Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).     

The role of a national park in classifying mountain tourism destinations: An exploratory study of the Italian Western Alps

Together with the main aim of preserving nature, national parks are also expected to play an important role for the local communities, driving economic activities toward the lens of sustainable development. This contribution aims to present an exploratory study on the relationship between the presence of a protected mountain area, the Gran Paradiso National Park(GPNP), in the North West of the Italian Alps, and the classification of tourism destinations, according to Weaver model of destination management. Starting from the model,the authors provide a quantitative analysis using a set of variables and indicators to comprehensively assess the differing patterns assumed by the municipalities within the borders of the GPNP and those that are not.The provisional results illustrate that the municipalities within the border of a protected area are more likely to be grouped alongside the sustainable mountain destinations. Meanwhile,research outcomes confirm that a protected area does not necessarily contrast the tourism industry but instead may boost local development by driving it within the borders of the sustainable development,switching from the area's only preservation function to a flywheel for the local communities.     

Gene flow and demographic history of the mangrove crab Neosarmatium meinerti: A case study from the western Indian Ocean

Most marine organisms are characterized by at least one planktonic phase during their life history, potentially allowing interconnection of populations separated by several hundred kilometers. For many years, the idea that marine species are genetically homogenous throughout their range of distribution, due to passive larval transport, has been a paradigm. Nowadays, a growing number of studies underline the existence of boundaries in the marine realm and highlight how larval dispersal is a complex process depending on biotic as well as abiotic factors. Marine fragmented habitats, such as atolls, mangroves and estuaries, are optimal systems for investigating the marine dispersion process under a metapopulation approach, since populations can be geographically defined a priori as opposed to those occupying open marine environments. Within this frame, the present paper investigates the population genetic structure and the demographic history of the mangrove crab Neosarmatium meinerti within the western Indian Ocean by partial sequences of the mitochondrial DNA cytochrome oxidase subunit I. A total of 167 specimens were sampled from six mangrove sites distributed along the East African coast, from Kenya to South Africa, also including a mangrove forest located on Mahé Island, Seychelles. A sharp genetic break between the mainland and the Seychelles is recorded, revealing the existence of two historically distinct groups that can be defined as independent evolutionary units. Gene flow along the East African coast appears to be high enough to form a single metapopulation, probably by means of stepping stone populations. Otherwise, this mainland metapopulation is currently under expansion through a gradual moving front from the subtropical toward the equatorial populations.     

Analysis of a regional change in the sign of the SAM�Ctemperature relationship in Antarctica

This study examines regional atmospheric circulation changes associated with a reversal in the sign of the relationship between the Southern Annular Mode (SAM) and near-surface temperatures at Halley station, East Antarctica, during the 1980s. We show that the key factor affecting the regional SAM?Ctemperature relationship (STR) is the relative magnitude of two climatological low pressure centres to the west and east of the area, which determines the source region of air masses advected into the locality. The principal difference affecting the STR is shown to be a trend towards a significantly weaker climatological low (higher pressure) at ~20°E during a positive phase of the SAM. Specifically, it is variations in the phase and magnitude of the wave number three patterns of atmospheric circulation, the non-annular component of the SAM, which are the principal factors governing the regional STR. A similar reversal is observed in the sign of the correlation between the SAM and oxygen-isotope values from an ice core located some 1,200?km east of Halley. This relationship is examined throughout the 20th Century, by comparing the isotope data to SAM reconstructions, and demonstrates marked decadal variability. Thus, these data suggest that switches in the STR are more likely to reflect natural variability in the long-wave patterns over the Southern Ocean rather than the influence of an anthropogenic forcing. This finding is important when considering the potential utility of Antarctic isotope data as a proxy for the SAM.     

Self‐centering structural systems with combination of hysteretic and viscous energy dissipations

This paper presents an innovative set of high‐seismic‐resistant structural systems termed Advanced Flag‐Shaped (AFS) systems, where self‐centering elements are used with combinations of various alternative energy dissipation elements (hysteretic, viscous or visco‐elasto‐plastic) in series and/or in parallel. AFS systems is developed using the rationale of combining velocity‐dependent with displacement‐dependent energy dissipation for self‐centering systems, particularly to counteract near‐fault earthquakes. Non‐linear time‐history analyses (NLTHA) on a set of four single‐degree‐of‐freedom (SDOF) systems under a suite of 20 far‐field and 20 near‐fault ground motions are used to compare the seismic performance of AFS systems with the conventional systems. It is shown that AFS systems with a combination in parallel of hysteretic and viscous energy dissipations achieved greater performance in terms of the three performance indices. Furthermore, the use of friction slip in series of viscous energy dissipation is shown to limit the peak response acceleration and induced base‐shear. An extensive parametric analysis is carried out to investigate the influence of two design parameters, λ₁ and λ₂ on the response of SDOF AFS systems with initial periods ranging from 0.2 to 3.0 s and with various strength levels when subjected to far‐field and near‐fault earthquakes. For the design of self‐centering systems with combined hysteretic and viscous energy dissipation (AFS) systems, λ₁ is recommended to be in the range of 0.8–1.6 while λ₂ to be between 0.25 and 0.75 to ensure sufficient self‐centering and energy dissipation capacities, respectively. Copyright © 2010 John Wiley & Sons, Ltd.