Groundwater recharge in a sedimentary basin in semi-arid Mexico

Recharge mechanisms and the hydrochemical evolution of groundwater in a semi-arid, 6,840-km², intermountain basin in central Mexico were investigated using stable isotopes and major chemical constituents. Ionic ratio analysis helped to conceptualize and quantify in part the subsequent geochemical evolution in the aquifer system. Mass balance models (PHREEQC) were used to interpret and rectify the geochemical properties of the aquifer. The recharge conditions have not changed noticeably during the last several thousands of years. The recharge mechanisms are accompanied by leaching of meteoric salts on and near the ground surface during major rain events, which previously accumulated after minor rain events. Rapid and diffuse infiltration can be excluded. Indirect infiltration from wadis (arroyos) and depressions (playas) with little mixing in shallow groundwater contrasts with a high degree of mixing for water with deep circulation. The prevailing source of major cations (Ca²⁺, Mg²⁺, Na⁺, K⁺) is weathering of carbonates and albite, followed by exchange reactions on clays and hydroxides. Ca²⁺/Na⁺ exchange may interchange along the flow path with reverse (Na⁺/Ca²⁺) exchange, although the Ca²⁺/Na⁺ option is prevalent. Meteoric Ca and Mg inputs are relatively small; however, meteoric Na is insignificant. Irrigation return flow plays an important role in the western part of the study area, giving rise to elevated sulfate and chloride concentrations.

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Resumen Se han investigado los mecanismos de recarga y la evolución hidroquímica de las aguas subterráneas en una cuenca semiárida e intermontanosa de México central, de 6.840 km². Para ello, se han utilizado isótopos estables y los constituyentes químicos mayores. El análisis de las relaciones iónicas ha servido para conceptuar y cuantificar en parte su evolución geoquímica posterior dentro del sistema acuífero. Se ha recurrido a modelos de balance de masas (PHREEQC) para interpretar y rectificar las propiedades geoquímicas del acuífero. Las condiciones de recarga no han cambiado de forma apreciable durante los últimos miles de años. Los mecanismos de recarga se ven acompañados por el lixiviado de las sales meteóricas sobre y cerca de la superficie del terreno durante los episodios principales de lluvia, las cuales son acumuladas en episodios menores de lluvia. Se puede excluir la infiltración rápida y difusa. La infiltración indirecta desde arroyos ( wadis) y depresiones ( playas), que apenas se mezcla con las aguas subterráneas someras, contrasta con un elevado nivel de mezcla con el agua de circulación profunda. La fuente dominante de cationes mayores (calcio, magnesio, sodio, potasio) es la meteorización de los carbonatos y albita, mientras que las reacciones de intercambio en las arcillas e hidróxidos son menos importantes. El intercambio ión calcio-ión sodio puede ser reemplazado a lo largo de una línea de flujo por el intercambio opuesto (ión sodio-ión calcio), aunque la primera es prioritaria. Las aportaciones meteóricas de calcio y magnesio son relativamente pequeñas, mientras que la de sodio es insignificante. Los retornos de riego desempeñan un papel importante en la parte occidental del área de estudio, dando lugar a concentraciones elevadas de sulfato y cloruro.

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Résumé Les mécanismes de recharge et lévolution hydrochimique de leau souterraine dans un bassin de montagne de 6 840 km² en zone semi-aride, dans le centre du Mexique, ont été étudiés au moyen des isotopes stables et des composés chimiques majeurs. Lanalyse des rapports ioniques a aidé à conceptualiser et à quantifier en partie lévolution géochimique qui en résulte, dans le système aquifère. Des modèles de bilan de masse (PHREEQC) ont été utilisés pour interpréter et corriger les propriétés de laquifère. Les conditions de recharge nont pas changé notablement au cours des derniers millénaires. Les mécanismes de recharge sont accompagnés, durant les épisodes majeurs de précipitation, dun lessivage, à la surface du sol et à son voisinage, de sels météoriques accumulés auparavant pendant les petits épisodes de pluie. Linfiltration rapide et diffuse peut être exclue. Linfiltration indirecte à partir des oueds (arroyos) et des dépressions (playas) avec un faible mélange dans la nappe superficielle contraste avec le degré élevé de mélange de leau avec les circulations profondes. La source prépondérante des cations majeurs (Ca²⁺, Mg²⁺, Na⁺, K⁺) est laltération des carbonates et des feldspaths ; léchange de cations avec les argiles et les hydroxydes est moins important. Léchange de Ca²⁺ avec Na⁺ peut sinverser le long des axes découlements pour donner un échange de Na⁺ avec Ca²⁺, bien que le cas Ca²⁺/Na⁺ soit prépondérant. Les apports météoriques de Ca et de Mg sont relativement faibles, cependant que celui de Na météorique est insignifiant. Lécoulement par retour dirrigation joue un rôle important dans la partie occidentale de la région étudiée, produisant un accroissement des concentrations élevées en sulfate et en chlorure.

