Estimation of the normal geomagnetic field and geological interpretation of the normal field anomalies over middle-northern Croatia

Based on the ground survey of total-field magnetic data at 53 sites, which recorded a time-series over the interval 2003–2005, the core field + long wavelength lithospheric field over the middle-northern Croatia region was calculated. The area of the survey was 18900 km², an average distance between the neighbouring sites being 12 km. The results were reduced to 2004.5 epoch. This “normal” total-field was estimated using the firstorder Taylor polynomial as a function of geographic coordinates, and the polynomial coefficients were calculated with three methods of adjustment: simple and weighted least squares fits and adjustment according to the most frequent value. The stability of the normal field was tested using the Monte Carlo-type test, by decreasing the input data set in each adjustment (up to 90%). All obtained field residuals (measured-“normal”) were mutually compared, as well as fit coefficients of the Taylor polynomials. The residual values indicate the presence of shorter-wavelength anomalies, specifically three major residual anomalies were found (−106 nT, 74 nT and 57 nT). The geostatistical analysis of the ground survey data and the normal field residuals (respectively), using the median absolute deviation method, was further conducted in order to evaluate the calculated anomalies. The geological situation around the anomalies derived by the median absolute deviation method, and around the normal field residual anomalies, is given. The correlation was found between higher value anomalies of the normal field residuals, and shallow volcanic rocks and oil field, respectively.     

Rječina River sediments (Croatia): from captured spring to polluted prodelta

Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.     

Fe2+, Mg-distribution among non-equivalent structural sites M1 and M2 in natural olivines: an optical spectroscopy study

Analysis of E||X-polarized optical absorption spectra of natural olivines of various origin in the range of electronic spin-allowed dd-transitions of Fe²⁺ evidences that in some crystals, there is a weak ordering of Fe²⁺ as in M1, as in M2 structural sites. The samples of three different depth facies seem showing a vague tendency of lowering of k _D -values from spinel-pyroxene (Sp-Px) through graphite-pyrope (G-Py) to diamond-pyrope (D-Py) facies, but the statistics are too poor (24 samples only) to be certain of it. Weak relations between Mg, Fe²⁺-distribution and iron content were found for the samples of Sp-Px- and G-Py-facies, while there is practically no one for those of the deepest D-Py facie.     

The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds

The crystal structure of ilinskite, NaCu₅O₂(SeO₃)₂Cl₃, a rare copper selenite chloride from volcanic fumaroles of the Great fissure Tolbachik eruption (Kamchatka peninsula, Russia), has been solved by direct methods and refined to R ₁?=?0.044 on the basis of 2720 unique observed reflections. The mineral is orthorhombic, Pnma, a?=?17.769(7), b?=?6.448(3), c?=?10.522(4) Å, V?=?1205.6(8) ų, Z?=?4. The The CuO_mCl_n coordination polyhedra share edges to form tetramers that have 'additional' O1 and O2 atoms as centers. The O1Cu₄ and O2Cu₄ tetrahedra share common Cu atoms to form [O₂Cu₅]⁶⁺ sheets. The SeO₃ groups and Cl atoms are adjacent to the [O₂Cu₅]⁶⁺ sheets to form complex layers parallel to (100). The Na⁺ cations are located in between the layers. A review of mixed-ligand CuO_mCl_n coordination polyhedra in minerals and inorganic compounds is given. There are in total 26 stereochemically different mixed-ligand Cu-O-Cl coordinations.     

Surficial deposits on salt diapirs (Zagros Mountains and Persian Gulf Platform, Iran): Characterization, evolution, erosion and the influence on landscape morphology

The surfaces of salt diapirs in the Zagros Mountains are mostly covered by surficial deposits, which significantly affect erosion rates, salt karst evolution, land use and the density of the vegetation cover. Eleven salt diapirs were selected for the study of surficial deposits in order to cover variability in the geology, morphology and climate in a majority of the diapirs in the Zagros Mountains and Persian Gulf Platform. The chemical and mineralogical compositions of 80 selected samples were studied mainly by X-ray powder diffraction and X-ray fluorescence. Changes in salinity along selected vertical profiles were studied together with the halite and gypsum distribution. The subaerial residuum formed from minerals and rock detritus released from the dissolved rock salt is by far the most abundant material on the diapirs. Fluvial sediments derived from this type of residuum are the second most common deposits found, while submarine residuum and marine sediments have only local importance. The mineralogical/chemical composition of surficial deposits varies amongst the three end members: evaporite minerals (gypsum/anhydrite and minor halite), carbonates (dolomite and calcite) and silicates-oxides (mainly quartz, phyllosilicates, and hematite). Based on infiltration tests on different types of surficial deposits, most of the rainwater will infiltrate, while overland flow predominates on rock salt exposures. Recharge concentration and thick accumulations of fine sediment support relatively rich vegetation cover in some places and even enable local agricultural activity. The source material, diapir relief, climatic conditions and vegetation cover were found to be the main factors affecting the development and erosion of surficial deposits. A difference was found in residuum type and landscape morphology between the relatively humid NW part of the studied area and the arid Persian Gulf coast: In the NW, the medium and thick residuum seems to be stable under current climatic conditions. Large sinkholes and blind valleys with sinking streams are common. On other diapirs, the original thick residuum is undergoing erosion and the new morphology is currently represented by salt exposures and badland-like landscapes or by fields of small sinkholes developed in the thin residuum. Models for evolution of the subaerial residuum and the diapir landscape/morphology are described in this paper. While the thick residuum with vegetation has very low erosion rates, the salt exposures and thin residuum are eroded rapidly. During wet periods (e.g. early Holocene), the diapirs rose and salt glaciers expanded as the influx of salt mass was much faster compared to erosion. After the onset of an arid climate, c. 6 ka BP, the rising of the some diapir surfaces decreased or even reversed due to acceleration of erosion thanks to vegetation degradation and changes in the residuum type and thickness.     

