively little is known about how the depositional processes and sedimentary architecture of kilometre‐scale bars vary within a multi‐kilometre reach or over several hundreds of kilometres downstream. This study presents Ground Penetrating Radar and core data from 11, kilometre‐scale bars from the Río Paraná, Argentina. The investigated bars are located between 30 km upstream and 540 km downstream of the Río Paraná – Río Paraguay confluence, where a significant volume of fine‐grained suspended sediment is introduced into the network. Bar‐scale cross‐stratified sets, with lengths and widths up to 600 m and thicknesses up to 12 m, enable the distinction of large river deposits from stacked deposits of smaller rivers, but are only present in half the surface area of the bars. Up to 90% of bar‐scale sets are found on top of finer‐grained ripple‐laminated bar‐trough deposits. Bar‐scale sets make up as much as 58% of the volume of the deposits in small, incipient mid‐channel bars, but this proportion decreases significantly with increasing age and size of the bars. Contrary to what might be expected, a significant proportion of the sedimentary structures found in the Río Paraná is similar in scale to those found in much smaller rivers. In other words, large river deposits are not always characterized by big structures that allow a simple interpretation of river scale. However, the large scale of the depositional units in big rivers causes small‐scale structures, such as ripple sets, to be grouped into thicker cosets, which indicate river scale even when no obvious large‐scale sets are present. The results also show that the composition of bars differs between the studied reaches upstream and downstream of the confluence with the Río Paraguay. Relative to other controls on downstream fining, the tributary input of fine‐grained suspended material from the Río Paraguay causes a marked change in the composition of the bar deposits. Compared to the upstream reaches, the sedimentary architecture of the downstream reaches in the top ca 5 m of mid‐channel bars shows: (i) an increase in the abundance and thickness (up to metre‐scale) of laterally extensive (hundreds of metres) fine‐grained layers; (ii) an increase in the percentage of deposits comprised of ripple sets (to >40% in the upper bar deposits); and (iii) an increase in bar‐trough deposits and a corresponding decrease in bar‐scale cross‐strata (<10%). The thalweg deposits of the Río Paraná are composed of dune sets, even directly downstream from the Río Paraguay where the upper channel deposits are dominantly fine‐grained. Thus, the change in sedimentary facies due to a tributary point‐source of fine‐grained sediment is primarily expressed in the composition of the upper bar deposits.     

Epistemological possibilities and imperatives of complexity research: a reply to Reitsma

Reitsma (A response to ‘simplifying complexity’. Geoforum 34 (1) (2003) 13), in response to the article ‘Simplifying Complexity’ (Manson, S.M., Simplifying complexity: a review of complexity theory. Geoforum 32 (3) (2001) 405), highlights a number of interesting and important aspects of complexity theory that invite further discussion. In particular, there are three areas of complexity research that are open to deeper exploration: (1) the width and breadth of ‘complexity’ defined as a scientific endeavor; (2) the role of theory relative to practice and their relationship with pattern and process in complex systems; and (3) the need for greater discussion and exploration in order to define the conceptual bounds of complexity theory.     

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.