     

Neural network approach to prediction of temperatures around groundwater heat pump systems

A fundamental aspect in groundwater heat pump (GWHP) plant design is the correct evaluation of the thermally affected zone that develops around the injection well. This is particularly important to avoid interference with previously existing groundwater uses (wells) and underground structures. Temperature anomalies are detected through numerical methods. Computational fluid dynamic (CFD) models are widely used in this field because they offer the opportunity to calculate the time evolution of the thermal plume produced by a heat pump. The use of neural networks is proposed to determine the time evolution of the groundwater temperature downstream of an installation as a function of the possible utilization profiles of the heat pump. The main advantage of neural network modeling is the possibility of evaluating a large number of scenarios in a very short time, which is very useful for the preliminary analysis of future multiple installations. The neural network is trained using the results from a CFD model (FEFLOW) applied to the installation at Politecnico di Torino (Italy) under several operating conditions. The final results appeared to be reliable and the temperature anomalies around the injection well appeared to be well predicted.     

GIS tools for preliminary debris-flow assessment at regional scale

The assessment of the areas endangered by debris flows is a major issue in the context of mountain watershed management. Depending on the scale of analysis, different methods are required for the assessment of the areas exposed to debris flows. While 2-D numerical models are advised for detailed mapping of inundation areas on individual alluvial fans, preliminary recognition of hazard areas at the regional scale can be adequately performed by less data-demanding methods, which enable priority ranking of channels and alluvial fans at risk by debris flows. This contribution focuses on a simple and fast procedure that has been implemented for regional-scale identification of debris-flow prone channels and prioritization of the related alluvial fans. The methodology is based on the analysis of morphometric parameters derived from Digital Elevation Models (DEMs). Potential initiation sites of debris flows are identified as the DEM cells that exceed a threshold of slope-dependent contributing area. Channel reaches corresponding to debris flows propagation, deceleration and stopping conditions are derived from thresholds of local slope. An analysis of longitudinal profiles is used for the computation of the runout distance of debris flows. Information on erosion-resistant bedrock channels and sediment availability surveyed in the field are taken into account in the applications. A set of software tools was developed and made available (https://github.com/HydrogeomorphologyTools) to facilitate the application of the procedure. This approach, which has been extensively validated by means of field checks, has been extensively applied in the eastern Italian Alps. This contribution discusses potential and limitations of the method in the frame of the management of small mountain watersheds.     

Reply to “Discussion 1 on ‘Introspection on improper seismic retrofit of Basilica Santa Maria di Collemaggio after 2009 Italian earthquake' by G.P.Cimellaro, A.M.Reinhorn and A.De Stefano” by Vincenzo Ciampi

The authors thank the discusser for his interest and careful review of the paper and his valuable comments.They also welcome this discussion,because it gives the authors the opportunity to clarify several points which were not explained in sufficient detail in the paper,due to space limitations. The paper does not provide any personal or professional criticism of the discusser or his work and if any statement may have raised an ambiguous interpretation,this should be clarified and dismissed.Any inaccuracy in the reference's citation was not intentional.Some of the authors do not speak Italian;therefore they could not read directly and understand the paper cited by the discusser,which is in Italian.     

Influence of object concentration on finite strain and effective viscosity contrast: insights from naturally deformed packstones

Deformed conglomerates and ooidal/oncoidal packstones are commonly used to evaluate finite strain in deformed sedimentary successions. In order to obtain a correct estimate of finite strain, it is necessary to consider not only the different behaviour of matrix and objects, but also object concentration. The analysis of two-component rocks characterised by high values of packing commonly results in a substantial underestimate of bulk strain and of viscosity contrast between objects and matrix. In this study, the effects of the volumetric fraction of competent inclusions on both object and bulk measured finite strain, as well as on apparent viscosity contrast, have been investigated in naturally deformed packstones characterised by variable object concentration on the scale of the hand specimen (and hence for homogenous viscosity contrast). Object finite strain has been obtained by Rf/ analysis, whereas the Fry method provides a measure of whole-rock strain that is also a function of inclusion concentration. Therefore, the finite strain measured by the Fry method is better termed effective bulk strain. In order to investigate the role of object concentration, this parameter has been plotted against object and effective bulk strain, and also against viscosity contrast. These diagrams show that: (i) for high values of packing, measured object and effective bulk strain show values that are significantly lower with respect to the calculated maximum value (that would result in the ideal case of no particle interaction and represents therefore the real bulk strain of the samples); (ii) the viscosity contrast shows lower values with respect to the calculated maximum one (that is equal for the three principal sections of the finite strain ellipsoid), and as packing reaches the maximum value, the viscosity contrast approaches a unit value. Empirical equations have also been found that link object concentration with both object and effective bulk finite strain.     

