Biogeochemical processes in the Chukchi Sea

Study of biogeochemical processes in water and sediments of the Chukchi Sea in August 2004 revealed atypical maximums of the concentration of biogenic elements (N, P, and Si) and the rate of microbial sulfate reduction in the surface layer (0–3 cm) of marine sediments. The C: N: P ratio in the organic matter (OM) of this layer does not fit the Redfield-Richards stoichiometric model. Specific features of biogeochemical processes in sea are likely related to the complex dynamics of water, high primary productivity (110–1400 mg C/(m² day)), low depth of basin (<50 m in 60% of the water area), reduced food chain due to low population of zooplankton, high density of zoobenthos (up to 4230 g m^?2), and high activity of microbial processes. Drastic decrease in the concentration of biogenic elements, iodine, total alkalinity (Alk), and population of microorganisms beneath the 0–3 cm layer testify to a large-scale OM decay at the water-seafloor barrier. Our original experimental data support the high annual rate of OM mineralization at the bottom of the Chukchi Sea.     

Subaquatic slope instabilities: The aftermath of river correction and artificial dumps in Lake Biel (Switzerland)

River engineering projects are developing rapidly across the globe, drastically modifying water courses and sediment transfer. Investigation of the impact of engineering works focuses usually on short-term impacts, thus a longer-term perspective is still missing on the effects that such projects have. The ‘Jura Water Corrections’ – the largest river engineering project ever undertaken in Switzerland – radically modified the hydrological system of Lake Biel in the 19th and 20th Century. The deviation of the Aare River into Lake Biel more than 140 years ago, in 1878, thus represents an ideal case study to investigate the long-term sedimentological impacts of such large-scale river rerouting. Sediment cores, along with new high-resolution bathymetric and seismic reflection datasets were acquired in Lake Biel to document the consequences of the Jura Water Corrections on the sedimentation history of Lake Biel. Numerous subaquatic mass transport structures were detected on all of the slopes of the lake. Notably, a relatively large mass transport complex (0·86 km²) was observed on the eastern shore, along the path of the Aare River intrusion. The large amount of sediment delivered by the Aare River since its deviation into the lake likely caused sediment overloading resulting in subaquatic mass transport. Alternatively, the dumping since 1963 in a subaquatic landfill of material excavated during the second phase of river engineering, when the channels flowing into and out of Lake Biel were widened and deepened, might have triggered the largest mass transport, dated to 1964 or 1965. Additional potential triggers include two nearby small earthquakes in 1964 and 1965 (M_W 3·9 and 3·2, respectively). The data for this study indicate that relatively large mass transports have become recurrent in Lake Biel following the deviation of the Aare River, thus modifying hazard frequency for the neighbouring communities and infrastructure.     

Multiscale approach to geo‐composite cellular structures subjected to rock impacts

Geo‐composite cellular structures are an efficient technological solution for various applications in civil engineering. This type of structure is particularly well adapted to resisting rockfalls and can act as a defensive structure. However, the design of such structures is for the most part empirically based; this lack of research‐based design stagnates optimization and advanced development. In this paper, the mechanical behaviour of a geo‐composite cellular structure is investigated using a multi‐scale approach, from the individual cell made up of an assembly of rocky particles contained in a wire netting cage to the entire structure composed of a regular array of cells. Based on discrete modelling of both the cell and structure scales, a computational tool has been developed for design purposes. Copyright © 2007 John Wiley & Sons, Ltd.     

Authigenic carbonates related to active seepage of methane-rich hot brines at the Cheops mud volcano,Menes caldera (Nile deep-sea fan,eastern Mediterranean Sea)

On the passive margin of the Nile deep-sea fan, the active Cheops mud volcano (MV; ca. 1,500 m diameter, ~20–30 m above seafloor, 3,010–3,020 m water depth) comprises a crater lake with hot (up to ca. 42 °C) methane-rich muddy brines in places overflowing down the MV flanks. During the Medeco2 cruise in fall 2007, ROV dives enabled detailed sampling of the brine fluid, bottom lake sediments at ca. 450 m lake depth, sub-surface sediments from the MV flanks, and carbonate crusts at the MV foot. Based on mineralogical, elemental and stable isotope analyses, this study aims at exploring the origin of the brine fluid and the key biogeochemical processes controlling the formation of these deep-sea authigenic carbonates. In addition to their patchy occurrence in crusts outcropping at the seafloor, authigenic carbonates occur as small concretions disseminated within sub-seafloor sediments, as well as in the bottom sediments and muddy brine of the crater lake. Aragonite and Mg-calcite dominate in the carbonate crusts and in sub-seafloor concretions at the MV foot, whereas Mg-calcite, dolomite and ankerite dominate in the muddy brine lake and in sub-seafloor concretions near the crater rim. The carbonate crusts and sub-seafloor concretions at the MV foot precipitated in isotopic equilibrium with bottom seawater temperature; their low δ¹³C values (–42.6 to –24.5‰) indicate that anaerobic oxidation of methane was the main driver of carbonate precipitation. By contrast, carbonates from the muddy lake brine, bottom lake concretions and crater rim concretions display much higher δ¹³C (up to –5.2‰) and low δ¹⁸O values (down to –2.8‰); this is consistent with their formation in warm fluids of deep origin characterized by ¹³C-rich CO₂ and, as confirmed by independent evidence, slightly higher heavy rare earth element signatures, the main driver of carbonate precipitation being methanogenesis. Moreover, the benthic activity within the seafloor sediment enhances aerobic oxidation of methane and of sulphide that promotes carbonate dissolution and gypsum precipitation. These findings imply that the coupling of carbon and sulphur microbial reactions represents the major link for the transfer of elements and for carbon isotope fractionation between fluids and authigenic minerals. A new challenge awaiting future studies in cold seep environments is to expand this work to oxidized and reduced sulphur authigenic minerals.     

