Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia)

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.     

Is there a fuelwood crisis in rural Mali?

The study takes a conventional supply and demand approach to the study of fuelwood use. It compares estimated wood production in West African bush and forest formations based on an available equation using rainfall data with own collected data on local wood consumption in a village in southern Mali. To allow comparison, data from 49 other villages in the same area are analysed. This study, toget her with an earlier study in northern Mali, indicates that locally induced deforestation caused by fuelwood use does not represent an immediate problem in rural Mali. Local use of fuelwood does not seem to be exceeding forest regeneration. However, where there is external pressure on the forest represented by commercial exploitation of wood for sale in the urban centres, fuelwood depletion might occur.     

Ferromanganese crusts from submarine volcanoes of backarc basins as a new genetic type of gallium deposits

Study of the material composition of Fe-Mn crusts from submarine rises in the central part of the Sea of Japan, with modern precision methods applied, has yielded a high (up to 854 g/t) concentration of gallium contained in sorbed form. The new data obtained have allowed a new genetic type of gallium deposits—hydrothermal-sedimentary—to be distinguished.     

A study of bernalite,Fe(OH)3, using Mössbauer spectroscopy,optical spectroscopy and transmission electron microscopy

To study the crystal chemistry of bernalite, Fe(OH)₃, and the nature of the octahedral Fe³⁺ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H ₀ = 55.7±0.3 T and T _N = 427±5K. The centre shift data were fitted to the Debye model with parameters ₀=0.482±0.005 mm/s (relative to -Fe) and _M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe³⁺ at 11 300, 16000 and 23 200 cm^-1, giving a crystal field splitting of 14 570 cm^-1 and Racah parameters of B=629 cm^-1 and C=3381 cm^-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm^-1, suggesting the presence of molecular CO₂ in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe³⁺ site, and compared with values for other iron oxides and hydroxides.     

The Role of the Magnetic Field in the Ascension of the 22nd and 23rd Cycles of Activity

The first small active regions of the last two new cycles seem to be formed, in its very first, preparatory stage, close to the equator with uncertain magnetic orientation, and as secondary products at the periphery of equatorial `magnetic bubbles' of the new magnetic flux still belonging to the old cycle. At the real beginning of the new cycle, at the periphery of its higher-latitude `magnetic bubbles', the opposite applies to the secondary regions of the ending cycle. It seems that two modes of magnetic flux supply the visible layers of the photosphere during the cycle transition phase: the emergence of the magnetic flux from the depth of the convective zone, and the mutual interaction of the earlier emerging fluxes, or the action of the `local dynamo', giving rise to the new local magnetic field concentrations.     

Mean crustal velocity: a critical parameter for interpreting crustal structure and crustal growth

Mean crustal velocity is a critical parameter for genesis of continental crystalline crust because it is a function of mean crustal composition and therefore may be used to resolve continental crustal growth in space and time. Although the best values of mean crustal velocity are determined from wide-angle reflection measurements, most studied here necessarily come from vertical averages in crustal refraction determinations. The mode of 158 values of mean crustal velocity is 6.3 km/s, a velocity which corresponds to a mean crustal composition of granodiorite to felsic quartz diorite; Archean crust may be slightly more mafic. Mean crustal velocities range from 5.8 to 7.0 km/s. The lowest values invariably are found in thermally disturbed rift zones and the highest values correspond to velocities in gabbro. Velocities in island arcs may be as low as 6.0 km/s but are typically 6.5–6.9 km/s which corresponds to andesitic composition; estimates of island arc composition are andesitic. If values of mean crustal velocity are not biased, this observation suggests that continental crust did not grow simply by addition of island arc material. Possibilities are that crust formed from fusion of island arcs and was later changed to more felsic composition by addition of material from the mantle or that the late Archean episode of major crustal growth did not involve processes similar to younger island arcs. Some crustal blocks might be changed in composition and thickness by such processes as underplating, interthrusting, necking and sub-crustal erosion. Specially designed experiments are suggested to determine this parameter so critical for understanding genesis of continental crust.     

A Search for a Globular Cluster whose Passage Through the Galactic Disk Could Induce the Formation of the Gould Belt

The distribution of sites where globular clusters have crossed the Galactic disk during the last 100 million years has been analyzed using the most recent kinematic data for 133 globular clusters (GCs). ThreeGCs (NGC 6341, NGC 7078, and ω Cen) whose distances between the positions where they crossed the Galactic disk and trajectories of the Gould Belt are less than 20% of their heliocentric distances at the crossing time (82, 98, and 96 million years ago, respectively) have been identified. For each of the clusters, this was their next to last, rather than their last, crossing of the Galactic disk. The passage of any one of these three GCs through the disk could potentially have initiated the formation of the Gould Belt.     

Winter Temperature Variability During Warming and Cooling Periods in the Conterminous United States, 1947–1992

Summary  Much literature has reported on the concept of increased surface temperature variability during cool periods, although analyses on temperature records have rendered inconsistent results. In addition, temperature variability during transition periods has been rarely investigated. This study examines temperature variability during wintertime cooling (1947–1977) and warming (1978–1992) periods for the conterminous United States to determine both whether temperature variability is different during warming or cooling periods, and whether the change in variability is supported by midtropospheric circulation conditions. Our results indicate that regions with high temperature variability are mostly found below the troughs in the midtropospheric pressure fields. The direction of change in temperature variability corresponding to cooling or warming conditions, however, varied spatially. For the southeastern and northeastern United States, winter temperatures were more variable during the cooling period than during the warming period, while the northern and central Great Plains had greater temperature variability during the warming period than the cooling period. Similar spatial patterns are also found for the changes in the variability of geopotential height fields. Such spatial patterns in the temperature and height variability during warming and cooling periods may be related to the dominant midtropospheric circulation patterns, such as the different phases of the Pacific-North American teleconnection pattern, and the El Ni?o/Southern Oscillation events. It is concluded that the response of interannual temperature variability to climatic changes is determined by the variation in circulation patterns, and therefore, not spatially uniform. Received September 26, 1996 Revised April 2, 1998