Toxic chemicals in Canadian fish-eating birds

Cross-country comparison of DDE and PCB residue levels in cormorant, gull and tern eggs in Canada reveal that bird populations at the Great Lakes are most contaminated with those pollutants. DDE levels have been correlated with reproductive failure in Double-crested Cormorants in the Great Lakes with eggshell thinning as a major factor. Low reproductive success in Herring Gull colonies at Lake Ontario is associated with high chlorinated hydrocarbon levels in eggs. Fish-eating birds in the Wabigoon River system, northwestern Ontario, are among the most known mercury contaminated birds. It is suggested that the effects of mercury on the reproduction of fish-eating birds should be further examined there.Fish-eating birds occupy the highest levels of the food web and magnification of toxic chemicals through prey organisms in this web makes those birds vulnerable to the effects of environmental contaminants. Since fish-eating birds are present everywhere in Canada's freshwater and marine habitats and occupy various niches there, they may serve as pollution indicators in various food chains of our aquatic environment. Colonial birds are especially valuable indicators as pollution effects on total bird populations can be studied. Baseline information on fish-eating bird populations should now be collected everywhere in Canada for measuring present and future effects of environmental pollutants, as well as other man-made disturbances on their populations.     

Ar–Ar age determinations of eclogitic clinopyroxene and garnet inclusions in diamonds from the Venetia and Orapa kimberlites

Ar–Ar age measurements are reported for selected eclogitic clinopyroxene and garnet inclusions in Orapa diamonds and clinopyroxene inclusions in Venetia diamonds. Laser drilling of encapsulated clinopyroxene inclusions within Venetia diamonds released a maximum of 3% of the total ⁴⁰Ar, indicating little diffusive transfer and storage of radiogenic ⁴⁰Ar at the diamond–inclusion boundary. Apparent ages obtained during stepped heating of three diamonds are consistent with diamond crystallisation occurring just prior to the kimberlite eruption 520 Ma ago. Stepped heating of three clinopyroxene-bearing Orapa diamonds gave ages of 906–1032 Ma, significantly above the eruption age, but consistent with previously determined isotopic ages. A few higher apparent ages hint at the presence an older generation of Orapa diamonds that formed >2500 Ma ago. Orapa garnets also contain measurable K contents, and record a range of ages between 1000 and 2500 Ma. The old apparent ages and lack of significant interface ⁴⁰Ar released by the laser probe, suggests that pre-eruption radiogenic ⁴⁰Ar and mantle-derived ⁴⁰Ar components are trapped in microinclusions within the pyroxene and garnet inclusions.     

Post-breakup basaltic magmatism along the East Greenland Tertiary rifted margin

Mafic and ultramafic intrusions in East Greenland adjacent to the offshore Greenland–Iceland ridge were emplaced 5–9 My after continental breakup at 55 Ma [1]. Rare earth element (REE) concentrations determined by secondary ion mass spectrometry are reported for cumulus clinopyroxene from these intrusions, and the data are used to estimate REE abundance in equilibrium melts using available partitioning data. Estimated equilibrium melts from intrusions have strongly fractionated REE patterns with Nd/Dy(N) in the range 2 to 5.6 and Yb/Dy(N) 0.55 to 0.92, similar to values for coeval basalts. These melts have markedly higher Nd/Dy(N) than earlier breakup related flood basalts. The moderately low Yb/Dy(N) for the post-breakup volcanism is indicative of residual garnet in the source, while their high Nd/Dy(N) ratios can best be explained by aggregating low degree melts from a light-REE-enriched garnet- and spinel-bearing mantle source. We also report He, Sr, and Nd isotopic data for the intrusions. The highest ³He/⁴He ratios (>10 R/R_a) are found in the samples whose REE data reflect the largest proportion of melts from a garnet-bearing source, and having Sr and Nd isotopic compositions identical with the radiogenic Sr and unradiogenic Nd isotope end of the Iceland compositional field. There is no indication of a MORB-type mantle in the source of the intrusions. We postulate that post-breakup volcanism along the East Greenland coastline reflects the increasing proximity of the mantle plume to the East Greenland continental margin. The low degree of melting at high mean pressure inferred for the parental melts for the intrusions may reflect re-thickening of the lithosphere, which in turn was caused by the vigorous volcanism during breakup, with accompanying depletion of upper mantle and underplating of the crust at the continental margin.     