THE IMPACT-FLOOD CONNECTION: DOES IT EXIST?*

In a recent article in Terra Nova, Kristan-Tollmann and Tollmann (1994) suggested that the Biblical Flood can be explained by seven fragments of a comet that impacted the ocean at seven locations on Earth at 03.00h (C.E.T.) on 23 September, 9545 yr BP. We demonstrate that all the ‘geological proofs’ that allegedly support their conclusions are not supported by the available data on impact cratering. Their hypothesis is based on insufficient and ambiguous data, selective citation, and incomplete comprehension of previous research.     

New brown dwarf candidates in the Pleiades

We have performed deep, wide‐field imaging on a ∼0.4 deg² field in the Pleiades (Melotte 22). The selected field was not yet target of a deep search for low mass stars and brown dwarfs. Our limiting magnitudes are R ∼ 22 mag and I ∼ 20 mag, sufficient to detect brown dwarf candidates down to 40 M_J. We found 197 objects, whose location in the (I, R – I) color magnitude diagram is consistent with the age and the distance of the Pleiades. Using CTK R and I as well as JHK photometry from our data and the 2MASS survey we were able to identify 7 new brown dwarf candidates. We present our data reduction technique, which enables us to resample, calibrate, and co‐add many images by just two steps. We estimate the interstellar extinction and the spectral type from our optical and the NIR data using a two‐dimensional χ² fitting (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

中缅毗邻区金腊Pb-Zn-Ag多金属矿田花岗岩锆石U-Pb定年与地球化学特征

位于中缅毗邻区的金腊铅锌银多金属矿田大地构造上处于保山—掸泰地块东缘,勐统—耿马—西盟元古宙—古生代被动大陆边缘活动带南段。与矿化有关的花岗岩(简称金腊花岗岩)包括老厂似斑状角闪二长花岗岩、勐林山似斑状黑云二长花岗岩和南腊碱长花岗斑岩。文中系统研究了上述岩石的主量元素、稀土元素、微量元素、成矿元素和锆石U-Pb同位素年龄等特征,从构造岩浆演化的角度,探讨上述岩体之间内在联系、成因演化以及与成矿的关系:(1)在金腊花岗岩三种岩石类型中,老厂似斑状角闪二长花岗岩和勐林山似斑状黑云二长花岗岩的锆石同位素U-Pb年龄皆为(45±1)Ma,形成于岩浆结晶分异早期阶段的深成环境,而南腊碱长花岗斑岩的锆石同位素U-Pb年龄为(43.41±0.78)Ma,形成于岩浆结晶分异晚期阶段的浅成环境。(2)主量元素和微量元素(稀土元素和某些微量元素(Zr/Hf、Nb/Ta、Rb/Sr、Rb/Ba、K/Rb、(Rb/Yb)N、Sr*、K*和Zr*)),结合U-Pb同位素定年研究表明,本区花岗岩形成于喜马拉雅同碰撞造山成矿作用末期局部拉张构造环境,并分别代表了构造岩浆演化过程中不同演化阶段岩浆分异结晶的产物。(3)上述三类花岗岩样品皆位于S型花岗岩区,但从老厂似斑状角闪二长花岗岩,勐林山似斑状黑云二长花岗岩,到南腊碱长花岗斑岩,样品分布逐渐远离"I"型花岗岩和"S"型花岗岩的分界线,这表明自老厂似斑状角闪二长花岗岩至勐林山似斑状黑云二长花岗岩,到南腊碱长花岗斑岩幔源组分逐渐减少。(4)相对中国花岗岩,南腊碱长花岗斑岩不仅更富集W、Cu、Bi、Sb、Mo、Sn、Ag、Pb和Au等成矿元素,而且还强烈富集F、B和As等矿化剂元素,因此,碱长花岗斑岩是最有成矿远景的岩体。     

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.