Subduction Influence on Oxygen Fugacity and Trace and Volatile Elements in Basalts Across the Cascade Volcanic Arc

Fluids or melts derived from a subducting plate are often citedas a mechanism for the oxidation of arc magmas. What remainsunclear is the link between the fluid, oxygen fugacity, andother major and trace components, as well as the spatial distributionof the impact of those fluids. To test the potential effectsof addition of a subduction-derived fluid or melt to the sub-arcmantle, olivine-hosted melt inclusions from primitive basalticlavas sampled from across the central Oregon Cascades (43°–45°N)have been analyzed for major, trace and volatile elements andfO₂. Oxygen fugacity was determined in melt inclusions fromsulfur speciation determined by electron microprobe and fromolivine–chromite oxygen geobarometry. The overall rangein fO₂ based on sulfur speciation measurements is from <–0·25log units to + 1·9 log units (FMQ, where FMQ is fayalite–magnetite–quartzbuffer). Oxygen fugacity is positively correlated with fluid-mobiletrace element and light rare earth element contents in basaltsgenerated by relatively low-degree partial melting. Establishinga further correlation between fO₂ and fluid-mobile trace elementabundances with position along the arc requires the basaltsto be subdivided into shoshonitic, calc-alkaline, low-K tholeiiteand enriched intraplate basalt groups. Melt inclusions fromenriched intraplate and shoshonitic lavas show increasing fO₂and trace element abundances closer to the trench, whereas calc-alkalinemelt inclusions exhibit no significant across-arc variations.Low-K tholeiitic melt inclusions record an increase in incompatibletrace elements closer to the trench; however, there is no correlatedincrease in fO₂. The correlation observed in enriched intraplateand shoshonitic melt inclusions is interpreted to reflect aprogressively greater proportion of a fluid-rich, oxidized subductioncomponent in magmas generated nearer the subduction zone. Significantly,calc-alkaline melt inclusions with high ratios of large ionlithophile elements to high field strength elements, characteristicof ‘typical’ arc magmas, have oxidation states indistinguishablefrom low-K tholeiite and enriched intraplate basalt melt inclusions.The lack of across-arc geochemical variation in calc-alkalinemelt inclusions may suggest that these basalts are not necessarilythe most appropriate magmas for examining recent addition ofa subduction component to the sub-arc mantle. Flux and batchmelt model results produce a wide range of predicted amountsof melting and subduction component added to the mantle source;however, general trends characterized by increased melting andproportion of the subduction component from enriched intraplate,to low-K tholeiite, to calc-alkaline are robust. The model resultsdo not require enriched intraplate, low-K tholeiite and calc-alkalinemagmas to be produced from the same more fertile mantle source.However, enriched intraplate magmas, in contrast to calc-alkalineand low-K tholeiite magmas, cannot be generated from a depletedmantle source. Flux or batch melting of either the more fertileor depleted mantle sources used to generate the low-K tholeiite,calc-alkaline, and enriched intraplate magmas cannot reproduceshoshonitic compositions, which require a significantly depletedmantle source strongly metasomatized by a subduction component.The potential mantle source for shoshonitic basalts has a predictedfO₂ (after oxidation) from + 0·3 to + 2·4 logunits (FMQ) whereas the mantle source for low-K tholeiite, calc-alkaline,and enriched intraplate magmas may range from –1·1to + 0·7 log units (FMQ). KEY WORDS: basalt; Cascades; melt inclusions; oxidation state; volatiles     

A Simple Model for the Movement of Fire Smoke in a Confined Tunnel

Fires in tunnels are unfortunately frequent occurrences often with tragic outcomes. A recent example is the fire on the funicular train at the ski resort in Kaprun (Austria), which caused nearly 160 deaths. Design engineers and risk analysts require knowledge of the fluid dynamics of the fire and smoke movement to answer questions such as how much oxygen can access and feed the fire, and what concentration of smoke will the people be exposed to. As an example in the Austrian accident the geometry was a long tunnel with fire doors closed at one end, and with a fire initiated near the closed (lower) end. The hot smoke from the fire is a source of buoyancy; the smoke reaches the ceiling of the tunnel, and then develops along the ceiling as a wall-bounded plume. The motion of the smoke is driven by a buoyancy force, but at the same time, mechanisms of turbulent heat and mass transfer act as a brake to this motion. In this paper we present how a generic model describing a semi-enclosed buoyancy-driven flow can be interpreted and used in the modelling of fire smoke movement in a confined tunnel. A consideration of the net pollutant volume flux through the tunnel leads to predictions for the variation of concentrations along the tunnel. The smoke concentrations near the fire smoke source scale linearly with the length of the tunnel, with higher concentrations at the lower section of the tunnel, as could be expected. Similarly the concentration of oxygen making its way through to the fire source decreases linearly with the length of the tunnel. A lower bound estimate of the smoke residence time can be obtained based on smoke concentration predictions from the model.     

