Total concentrations of 13 elements (K, Ca, Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Y, Zr, Pb) in the size-fractionated Sava River sediments upstream and downstream of the Krsko nuclear power plant together with metal speciation within bulk sediment have been investigated. Trace metals generally increase with decreasing particle size, however, because of entrapment of organic matter in the 0.63–1 mm fraction, concentrations in the coarser sediment fraction are higher than expected. Exchangeable Pb, Zn, Cu, Mn, Cr and Fe are generally found to represent a negligible fraction of the total metal concentration of the bulk sediment. Seasonal variations of the Pb, Zn and Cu concentrations in the <0.5 mm fraction reflect decreased values during the spring period. Heavy metal concentrations in the 2003 waste water discharges from the Krsko nuclear power plant released into the Sava River were much lower than their maximum allowed values. Combined rubidium and organic matter normalization of the Zn, Pb and Cu concentrations, which was applied on the minus 0.063 mm fraction, indicated three potential sources of contaminants. 相似文献
Factual data for 70 rapid, giant landslides since 1900 show that the occurrence of these landslides was largely predisposed by tectonics, geological structures, lithology and topography, and often triggered by rainfall and earthquakes. In terms of mobile behavior, the giant landslides can be classified into three types: slides, slide-flows and flows. It is found that each type of landslide was constrained to certain geologic and topographic regimes. There are good correlations between kinematic parameters of landslides and slope geometries, which confirm the important role played by topographical condition in the mobile behavior of landslides. Moreover, it is also found that each type of landslide presents distinct geotechnical characteristics in terms of nature of the slip zone and properties of sliding mass. Brief analyses of five typical cases illustrate that landslide mechanisms can be conceptually depicted by failure mechanisms of their slip zones prior to onset of movement and following energy conversion during movement. Problems and questions related to experience in China suggest that comprehensive and systematic investigation and study on rapid giant landslides are urgently needed. 相似文献
Cambrian and Ordovician-Middle Devonian sequences of two successive Early Palaeozoic basins of the Barrandian unconformably overlie Cadomian basement in the Bohemian Massif NW interior (Teplá-Barrandian unit) which is the easternmost peri-Gondwanan remnant within the Variscides. Correlation of stratigraphy and geochemistry of the Early Palaeozoic siliciclastic rocks elucidated sediment provenances. Sandstones of the Middle Cambrian Píbram-Jince Basin were derived from a Cadomian Neoproterozoic island arc. The source area of the Ordovician shallow-marine siliciclastics of the successor Prague Basin is a dissected Cadomian orogen. Late Cambrian acid volcanics of the Barrandian and Cambrian (meta)granitoids emplaced in the W part of the Teplá-Barrandian Cadomian basement are also discernible in these sediments. Old sedimentary component increased during the Ordovician. Early Llandovery siliciclastic rocks show characteristics of an abruptly weakened supply of terrigenous material and an elevated proportion of synsedimentary basic volcanics as a result of Silurian transgression. Emsian siliciclastics (intercalated in the Late Silurian to Early Devonian limestone suite) presumably comprise an addition of coeval basic/ultrabasic volcaniclastics. Middle Devonian flysch-like siliciclastics indicate reappearance of Cadomian source near the Barrandian during early Variscan convergences of Armorican microplates that preceeded accretion of the Teplá-Barrandian unit within the Bohemian Massif terrane mosaic.Dr. Patoka deceased in July 2004. 相似文献
Lower to Middle Devonian carbonates of the Prague Syncline, the Carnic Alps, the Montagne Noire, and the Cantabrian Mountains were investigated for δ13Ccarb and δ13Corg. These values were measured on bulk rocks, selected components and cements. Many carbonates exhibit primary marine values, but some are altered by diagenesis. A δ13C curve can be presented for the latest Pridolian to Emsian time interval. Several sharp or broad positive excursions are obvious in the woschmidti-postwoschmidti, sulcatus, kitabicus, Late serotinus, and kockelianus conodont zones. The excursion at the Silurian–Devonian boundary is known worldwide and therefore considered global in nature. Some of the others are described for the first time from central and southern Europe, and their global nature has to be verified by further investigations in other regions. Most excursions relate to and/or started during major regressions whereas sea-level highstands correspond to minimal δ13C values. Similar relationships between sea-level changes and δ13C have been observed from other early Palaeozoic intervals. The transgressive Chote? (?) and Ka?ák events are marked by positive isotope excursions, this type of combination is usually observed in late Palaeozoic to Cenozoic black shale events. 相似文献
