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31.
Stanislaw Halas Janina Szaran Maciej Czarnacki Ahmad Tanweer 《Geostandards and Geoanalytical Research》2007,31(1):61-68
Refinements have been made to achieve over 99% yield in the conversion of CO to CO2 in order to improve the reproducibility and accuracy of δ18 O measurements in sulfates. BaSO4 (10-15 mg) was mixed with an identical amount of spectrographic-grade graphite and loaded into a Pt boat. The mixture was gradually heated to 1100 °C to reduce sulfate to CO and CO2 ; the former gas was simultaneously converted to CO2 by a glow discharge between Pt electrodes immersed in a magnetic field (produced by a pair of external neodymium magnets). A small memory effect was noticed during the analysis (less than 0.3‰ per 10‰ difference in δ18 O between two subsequently analysed samples). The memory effect, however, was suppressed by repetitive preparation of the same specimen. CO2 produced in this way from sulfate reference samples was analysed on a dual inlet and triple collector mass spectrometer along with CO2 equilibrated with VSMOW, GISP and SLAP water reference samples. To avoid large departures of measured isotope ratios from 18 O/16 O of the working calibrator we used CO2 gas prepared from ocean water sulfate for this purpose. The calibrated δ18 O values (in ‰) obtained in this way for NBS-127, IAEA SO-5 and IAEA SO-6 reference materials were 8.73 ± 0.05, 12.20 ± 0.07 and -10.43 ± 0.12, respectively. 相似文献
32.
Stanislaw R. Massel 《Ocean Engineering》1998,25(9):735-752
The vertical acceleration threshold concept has been applied to evaluate the limiting wave height in the train of wind-induced waves propagated over a horizontal bottom. This concept yields very simple computation of the probability of breaking for stochastic sea in deep and finite water depths. The computations confirmed the available field and laboratory observations that the limiting wave steepness in the deep water is lower than the steepness predicted by Stokes. For shallow water depth, the limiting wave height is smaller than 0.55h. This conclusion is consistent with field as well as wave tank observations. 相似文献
33.
Heat flow variations with depth in Europe can be explained by a model of surface temperature changes >10°C. New heat flow
map of Europe is based on updated database of uncorrected heat flow values to which paleoclimatic correction is applied across
the continent. Correction is depth dependent due to a diffusive thermal transfer of the surface temperature forcing of which
glacial–interglacial history has the largest impact. It is obvious that large part of the uncorrected heat flow values in
the existing heat flow databases from wells as shallow as few hundreds of meters is underestimated. This explains some very
low uncorrected heat flow values 20–30 mW/m2 in the shields and shallow basin areas of the craton. Also, heat flow values in other areas including orogenic belts are
likely underestimated. Based on the uncorrected and corrected heat flow maps using 5 km × 5 km grid, we have calculated average
heat flow values (uncorrected heat flow: 56.0 mW/m2; SD 20.3 mW/m2 vs. corrected heat flow: 63.2 mW/m2; SD 19.6 m/Wm2) and heat loss for the continental part. Total heat loss is 928 E09 W for the uncorrected values versus corrected 1050 E09 W. 相似文献
34.
Michal Siwak Stanislaw Zola Tomasz Szymanski Maria Kurpinska-Winiarska Maciej Winiarski Dorota Koziel-Wierzbowska Waclaw Waniak Michal Drahus 《New Astronomy》2012,17(8):691-696
We have analysed the available spectra of WW And and for the first time obtained a reasonably well defined radial velocity curve of the primary star. Combined with the available radial velocity curve of the secondary component, these data led to the first determination of the spectroscopic mass ratio of the system at qspec = 0.16 ± 0.03. We also determined the radius of the accretion disc from analysis of the double-peaked Hα emission lines. Our new, high-precision, Johnson VRI and the previously-available Strömgren vby light curves were modelled with stellar and accretion disc models. A consistent model for WW And – a semidetached system harbouring an accretion disc which is optically thick in its inner region, but optically thin in the outer parts – agrees well with both spectroscopic and photometric data. 相似文献
35.
Witold G. Strupczewski Vijay P. Singh Stanislaw Weglarczyk Krzysztof Kochanek Henryk T. Mitosek 《水文研究》2006,20(16):3535-3554
Similarity and differences between linear flood routing modelling (LFRM) and flood frequency analysis (FFA) techniques are presented. The moment matching used in LFRM to approximate the impulse response function (IRF) was applied in FFA to derive the asymptotic bias caused by the false distribution assumption. Proceeding in this way, other estimation methods were used as approximation methods in FFA to derive the asymptotic bias. Using simulation experiments, the above investigation was extended to evaluate the sampling bias. As a feedback, the maximum likelihood method (MLM) can be used for approximating linear channel response (LCR) by the IRFs of conceptual models. Impulse responses of the convective diffusion and kinematic diffusion models were applied and developed as FFA models. Based on kinematic diffusion LFRM, the equivalence of estimation problems of discrete‐continuous distribution and single‐censored sample are shown both for the method of moments (MOM) and the MLM. Hence, the applicability of MOM is extended for the case of censored samples. Owing to the complexity and non‐linearity of hydrological systems and resulting processes, the use of simple models is often questionable. The rationale of simple models is discussed. The problems of model choice and overparameterization are common in mathematical modelling and FF modelling. Some results for the use of simple models in the stationary FFA are presented. The problems of model discrimination are then discussed. Finally, a conjunction of linear stochastic processes and LFRM is presented. The influence of river courses on stochastic properties of the runoff process is shown by combining Gaussian input with the LCR of the simplified Saint Venant model. It is shown that, from the classification of the ways of their development, both LFRM and FFA can benefit. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
36.
Witold G. Strupczewski Stanislaw Weglarczyk Vijay P. Singh 《Journal of Hydrology》2003,270(3-4):328-351
It is hypothesized that the unit impulse response of a linearized kinematic diffusion (KD) model is a probability distribution suitable for frequency analysis of hydrologic samples with zero values. Such samples may include data on monthly precipitation in dry seasons, annual low flow, and annual maximum peak discharge observed in arid and semiarid regions. The hypothesized probability distribution has two parameters, which are estimated using the methods of moments (MOM) and maximum likelihood (MLM). Also estimated are errors in quantiles for MOM and MLM. The distribution shows an equivalency of MOM and MLM with respect to the mean value—an important property for ML-estimation in the case of the unknown true distribution function. The hypothesized KD distribution is tested on 44 discharge data series and compared with the Muskingum-like (M-like) probability distribution function. A comparison of empirical distribution with KD and M-like distributions shows that MOM better reproduces the upper tail of the distribution, while MLM is more robust for higher sample values and more conditioned on the value of the probability of the zero value event. The KD-model is suitable for frequency analysis of short samples with zero values and it is more universal than the M-like model as its modal value cannot be only equaled to zero value but also to any positive value. 相似文献
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