NASA's Astrophysics Data Archives

The NASA Office of Space Science has established a series of archivalcenters where science data acquired through its space science missionsis deposited. The availability of high quality data to the generalpublic through these open archives enables the maximization of sciencereturn of the flight missions. The Astrophysics Data Centers CoordinatingCouncil, an informal collaboration of archival centers, coordinates datafrom five archival centers distiguished primarily by the wavelength rangeof the data deposited there. Data are available in FITS format. Anoverview of NASA's data centers and services is presented in this paper.A standard front-end modifyer called Astrowbrowse is described. Othercatalog browsers and tools include WISARD and AMASE supported by theNational Space Scince Data Center, as well as ISAIA, a follow on toAstrobrowse.     

Organochlorine Pesticide Residues in Soils and Sediments of the Herbert and Burdekin River Regions, North Queensland – Implications for Contamination of the Great Barrier Reef

Organochlorine pesticides were widely used in the Australian sugarcane industry from the early 1950s until the late 1980s. Erosion of sugarcane soils and subsequent transport of sediment bound contaminants in river run-off to the Great Barrier Reef lagoon is a growing concern as the cane industry continues to expand. Organochlorine pesticide residues can be used as tracers to examine the worst-case scenario of the spatial extent to which currently used, though less persistent, organic agricultural pesticides might extend. The coastal alluvial flood-plains of the Herbert and Burdekin Rivers in North Queensland have sugarcane growing as the major coastal land-use. Sediment cores and surface sediment samples were collected from near-shore coastal regions of the Herbert and Burdekin Rivers. In addition, soil samples from cane-fields in the two catchments were collected. Analyses of the marine surface sediment samples and three sediment cores revealed the absence of detectable concentrations of organochlorine pesticides (<5 pg/g). However, easily detectable concentrations were found in the sugarcane soil samples (0.01–45 ng/g).     

RELATIONSHIP OF SELECTED BIOPHYSICAL VARIABLES TO SOIL MOISTURE AND SOIL TEMPERATURE VARIABILITY

Soil moisture and soil temperature at 15, 61, and 91 cm depths were measured through use of a neutron probe and thermocouple/psychrometers, respectively, at 12 sample sites distributed along a 200 km east-west transect in west-central Oklahoma. The data were collected weekly from May 7 to August 13, 1985. Multiple regression analysis was used to explain soil moisture and soil temperature variability at the three sample depths through a combination of selected biophysical variables representing temporal and spatial site characteristics, meteorologic inputs, energy variables, and soil conditions. The multiple regression analysis showed that 83, 91, and 82% of the variation in soil moisture, and 79, 91, and 92% of the variation in soil temperature for the three depths sampled could be explained by a combination of the selected biophysical variables.     

Sedimentary Basins and the Blockage of Lg Wave Propagation in the Continents

v--vThe phenomenon of "Lg blockage," where Lg is strongly attenuated by crustal heterogeneities, poses a serious problem to CTBT monitoring because Lg is an important seismic phase for discrimination. This paper examines blockage in three continental regions where the Lg blockages may be caused by large, enclosed sedimentary basins along the propagation path. The Barents Sea Basin blocks Lg propagation across the Barents Sea from the Russian nuclear test sites at Novaya Zemlya to Scandinavian stations. Also, "early Lg" waves are observed in Sn codas on NORSAR, NORESS, and ARCESS recordings of Novaya Zemlya explosions where direct Lg is blocked. Early Lg waves may have resulted from Sn-to-Lg mode conversion at the contact between the Barents Basin and the Kola Peninsula. The Northern and Southern Caspian Sea Basins also block Lg waves from PNEs and earthquakes, perhaps due to thick, low-velocity, low-Q sediments replacing the granitic layer rocks in the crust. Lg blockage has also been observed in the Western Mediterranean/Levantine Basin due to low-Q sediments and crustal thinning. A "basin capture" model is proposed to explain Lg blockage in sedimentary basins. In this model, shear waves that reverberate in the crust and constitute the Lg wave train are captured, delayed, and attenuated by thick, low-velocity sediments that replace the "granitic" layer rocks of the upper crust along part of the propagation path. Sn waves, which propagate below the basin, would not be blocked and in fact, the blocked Lg waves may be diverted downward into Sn waves by the low velocity sediments in the basin.     

Further assessment of flood‐ and drought‐dominated regimes in south‐eastern Australia

Kirkup et al. (1998) [Australian Geographer 29, pp. 241–55] criticise our theory of alternating flood regimes and question its application to river management. A brief but critical appraisal of their work shows many errors and misrepresentations. When these are corrected, their challenge is found deficient.     

Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

Age and structure of the southern Rockall Trough new evidence

The Rockall Trough separates the Rockall Plateau microcontinent from the shelf and slope west of the British Isles. The structure and age of the trough has been the source of considerable discussion. Although widely considered to be of oceanic origin, postulated ages for the spreading range from Permian to Cretaceous. New seismic profiles linked to the IPOD sites in the Bay of Biscay and to oceanic anomalies of known age are used to present a new assessment of the age and structure of the southern Rockall Trough. It is concluded that about 120 km of ocean crust is present in the trough and that spreading took place in the Albian-Maastrichtian interval.