An initial assessment of an old manufacturing site with groundwater impacted by trichloroethene (TCE) contamination in the metropolitan New York area showed that the TCE was being removed naturally by reductive dechlorination. However, complete dechlorination was not expected at the site because the process was progressing too slowly under transitional to aerobic conditions at a degradation constant of –0.0013 and a TCE half life of 533 days. A pilot test was conducted at the site in which a carbohydrate substrate (molasses) was injected into the groundwater to create an In-Situ Reactive Zone (IRZ). Post-pilot test groundwater sampling and analysis indicated that an IRZ was created successfully as the total organic carbon (TOC) content and conductivity increased significantly while oxidation-reduction (REDOX) potential and dissolved oxygen (DO) decreased. The created IRZ caused enhanced reductive dechlorination of TCE at the site, found to proceed with a degradation constant of –0.0158 and a TCE half life of 44 days. 相似文献
The present study gathers a large amount of both existing and unpublished biostratigraphic data, which allows a detailed and complete definition of the stratigraphic features of the late Oligocene–late Miocene Maltese Archipelago sedimentary succession, recording in turn the tectonic and eustatic history of the Central Mediterranean region. We selected five sections in the Malta Island and three in Gozo, representative of the entire sedimentary succession, affected by well-known erosional surfaces, correlated to low-stands of the sea level, often associated with phoshatic layers, linked to the subsequent high-stands. The sedimentary interval, and thus the associated hiatuses, was constrained both by the bio-chronostratigraphic attribution and by the comparison with the third-order succession of the New Jersey passive margin, which shows strict analogy with the geodynamic context in which the Maltese succession deposited. The diachroneity at the base of the formations in the different sections, and the presence of intraformational unconformity/hiatuses, highlighted the role of the tectonic, which depicted a complex sedimentary basin, characterized by more distal versus more marginal sectors. Furthermore, the possibility to compare the sedimentary succession with the oxygen isotope curve connects the sedimentation interruptions, recorded within the Maltese Archipelago deposits, to global cooling events.
A new method for calculating the perturbation spectrum in the framework of Kaula's linear satellite theory (LST) is introduced. The novelty of this approach consists in using recent results on the spectral decomposition of the perturbation frequencies in LST to provide a closed formulation for the amplitude and the phase of each line in the perturbation spectrum. The theory presented here can be applied to perturbations in the elements or in the radial and transverse directions due to the geopotential or to the tides. Separate algorithms are developed for application to orbits with circulating or frozen perigee. 相似文献
To evaluate the contribution of biogeochemical processes to the oceanic carbon cycle and to calculate the ratio of calcium
carbonate to organic carbon downward export, we have incorporated biological and alkalinity pumps in the yoked high-latitude
exchange/interior diffusion-advection (YOLDA) model. The biogeochemical processes are represented by four parameters. The
values of the parameters are tuned so that the model can reproduce the observed phosphate and alkalinity distributions in
each oceanic region. The sensitivity of the model to the biogeochemical parameters shows that biological production rates
in the euphotic zone and decomposition depths of particulate matters significantly influence horizontal and vertical distributions
of biogeochemical substances. The modeled vertical fluxes of particulate organic phosphorus and calcium carbonate are converted
to vertical carbon fluxes by the biological pump and the alkalinity pump, respectively. The downward carbon flux from the
surface layer to the deep layer in the entire region is estimated to be 3.36 PgC/yr, which consists of 2.93 PgC/yr from the
biological pump and 0.43 PgC/yr from the alkalinity pump, which is consistent with previous studies. The modeled rain ratio
is higher with depth and higher in the Pacific and Indian Oceans than in the Atlantic Ocean. The global rain ratio at the
surface layer is calculated to be 0.14 to 0.15. This value lies between the lower and higher ends of the previous estimates,
which range widely from 0.05 to 0.25. This study indicates that the rain ratio is unlikely to be higher than 0.15, at least
in the surface waters. 相似文献