Lettau’s Contribution to the Obukhov Length Scale: A Scientific Historical Study

Boundary-Layer Meteorology - It has been repeatedly assumed that Heinz Lettau found the Obukhov length in 1949 independently of Obukhov in 1946. However, it was not the characteristic length scale,...     

Influence of salinity on permeability characteristics of marine sediments

Abstract

Laboratory tests were conducted on compacted marine sediments to study the effect of salt concentration of permeating fluid on its permeability characteristics. Deep sea sediment samples were collected from water depths varying from 3700 to 4500 m off Mauritius coast. Liquid limit and plasticity index varied widely from 45 to 75 and 10 to 35, respectively. Permeability was found at different void ratios with distilled water and 0.2, 0.4, and 0.8 N NaCl solutions as permeating fluid. It was found that permeability increases with an increase in salt concentration for a given void ratio. This is explained by diffused double layer theory. Also, the rate of increase in permeability decreases with increase in salt concentration. The effect of salt concentration seemed to be less at higher void ratios.     

Inverse Analysis of Deep Excavation Using Differential Evolution Algorithm

This paper presents the applications of the differential evolution (DE) algorithm in back analysis of soil parameters for deep excavation problems. A computer code, named Python‐based DE, is developed and incorporated into the commercial finite element software ABAQUS, with a parallel computing technique to run an FE analysis for all trail vectors of one generation in DE in multiple cores of a cluster, which dramatically reduces the computational time. A synthetic case and a well‐instrumented real case, that is, the Taipei National Enterprise Center (TNEC) project, are used to demonstrate the capability of the proposed back‐analysis procedure. Results show that multiple soil parameters are well identified by back analysis using a DE optimization algorithm for highly nonlinear problems. For the synthetic excavation case, the back‐analyzed parameters are basically identical to the input parameters that are used to generate synthetic response of wall deflection. For the TNEC case with a total of nine parameters to be back analyzed, the relative errors of wall deflection for the last three stages are 2.2, 1.1, and 1.0%, respectively. Robustness of the back‐estimated parameters is further illustrated by a forward prediction. The wall deflection in the subsequent stages can be satisfactorily predicted using the back‐analyzed soil parameters at early stages. Copyright © 2014 John Wiley & Sons, Ltd.     

Precession of the orbital nodes of Jupiter and Saturn triggered by the mutual perturbation: A model of two rings

The problem of the precession of the orbital planes of Jupiter and Saturn under the influence of mutual gravitational perturbations was formulated and solved using a simple dynamical model. Using the Gauss method, the planetary orbits are modeled by material circular rings, intersecting along the diameter at a small angle α. The planet masses, semimajor axes and inclination angles of orbits correspond to the rings. What is new is that each ring has an angular momentum equal to the orbital angular momentum of the planet. Contrary to popular belief, it was proved that the orbital resonance 5: 2 does not preclude the use of the ring model. Moreover, the period of averaging of the disturbing force (T ≈ 1332 yr) proves to be appreciably greater than a conventionally used period (≈900 yr). The mutual potential energy of rings and the torque of gravitational forces between the rings were calculated. We compiled and solved the system of differential equations for the spatial motion of rings. It was established that a perturbing torque causes the precession and simultaneous rotation of the orbital planes of Jupiter and Saturn. Moreover, the opposite orbit nodes on the Laplace plane coincide and perform a secular movement in retrograde direction with the same velocity of 25.6″/yr and the period T _J = T _S ≈ 50687 yr. These results are close to those obtained in the general theory (25.93″/yr), which confirms the adequacy of the developed model. It was found that the vectors of the angular velocity of orbital rings move counterclockwise over circular cones and describe circles on the celestial sphere with radii β₁ ≈ 0.8403504° (Saturn) and β₂ ≈ 0.3409296° (Jupiter) around the point which is located at an angular distance of 1.647607° from the ecliptic pole.     

Agpaitic magmatism at Norra Kärr? RbSr isotopic evidence

RbSr isotopic analyses of 10'whole-rock samples from the controversial peralkaline Norra Kärr complex of southern Sweden suggest an age (1580±62 m.y.) considerably older than had previously been anticipated, and indicate an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.7072±0.0035 (errors at 2σ). The isotopic data are consistent with a primary magmatic origin for the Norra Kärr agpaites, but data from 8 mineral separates show that they have experienced at least one period of metamorphic disturbance since the original intrusion; the last episode of isotopic readjustment must have occurred after 1250 m.y. before present, and is attributed to the Sveconorwegian (Grenville) metamorphism.