Mg-enriched erythrite from Bou Azzer,Anti-Atlas Mountains,Morocco: geochemical and spectroscopic characteristics

Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,...     

The use of cartographic control points in the harmonization and revision of MRDBs

The main purpose of the research is to achieve fully automated approach for supplying multi-resolution databases with linear objects in each scale. Moreover, the proposed solutions maintain the repeatability and accuracy of output data wherever possible according to the input scale. These properties are achieved by keeping the minimal object dimensions as well as the appropriate data pre-processing, based on the classification of source points. The classification distinguishes three classes of points: constant (unchangeable), temporary, and inherited. These classes build a structure of cartographic control points. Based on these solutions, the authors proposed an algorithm for linear object simplification based on minimal object dimensions and cartographic control points. It was also confirmed that the simplification between constant points does not cause geometry discrepancies in relation to the global simplification of the whole line.     

Evaluation of site conditions for the Ankara Basin of Turkey based on seismic site characterization of near-surface geologic materials

Regional site conditions relevant for seismic hazard studies can be derived from various geologic, seismologic, and geotechnical sources. In this study, site conditions are derived for the Ankara Basin in Turkey by merging in-situ seismic measurements of dynamic properties, geologic information, and some geotechnical boring information. Field seismic refraction surveys were performed at 259 sites in the project area to classify and characterize Plio–Pleistocene fluvial deposits and Quaternary alluvial and terrace deposits. The shear-wave velocity profiles of the near-surface geologic units are used to characterize site classes according to the International Building Code [International Code Council, ICC. International Building Code. Structural and fire- and life-safety provisions (seismic, wind, accessibility, egress, occupancy and roof codes), 2006. Whittier, CA.] and the Turkish Seismic Code [Ministry of Public Works and Settlement, 1998. Turkish Seismic Code, Specification for Structures to be Built in Disaster Areas, Ankara, Turkey], and to develop a regional model for the average shear-wave velocity in the top 30 m. The resulting maps of site class indicate that the classification system for the Turkish Seismic Code results in a significant portion of the Ankara Basin being classified as Z4, the softest site class. The International Building Code site classification system results in most of the Ankara Basin being classified as D, stiff soil. These differences are caused by the Turkish Seismic Code incorporating information from only the surface layer, while the International Building Code incorporates information from the top 30 m.     

Versuch der Geschlechtsbestimmung beim Wels,Silurus glanis L., mit Hilfe der Diskriminanzanalyse von Brustflossendaten

Width of the first ray of the pectoral fin has been measured in two places for 154 young and 89 adult wels. Statistical relationships between the above characters and fish length as well as its maturity and sex have been proved. Three models of discriminant function for identification of adult fish sex have been derived and verified. The accuracy of sex separation has been 89,5% in a standard sample of wels, and 90,6% in a routine sample, after an adjustment in the procedure.     

Phase equilibrium and calorimetric study of the transition of MnTiO3 from the ilmenite to the lithium niobate structure and implications for the stability field of perovskite

The phase boundary between MnTiO₃ I (ilmenite structure) and MnTiO₃ II (lithium niobate structure) has been determined by analysis of quench products from reversal experiments in a cubic anvil apparatus at 1073–1673 K and 43–75 kbar using mixtures of MnTiO₃ I and II as starting materials. Tight brackets of the boundary give P(kbar)=121.2−0.045 T(K). Thermodynamic analysis of this boundary gives ΔH^o=5300±1000 J·mol⁻¹, ΔS^o = 1.98 ±1J·K⁻¹· mol⁻¹. The enthalpy of transformation obtained directly by transposed-temperature-drop calorimetry is 8359 ±2575 J·mol⁻¹. Possible topologies of the phase relations among the ilmenite, lithium niobate, and perovskite polymorphs are constrained using the above data and the observed (reversible with hysteresis) transformation of II to III at 298 K and 20–30 kbar (Ross et al. 1989). The observed II–III transition is likely to lie on a metastable extension of the II–III boundary into the ilmenite field. However the reversed I–II boundary, with its negative dP/ dT does represent stable equilibrium between ilmenite and lithium niobate, as opposed to the lithium niobate being a quench product of perovskite. We suggest a topology in which the perovskite occurs stably at low T and high P with a triple point (I, II, III) at or below 1073 K near 70 kbar. The I–II boundary would have a negative P-T slope while the II–III and I–III boundaries would be positive, implying that entropy decreases in the order lithium niobate, ilmenite, perovskite. The inferred positive slope of the ilmenite-perovskite transition in MnTiO₃ is different from the negative slopes in silicates and germanates. These thermochemical parameters are discussed in terms of crystal structure and lattice vibrations.     

Thermodynamics and behavior of γ-Mg2SiO4 at high pressure: Implications for Mg2SiO4 phase equilibrium

Raman spectra of γ-Mg₂SiO₄ taken to 200 kbar were used to calculate entropy and heat capacity at various P-T conditions. These new thermodynamic data on γ-MgSiO₄, similar data on MgSiO₃ perovskite (pv), previous data on β-MgSiO₄ and MgO (mw), and previous volumetric data of all phases were used to calculate the phase boundaries in the Mg₂SiO₄ phase diagram. Our resulting slope for the β→γ transition (50±4 bar K^-1) is in excellent agreement with recent multi-anvil studies. The slopes for the β→pv+MgO and γ→pv+MgO are-7±3 and -25±4 bar K^-1, respectively, and are consistent with our CO₂ laser heated diamond anvil studies. These slopes result in a β-γ-MgO+pv triple point at approximately 229 kbar and 2260 K for the iron free system.     

