Iron speciation and isotope fractionation during silicate weathering and soil formation in an alpine glacier forefield chronosequence

The chemical weathering of primary Fe-bearing minerals, such as biotite and chlorite, is a key step of soil formation and an important nutrient source for the establishment of plant and microbial life. The understanding of the relevant processes and the associated Fe isotope fractionation is therefore of major importance for the further development of stable Fe isotopes as a tracer of the biogeochemical Fe cycle in terrestrial environments. We investigated the Fe mineral transformations and associated Fe isotope fractionation in a soil chronosequence of the Swiss Alps covering 150 years of soil formation on granite. For this purpose, we combined for the first time stable Fe isotope analyses with synchrotron-based Fe-EXAFS spectroscopy, which allowed us to interpret changes in Fe isotopic composition of bulk soils, size fractions, and chemically separated Fe pools over time in terms of weathering processes. Bulk soils and rocks exhibited constant isotopic compositions along the chronosequence, whereas soil Fe pools in grain size fractions spanned a range of 0.4‰ in δ⁵⁶Fe. The clay fractions (<2 μm), in which newly formed Fe(III)-(hydr)oxides contributed up to 50% of the total Fe, were significantly enriched in light Fe isotopes, whereas the isotopic composition of silt and sand fractions, containing most of the soil Fe, remained in the range described by biotite/chlorite samples and bulk soils. Iron pools separated by a sequential extraction procedure covered a range of 0.8‰ in δ⁵⁶Fe. For all soils the lightest isotopic composition was observed in a 1 M NH₂OH-HCl-25% acetic acid extract, targeting poorly-crystalline Fe(III)-(hydr)oxides, compared with easily leachable Fe in primary phyllosilicates (0.5 M HCl extract) and Fe in residual silicates. The combination of the Fe isotope measurements with the speciation data obtained by Fe-EXAFS spectroscopy permitted to quantitatively relate the different isotope pools forming in the soils to the mineral weathering reactions which have taken place at the field site. A kinetic isotope effect during the Fe detachment from the phyllosilicates was identified as the dominant fractionation mechanism in young weathering environments, controlling not only the light isotope signature of secondary Fe(III)-(hydr)oxides but also significantly contributing to the isotope signature of plants. The present study further revealed that this kinetic fractionation effect can persist over considerable reaction advance during chemical weathering in field systems and is not only an initial transient phenomenon.     

Periglacial trimlines and nunataks of the Last Glacial Maximum: the Gap of Dunloe,southwest Ireland

During the last main phase of glaciation (26–13 ka) an ice‐cap developed in southwest Ireland and ice, from a dispersal centre in the vicinity of Kenmare, flowed north through the Gap of Dunloe in the Macgillycuddy's Reeks. On surrounding hillsides a weathering limit separates ice‐moulded bedrock, on low ground, from frost‐weathered terrain above. Assessment of bedrock dilation joint characteristics, Schmidt hammer R‐value data and clay‐sized mineral contents of basal soil samples, demonstrate significant contrasts in the degree of weathering above and below this limit. The weathering limit declines in altitude along former ice flow‐lines and is confluent with morainic deposits on the eastern side of the Gap. This supports the assertion that the high‐level weathering limit is a periglacial trimline that marks the former maximum upper limit of the body of ice which occupied the Gap of Dunloe during the Last Glacial Maximum (LGM). Reconstruction of the former ice‐surface profile from periglacial trimline limits on the eastern side of the Gap yields a mean estimate for basal shear stress of 106.5 kPa. This value suggests that the ice mass which occupied the Gap of Dunloe at the LGM was warm based and flowed on a bedrock substrate. Copyright © 2004 John Wiley & Sons, Ltd.     

Infrared space borne experiments to study Galactic structure

The Geophysics Directorate of Phillips Lab is engaged in several Galactic structure studies. These studies involve a reprocessing and analysis of the IRAS measurements and experiments on the next two infrared satellites, the Midcourse Space Experiment (MSX) and the Infrared Space Observatory (ISO). A collaboration with the Deep Near Infrared Survey (DENIS) will provide complementary coverage of the same Galactic Plane fields surveyed by MSX and ISO.     

The effects of tropical storm Dennis on coastal phytoplankton

The effects of tropical storm Dennis were documented in the coastal waters of South Carolina during August 1981. Phytoplankton photosynthesis vs. irradiance curves showed initial depression of the parameter a followed by three- to five-fold increase of both a and the asymptotic maximum rate of photosynthesis P_m^B. Productivity rates were depressed in most samples immediately after the storm. Surface samples at the inshore stations were around 50 mg C m^?3 h^?1 at saturating light intensities, while the offshore station rates were around 10 mg C m^?3 h^?1. After a 10-day lag these rates had increased to about 200 mg C m^?3 h^?1 inshore and 75 mg C m^?3 h^?1 offshore. These changes are thought to be primarily caused by changes in species composition. Some of the dominant diatom species changed and dinoflagellate species were introduced. No significant changes in nutrient concentrations were observed. Transient depressions of water temperature, salinity and light intensity may have contributed to the observed changes.     

