Microstructure mechanism map of dynamically recrystallized marble

The relative nucleus density (RND) model of dynamically recrystallized grain size [Sakai, T., Jonas, J.J. 1984. Dynamic recrystallization: mechanical and microctructutal consideration. Acta metallurgica, 32, 198–209] was applied to experimentally and to naturally deformed marbles that have undergone dynamic recrystallization. The model shows that a relationship between initial grain size (D₀) and stable dynamically recrystallized grain size (D_S) for a given value of temperature-corrected strain-rate (Z) controls grain size evolution during dynamic recrystallization. New microstructural mechanism maps (MM-maps) for experimentally and naturally deformed marbles (based on previously published data) were defined in log grain size–log Z space and show two distinct regions of grain reduction and grain coarsening. The boundary between these two regions corresponds to an equation relating dynamically recrystallized grain size and temperature corrected strain rate, as proposed in this work. The new MM-map was used to trace semi-quantitatively microstructural and grain size evolution in naturally deformed marbles that underwent dynamic recrystallization at different thermal conditions. The boundary between grain coarsening and grain reduction does not necessarily coincide with the boundary between rotation and migration recrystallization mechanisms. Assessment of available natural data shows that the boundary condition D₀ = 2D_S between grain-coarsening and grain-reduction introduced by Sakai and Jonas [Sakai, T., Jonas, J.J. 1984. Dynamic recrystallization: mechanical and microctructutal consideration. Acta metallurgica, 32, 198–209] is not required for naturally deformed marble.     

LUKANGA SWAM: PROBABLY ASTROBLEME

This article summarizes information relevant to the interpretation of Lukanga Swamp — a depression some 52 km in diameter in central Zambia — as a considerably eroded astrobleme. The results of reconnaissance geological mapping, an airborne magnetic survey and petrological study of a small set of samples of impact rocks are presented. Circular topographic features coincide with a remarkably subdued magnetic field. A circular set of tangential faults indicates a diameter of the outer rim approximately 110 km. Polymict breccia occur, carrying marble megaclasts (klippes) up to 50 m long. Strongly shocked quartz clasts with several sets of decorated planar features are present as well as devitrified, flow-banded silica glass exhibiting decarbonation textures around marble clasts. Provisional correlation of the brecciation event with the local geological record suggests a Paleozoic age of the astrobleme.     

Star and polyline glyphs in a grid plot and on a map display: which perform better?

Glyphs are small geometric shapes that in geovisualization are often used to represent multidimensional spatial data. The aim of this study is to investigate the effectiveness of their two types – star and polyline glyphs, as they can encode the same message and can provide similar functionality. Thus, if the two glyph types are similar and can be used for the same data, the question arises as to which of them better facilitates various user tasks. To address this question, an empirical study of 26 individual users is conducted to investigate differences in user performance for polyline and star glyphs shown either in a grid plot or on a map display. In this study, a task-based approach with eye-tracking is applied, as well as a subjective questionnaire and a psychological test of cognitive style. The finding is that polyline glyphs better facilitate tasks when datapoint values in glyphs are to be read, whereas star glyphs are better when a visual search among glyphs is to be done. Moreover, the results reveal that the map display works better than the grid plot. If star glyphs are to be used, the key (legend) needs to be better incorporated into a visual interface.     

How rough sea affects marine seismic data and deghosting procedures

Most seismic processing algorithms generally consider the sea surface as a flat reflector. However, acquisition of marine seismic data often takes place in weather conditions where this approximation is inaccurate. The distortion in the seismic wavelet introduced by the rough sea may influence (for example) deghosting results, as deghosting operators are typically recursive and sensitive to the changes in the seismic signal. In this paper, we study the effect of sea surface roughness on conventional (5–160 Hz) and ultra‐high‐resolution (200–3500 Hz) single‐component towed‐streamer data. To this end, we numerically simulate reflections from a rough sea surface using the Kirchhoff approximation. Our modelling demonstrates that for conventional seismic frequency band sea roughness can distort results of standard one‐dimensional and two‐dimensional deterministic deghosting. To mitigate this effect, we introduce regularisation and optimisation based on the minimum‐energy criterion and show that this improves the processing output significantly. Analysis of ultra‐high‐resolution field data in conjunction with modelling shows that even relatively calm sea state (i.e., 15 cm wave height) introduces significant changes in the seismic signal for ultra‐high‐frequency band. These changes in amplitude and arrival time may degrade the results of deghosting. Using the field dataset, we show how the minimum‐energy optimisation of deghosting parameters improves the processing result.     

Extreme precipitation and long-term precipitation changes in a Central European sedge-grass marsh in the context of flood occurrence

This study offers a detailed analysis of the extreme precipitation and long-term precipitation changes in a sedge-grass marsh in the “Wet Meadows” area in the Czech Republic (Central Europe) in the context of flood occurrence. Namely, trends in annual maxima of daily precipitation and trends in the occurrence and amount of rainfall are investigated. The analysis is based on daily measurements of precipitation from 1977 to 2015. We found out that extreme precipitation has become significantly more frequent in recent years, and there are also other significant changes in the rainfall distribution. Possible negative effects on the wetland can be linked to a change of carbon exchange between the ecosystem and the atmosphere and a change of biodiversity. Awareness of these changes is necessary for possible positive human intervention when a desirable wetland functioning is threatened.     