A volcanic-carbonate association in the Góry Kaczawskie,Western Sudetes

Amidst metavolcanic rocks and phyllites of the Góry Kaczawskie region occur isolated carbonate bodies known as the Wojcieszów limestones. The bodies enclosed in the metavolcanites show primary (sedimentary) contacts, while those in the phyllites do not have such contacts. The Wojcieszów limestones and metavolcanic rocks form sequences displaying mutual spatial and genetical relations. Submarine volcanic elevations were covered with chemical and biochemical carbonate precipitation, the intensity of which was stimulated and controlled by the volcanic activity.

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Zusammenfassung Inmitten der metavulkanischen Gesteine und Phyllite von Góry Kaczawskie erscheinen isolierte Karbonatgesteinskörper, die als Wojcieszów-Kalke bekannt sind. Die Karbonatgesteine innerhalb der Metavulkanite zeigen sedimentäre Kontakte, während die in den Phylliten eher tektonisch begrenzt sind. So kann man den Wojcieszów-Kalken und den Metavulkaniten eine räumliche und genetische Beziehung zusprechen. Submarine Erhebungen aus Vulkangesteinen waren mit chemischen und biochemisch gefällten Karbonatserien bedeckt, wobei die vulkanische Aktivität die Karbonatbildung unmittelbar beeinflu\te.

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Résumé Parmi les métavolcanites et les phyllites de la région du Góry Kaczawskie, il existe des corps carbonatés isolés connus sous le nom de »calcaires de Wojcieszów«. Ceux qui sont inclus dans les métavolcanites présentent des contacts sédimentaires, contrairement à ceux qui sont inclus dans les phyllites, dont les contacts sont tectoniques. Entre les calcaires de Wojcieszów et les roches métavolcaniques, il est donc possible d'établir des relations spatiales et génétiques. Des reliefs volcaniques sous-marins ont été le siège d'une précipitation carbonatée chimique et biochimique dont l'intensité dépendait de l'activité volcanique.

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Effect of agricultural land use on the chemistry of groundwater from basaltic aquifers, Jeju Island, South Korea

Geochemical processes were identified as controlling factors of groundwater chemistry, including chemical weathering, salinization from seawater and dry sea-salt deposition, nitrate contamination, and rainfall recharge. These geochemical processes were identified using principal component analysis of major element chemistry of groundwater from basaltic aquifers in Jeju Island, South Korea, a volcanic island with intense agricultural activities. The contribution of the geochemical processes to groundwater chemistry was quantified by a simple mass-balance approach. The geochemical effects due to seawater were considered based on Cl contributions, whereas the effects due to natural chemical weathering were based on alkalinity. Nitrogenous fertilizers, and especially the associated nitrification processes, appear to significantly affect groundwater chemistry. A strong correlation was observed between Na, Mg, Ca, SO₄ and Cl, and nitrate concentrations in groundwater. Correspondingly, the total major cations, Cl, and SO₄ in groundwater were assessed to estimate relative effect of N-fertilizer use on groundwater chemistry. Cl originates more from nitrate sources than from seawater, whereas SO₄ originates mostly from rainwater. N-fertilizer use has shown the greatest effect on groundwater chemistry, particularly when nitrate concentrations exceed 6–7 mg/L NO₃–N. Nitrate contamination significantly affects groundwater quality and 18% of groundwater samples have contamination-dominated chemistry.     

Ecological conflicts in Poland

Transformation of the political system, observed in Poland for 10 years in connection with economic restructuring and basic socio-economic reforms to harmonise with European Union structures, is also evident in terms of environmental management. Pollution has been reduced in many ways but the rise in living standards, linked with the rapid growth of cars and other forms of consumption, has had a negative effect and environmental conditions have deteriorated in the central areas of large cities. The growth of waste water and refuse is a considerable problem. More areas are now officially protected and the three levels of local government established at the beginning of January 1999 (voivodeship, district and community) all have certain defined environmental protection responsibilities which are cumulatively greater than before. Meanwhile there is a greater awareness in society of environmental issues, although it does not yet lead to a high level of participation in protection work. However, there are strongly-expressed opinions on the ecological acceptability of certain economic developments and conflicts are frequently arising within communities and local governments and also between investors on the one side and ecological organisations and environmental protection institutions on the other. Most controversial are new roads, power stations (like the Zarnowiec nuclear project) and reservoirs like the one on the Dunajec river at Czorsztyn. Local communities frequently resist plans for waste dumps, incinerating plants and other developments which are seen as injurious to health or the quality of life. The planned reprivatisation of the state-owned forests is also criticised by foresters and ecological movements. Conflicts are likely to grow as economic development accelerates but better information and greater public understanding of the need for sustainability should make for consensus. This revised version was published online in July 2006 with corrections to the Cover Date.