Three years of photometry of IM pegasi = HR8703

Differential photometry of this K1 IV–III p RS VNn-type binary in 1978–79, 1979–80, and 1980–81 at eight different observatories shows that the variability, discovered orignally by Herbst, is periodic. The mean of three different determinations of the photometric period was 24^d.39±-0^d.03, about 1% shorter than the orbital period of 24^d.649 determined spectroscopically by Harper. The total range observed during these three years was 5 ^m .60<V<5 ^m .85. The light curve was nearly sinusoidal but always noticeably asymmetric, with the sense reversing sometime between 1979–80 and 1980–81.     

Observations on a solar saltworks near Burgas, Bulgaria

Data on biota and nutrients in solar ponds of a saltworks near Burgas, Bulgaria, were obtained. Surveys of the biota were undertaken, and records from management officials gave information on biological and physical conditions related to salt production. The decrease in the quality and quantity of sodium chloride harvested that began 10 to 15 years before the study, may be related to the high levels of plankton, combined nitrogen and phosphate, and the large accretion of bottom sediments and density of benthic communities. Biological management can improve the quality and quantity of the sodium chloride produced by the saltworks.     

Editors' note

Pure and Applied Geophysics -     

Hydrogen incorporation in orthopyroxene: interaction of different trivalent cations

The incorporation of hydrogen into ferrosilite, Fe-bearing enstatite and orthopyroxene containing different trivalent cations (Cr³⁺ and Al³⁺, Cr³⁺ and Fe³⁺) was investigated experimentally at 25 kbar. Hydrogen concentration was determined by FTIR-spectroscopy on oriented crystal sections and by secondary ion mass spectroscopy, whereas Mößbauer spectroscopy and optical spectroscopy were used to characterise the valence state of Fe in orthopyroxene. Results suggest that hydrogen incorporation in ferrosilite is achieved by a similar mechanism as in pure enstatite. In Cr-bearing samples, however, hydrogen incorporation is reduced by the presence of other trivalent cations by an increased tendency to form Tschermaks substitutions, e.g. Si _T ⁴⁺ + Mg _M1 ²⁺ ? Al _T ³⁺ + Cr _M1 ³⁺ . Thus, hydrogen solubility in natural orthopyroxenes from the Earth’s mantle, containing significant amounts of Cr³⁺, Al³⁺, and Fe³⁺, may be much more limited than expected from their trivalent cation content, as a large fraction of the trivalent cations does not participate in H-incorporating reactions as 2 Mg _M1 ²⁺ ? M _M1 ³⁺ + V_M1 + H _i ⁺ .     

Hatchery programs,stock enhancement,and cost effectiveness: A case study of the Albemarle Sound/Roanoke River stocking program 1981–1996

Fish hatchery programs commonly are used to enhance depleted fish populations. While these programs are highly valued by the public, most likely due to their nonrestrictive approach to restoring a fishery, the effectiveness of these programs has been often questioned. This study investigates economic and ecological effectiveness of the Albemarle Sound/Roanoke River (AR) striped bass stocking program from 1981 to1996 as a case study.     

Exploring the future of rural–urban connections in sub-Saharan Africa: modelling urban expansion and its impact on food production in the Addis Ababa region

Abstract

The built-up area of Addis Ababa and its surrounding towns is expanding into the peri-urban region leading to high losses of farmland, directly influencing the food production for the urban population. This paper investigates the patterns of settlement growth in the region surrounding Addis Ababa and their impact on peri-urban agriculture using an urban spatial scenario design model. The effects of two population density scenarios are explored within the framework of a proposed master plan. The model output was used to estimate areas of different suitability levels that would be lost to the modelled settlement expansion. The settlement area in 2038 would represent 29% of the case study’s total area in the low-density scenario but only 19% in the high-density scenario. Compared to the low-density scenario, the high-density scenario would only require a third of the agricultural land transformed into settlement areas. Settlement development would contribute to higher losses of land suitable for cultivating important export products, high nutritional value and import-substituting products. The scenario approach can support sustainable regional planning for settlement expansion that conserves valuable farmland in the peri-urban area and contributes to building capacity for strategic planning of the city regions of sub-Saharan Africa.