A revisitation of TRIX for trophic status assessment in the light of the European Water Framework Directive: application to Italian coastal waters

The trophic status classification of coastal waters at the European scale requires the availability of harmonised indicators and procedures. The composite trophic status index (TRIX) provides useful metrics for the assessment of the trophic status of coastal waters. It was originally developed for Italian coastal waters and then applied in many European seas (Adriatic, Tyrrhenian, Baltic, Black and Northern seas). The TRIX index does not fulfil the classification procedure suggested by the WFD for two reasons: (a) it is based on an absolute trophic scale without any normalization to type-specific reference conditions; (b) it makes an ex ante aggregation of biological (Chl-a) and physico-chemical (oxygen, nutrients) quality elements, instead of an ex post integration of separate evaluations of biological and subsequent chemical quality elements. A revisitation of the TRIX index in the light of the European Water Framework Directive (WFD, 2000/60/EC) and new TRIX derived tools are presented in this paper. A number of Italian coastal sites were grouped into different types based on a thorough analysis of their hydro-morphological conditions, and type-specific reference sites were selected. Unscaled TRIX values (UNTRIX) for reference and impacted sites have been calculated and two alternative UNTRIX-based classification procedures are discussed. The proposed procedures, to be validated on a broader scale, provide users with simple tools that give an integrated view of nutrient enrichment and its effects on algal biomass (Chl-a) and on oxygen levels. This trophic evaluation along with phytoplankton indicator species and algal blooms contribute to the comprehensive assessment of phytoplankton, one of the biological quality elements in coastal waters.     

Seasonal and event-controlled export of organic matter from the shelf towards the Gulf of Lions continental slope

To investigate the role of coastal canyons in the transfer of organic matter from the shelf to the slope and basin, we deployed sediment trap/current meter pairs at the head of five canyons in the Gulf of Lions (GoL) between November 2003 and May 2004. Analysis of organic carbon, biogenic silica, Corg isotopic composition, Corg/total nitrogen, chloropigments, and amino acids clearly shows the seasonal influence and effect of extreme meteorological events on the composition of collected particles. The sampling period was divided into three “scenarios”. The first corresponded to a large easterly storm and flood of the Rhone river during stratified water column conditions; the composition of material collected during this event was influenced by increased transfer of riverine and coastal particulate matter, with a lower Corg content. During the second “fall-winter” scenario, northern and northwestern winds blowing over the shelf caused cooling and homogenization of the shelf water column; particles collected at this time reflected the homogeneous source of particulate matter transported through canyons; particles sitting in the vicinity of canyon heads are most likely swept downslope by the general south-westward circulation. Organic tracers indicate a degraded origin for organic matter transported during this period. A third “spring” scenario corresponded to northern winds alternating with eastward windstorms that triggered and/or enhanced the cascading of dense waters accumulated on the bottom of the shelf due to previous cooling. These conditions occurred in conjunction with increased phytoplankton productivity in shelf surface waters. Organic matter advected mainly by dense shelf water cascading was fresher due to the transport of newly produced particles and a variable terrestrial fraction; this fraction depended on the proportion of resuspended material accumulated during previous high discharge periods that was involved in each transport pulse. The tight link shown between meteorological conditions and organic matter transport is important for continental margin geochemical studies as future changes in climatic conditions may lead to dramatic changes in carbon sequestration capability and in the ecosystems of deep margin environments.     

Hydrothermal dolomitization in platform and basin carbonate successions during thrusting: A hydrocarbon reservoir analogue (Mesozoic of Venetian Southern Alps,Italy)

The Early Jurassic dolomitized carbonates in the Venetian Alp, represent a surface analogue of the hydrocarbon exploration targets in Adriatic offshore and Po Plain, Italy. Dolomitization affected the carbonate platform of Monte Zugna Formation (Lower Jurassic) and the Neptunian dikes breccia in the pelagic Maiolica Formation (Uppermost Jurassic–Lower Cretaceous) improving the poro-perm characteristics. Petrography, stable isotope, strontium isotope ratio, trace element and fluid inclusion analyses were carried out on samples from the Monte Grappa Anticline, which is the direct analogue for subsurface. The petrographic analyses showed a first pervasive, replacement dolomitization phase (D1) followed by volumetrically less important dolomite cement precipitation phases (D2, D3, DS). The same, quite wide range of oxygen isotope (?9 to ?2‰ V-PDB) is observed in all dolomite types. The δ¹³C range is in the positive field of marine derived carbonate (from +0.5 to +3.2‰ PDB). The trace element analysis showed a slight enrichment in Fe and Mn contents in the Monte Zugna dolostones with respect the original limestone. The same dolomite precipitation temperature (up to 105 °C Th) was observed in the replacement and cement dolomites, suggesting a unique dolomitization event. This temperature, largely higher than the maximum burial temperature (about 50 °C), supports a hydrothermal origin of the dolomitizing fluids, which had a seawater to brackish composition. The data collected suggest a hydrothermal dolomitization occurring during to the South Alpine thrusting according to the “squeegee model”. The interpretation is consistent with the dolomitization model proposed for similar Jurassic successions in the Central Southern Alps. This study indicates that the deformed foreland and thrust fold belts carbonates in Po Plain and Adriatic offshore are suitable to be dolomitized, and therefore reflect an efficient hydrocarbon exploration play.