Taphonomic phenomenon of ancient hair from Glacial Beringia: perspectives for palaeoecological reconstructions

An accumulation of mammoth hair, discovered in the Bol'shaya Chukochya River valley (northeast Yakutia, Russia), was found to contain remains of terrestrial and aquatic organisms, including plants, insects, crustaceans, birds and mammals. Radiocarbon dating indicated that this post‐mortem taphocoenosis represented multiple time periods. The mammoth hair was dated to older than 45 ka BP, the plants were dated to 12 750±50 a BP (which corresponds to a shift in the environmental conditions and landscapes during the formation of thermokarst in northeastern Russia) and the bird feathers were dated to 4115±40 a BP. A scenario of the formation of this fossil assemblage is proposed, covering the MIS 3‐1 time range. The hair also yielded various Arctic branchiopod crustaceans, which inhabit shallow temporary water bodies and therefore are important for reconstruction of palaeoenvironments. The cladoceran subgenus Daphnia (Ctenodaphnia), currently absent from the Asian part of Beringia, is reported from this region for the first time. The study demonstrates that the discovered permafrost‐preserved hair is a unique repository of Ice Age organisms.     

Hydroxyl in mantle olivine xenocrysts from the Udachnaya kimberlite pipe

The incorporation of hydrogen in mantle olivine xenocrysts from the Udachnaya kimberlite pipe was investigated by Fourier-transform infrared spectroscopy and secondary ion mass spectrometry (SIMS). IR spectra were collected in the OH stretching region on oriented single crystals using a conventional IR source at ambient conditions and in situ at temperatures down to −180°C as well as with IR synchrotron radiation. The IR spectra of the samples are complex containing more than 20 strongly polarized OH bands in the range 3,730–3,330 cm⁻¹. Bands at high energies (3,730–3,670 cm⁻¹) were assigned to inclusions of serpentine, talc and the 10 Å phase. All other bands are believed to be intrinsic to olivine. The corresponding point defects are (a) associated with vacant Si sites (3,607 cm⁻¹ E || a, 3,597 E || a, 3,571 cm⁻¹ E || c, 3,567 E || c, and 3,556 E || b), and (b) with vacant M1 sites (most of the bands polarized parallel to a). From the pleochroic behavior and position of the OH bands associated with the vacant M1 sites, we propose two types of hydrogen—one bonded to O1 and another to O2, so that both OH vectors are strongly aligned parallel to a. The O2–H groups may be responsible for the OH bands at higher wavenumbers than those for the O1–H groups. The multiplicity of the corresponding OH bands in the spectra can be explained by different chemical environments and by slightly different distortions of the M1 sites in these high-pressure olivines. Four samples were investigated by SIMS. The calculated integral molar absorption coefficient using the IR and SIMS results of 37,500±5,000 L mol H₂O cm⁻² is within the uncertainties slightly higher than the value determined by Bell et al. (J Geophys Res 108(B2):2105–2113, 2003) (28,450±1,830 L mol H₂O cm⁻²). The reason for the difference is the different distributions of the absorption intensity of the spectra of both studies (mean wavenumber 3,548 vs. 3,570 cm⁻¹). Olivine samples with a mean wavenumber of about 3,548 cm⁻¹ should be quantified with the absorption coefficient as determined in this study; those containing more bands at higher wavenumber (mean wavenumber 3,570 cm⁻¹) should be quantified using the value determined by Bell et al. (J Geophys Res 108(B2):2105–2113, 2003).

The golden ark: arsenopyrite crystal plasticity and the retention of gold through high strain and metamorphism

Quantitative electron backscatter diffraction analysis and ion microprobe imaging of gold‐rich arsenopyrites provide the first insights into the crystal plasticity and element mobility behaviour of arsenopyrites through metamorphism (340°–460° and 2 kbar). Remarkably, the gold‐rich arsenopyrites remained structurally and chemically robust during high strain deformation. It was only during a superimposed lower strain deformation event, at a high angle to the preferred orientation of the arsenopyrites, that small amounts of crystal plasticity affected the arsenopyrites. During the low strain event, a dissolution–reprecipitation reaction resulted in loss of gold from the crystal lattice, facilitated by localised domains of recrystallisation, most likely due to fluid percolation along sub‐ and new grain boundaries. We suggest that the abundance and rheologically robust nature of gold‐rich arsenopyrite in giant gold deposits, affected by greenschist–amphibolite metamorphism, is actually critical in the preservation of those deposits.     

A recent history of metal accumulation in the sediments of Rijeka harbor, Adriatic Sea, Croatia

We studied metal pollution in the sediments of Rijeka harbor, including anthropogenic influence during recent decades and at the present time. Sediment profiles were collected at ten sampling points. The concentrations of 63 elements in bulk sediment were obtained using ICP-MS, and the concentrations of selected elements were evaluated by statistical factor analyses. We also calculated metal-enrichment factors and geoaccumulation indices and constructed spatial-distribution maps.Mercury (Hg) was the heaviest pollutant, with concentrations exceeding 4 mg/kg. Silver (Ag) was the second most important pollutant, with constantly increasing values. The average concentrations of the most toxic elements were comparable to those found in sediments of other ports throughout the world, and their toxicity ranged from threshold values [chromium (Cr), arsenic (As)] and midrange-effect values [cadmium (Cd), lead (Pb), copper (Cu), zinc (Zn), nickel (Ni)] to extreme-effect values (Hg). Metal pollution has decreased during recent decades, except for Ag and barium (Ba).     

Did the circum-Rodinia subduction trigger the Neoproterozoic rifting along the Congo–Kalahari Craton margin?

International Journal of Earth Sciences - Early Neoproterozoic metaigneous rocks occur in the central part of the Kaoko–Dom Feliciano–Gariep orogenic system along the coasts of the...