Food webs and carbon flux in the Barents Sea

Within the framework of the physical forcing, we describe and quantify the key ecosystem components and basic food web structure of the Barents Sea. Emphasis is given to the energy flow through the ecosystem from an end-to-end perspective, i.e. from bacteria, through phytoplankton and zooplankton to fish, mammals and birds. Primary production in the Barents is on average 93 g C m⁻² y⁻¹, but interannually highly variable (±19%), responding to climate variability and change (e.g. variations in Atlantic Water inflow, the position of the ice edge and low-pressure pathways). The traditional focus upon large phytoplankton cells in polar regions seems less adequate in the Barents, as the cell carbon in the pelagic is most often dominated by small cells that are entangled in an efficient microbial loop that appears to be well coupled to the grazing food web. Primary production in the ice-covered waters of the Barents is clearly dominated by planktonic algae and the supply of ice biota by local production or advection is small. The pelagic–benthic coupling is strong, in particular in the marginal ice zone. In total 80% of the harvestable production is channelled through the deep-water communities and benthos. 19% of the harvestable production is grazed by the dominating copepods Calanus finmarchicus and C. glacialis in Atlantic or Arctic Water, respectively. These two species, in addition to capelin (Mallotus villosus) and herring (Clupea harengus), are the keystone organisms in the Barents that create the basis for the rich assemblage of higher trophic level organisms, facilitating one of the worlds largest fisheries (capelin, cod, shrimps, seals and whales). Less than 1% of the harvestable production is channelled through the most dominating higher trophic levels such as cod, harp seals, minke whales and sea birds. Atlantic cod, seals, whales, birds and man compete for harvestable energy with similar shares. Climate variability and change, differences in recruitment, variable resource availability, harvesting restrictions and management schemes will influence the resource exploitation between these competitors, that basically depend upon the efficient energy transfer from primary production to highly successful, lipid-rich zooplankton and pelagic fishes.     

Platinum‐group elements and rhenium in mantle xenoliths from the East Sayan volcanic field (Siberia,Russia): evaluation of melt extraction and refertilization processes in lithospheric mantle of the Tuva‐Mongolian massif

We determined the concentrations of platinum‐group elements (PGE) and rhenium in granular spinel lherzolites entrained as xenoliths in the Late Cenozoic volcanic rocks of the East Sayan within the Sarkhoi palaeo‐arc block of the Tuva‐Mongolian massif. Major element, PGE and rhenium variations in the East Sayan xenoliths can be explained by impregnation of up to 15% of arc‐type melt into initially depleted mantle harzburgite. Such a refertilization process probably took place in the Middle Neoproterozoic, when the Tuva‐Mongolian massif was in a subduction environment. East Sayan xenoliths show close similarities to Vitim xenoliths, whose host basalts erupted within an off‐cratonic crustal block. Both East Sayan and Vitim xenoliths are different from cratonic and circum‐cratonic peridotite xenoliths of worldwide localities.     

Modeling the electric structures of two thunderstorms and their contributions to the global circuit

This study examines the electricity in two thunderstorms, typical for their respective locales (the Great Plains and the New Mexico mountains), by modeling them as a set of steady-state horizontal layers of external currents. The model electric sources, corresponding to the charge separation processes in the thundercloud, are embedded in an exponential conducting atmosphere. The source parameters are determined by fitting the model electric field to measured profiles. The resulting currents to the ionosphere (i.e., the Wilson current) from the two storms are 0.53 A and 0.16 A, while the calculated electrical energies of the storms are 2.3 × 10¹⁰ J and 2.8 × 10⁹ J, respectively. The more vigorous storm is estimated to transfer 16 000 C in the global circuit during 8.5 h of its lifetime, while the weaker mountain storm transferred about 1200 C in its entire 2-h lifetime. Removal of the screening charge layer from above the updraft region in one modeled storm leads to only a small increase in the net Wilson current of less than 3%, while it provides a substantial local disturbance of the electric field. Overall, the model findings indicate that differences in the Wilson currents and electrical energies of the two storms result from differences in their internal dynamical and electrical structures as well as their geographical locations.