Separate lead isotope analyses of leachate and residue rock fractions: implications for metal source tracing in ore deposit studies

Separate lead isotope analyses of leachate and residue fractions are applied to a broad spectrum of rocks commonly investigated in metallogenic studies. Resulting data highlight a systematic behavior of leachate and residue fractions with respect to lead isotope compositions, which essentially depends on the mineralogical composition of the rock. Granitoid and high-grade metamorphic rocks have residue compositions virtually identical to common lead. In contrast, low-grade metasedimentary rocks may have residue compositions swamped by radiogenic lead of leach-resistant zircons. Mafic magmatic rocks have residues that are often more radiogenic than leachates, depending on the ratio of leach-refractory zircons to common lead in the residual fraction of these rocks. Separate leachate and residue analyses of source rocks provide two lead isotope end members whose mixture may represent lead with the appropriate ore fluid composition. Our leaching experiments indicate that hot acid solutions (and by inference hydrothermal fluids) preferentially leach radiogenic lead from medium- to high-grade metamorphic and granitoid rocks, whereas they preferentially leach common lead from low-grade metasedimentary and mafic magmatic rocks. The method presented in this study provides a reliable alternative to other methods (i.e., age-correction of bulk-rock compositions) for the determination of the common lead signature of felsic to intermediate magmatic rocks. This may be preferable to age-corrected bulk-rock analyses, where ages to apply for corrections of bulk-rock data are not known or where moderately to highly altered rocks must be used. Case studies of orogenic gold and MVT districts of Peru (Pataz and San Vicente, respectively) show that separate leachate and residue lead isotope analyses carried out systematically on whole rocks allow a more thorough evaluation of metal source reservoirs than does the standard method of age-corrected or uncorrected bulk-rock analyses.     

High-resolution seismic stratigraphy of the late Neogene of the central sector of the Colombian Pacific continental shelf: A seismic expression of an active continental margin

The sedimentary prism of the central Pacific continental shelf of Colombia was affected by regional folding and faulting, and probably later mud diapirism, from the Late Miocene to the Holocene. Interpretation of high-resolution seismic lines (2 s/dt) revealed that the prism consists of 13 high-resolution seismic units, that can be separated into 5 seismic groups.Deposition of the prism and the associated stacking pattern, are probably the response to variable uplift and subsidence in a fore-arc basin that underwent important tectonic events by the end of the Miocene. Throughout the Pliocene, the continental shelf sedimentation was affected by the growing of a dome structure probable due to mud diapirism. This fact caused peripheral faults both normal and reverse that controlled the distribution of some of the seismic units. During the Late Pleistocene (Wisconsin stage?) a eustatic sea level fall caused the shoreline to advance about 50 km westward of its present position. Because of this eustatic sea level change, a strong fluvial dissection took place and is interpreted as the probable extension of the San Juan River to the south of the present day river mouth. Within this framework it is believed that the Malaga and Buenaventura Bays were the passageways of branches of the old drainage system of the San Juan River. The inner branch circulated through the present Buenaventura Bay and runs southward leaving the mark of an apparent valley identified in the seismic information in the eastern sector of the study area. This old fluvial valley and its filling material located in the present day inner continental shelf front of Buenaventura are postulated as important targets to find placer minerals such as gold and platinum.     

The Deformational Response of a Viscoelastic Solid Earth Model Coupled to a Thermomechanical Ice Sheet Model

We apply a coupled thermomechanical ice sheet—self-gravitating viscoelastic solid Earth model (SGVEM), allowing for the dynamic exchange of ice thickness and bedrock deformation, in order to investigate the effect of viscoelastic deformation on ice dynamics and vice versa. In a synthetic glaciation scenario, we investigate the interaction between the ice sheet and the solid Earth deformation, the glacial-isostatic adjustment (GIA), accounting for an atmospheric forcing depending on the ice sheet surface altitude. We compare the results from the coupled model to runs with the common elastic lithosphere/relaxing asthenosphere (ELRA) model, where the lithosphere is represented by a thin plate and the mantle relaxes with one characteristic relaxation time, as well as to a rigid Earth without any deformation. We find that the deformational behaviour of the SGVEM on ice dynamics (i.e. stored ice volume, ice thickness and velocity field) is comparable to the ELRA for an optimal choice of the parameters in steady state, but exhibits differences in the transient behaviour. Beyond the ice sheet, in the region of peripheral forebulge, the differences in the transient surface deformation between ELRA and SGVEM are substantial, demonstrating the inadequacy of the ELRA model for interpreting constraints on GIA in the periphery of the ice sheet, such as sea-level indicators and GPS uplift rates.     

Evolution of the Kivu Rift,East Africa: interplay among tectonics,sedimentation and magmatism

The seismically and volcanically active Kivu Rift, in the western branch of the East African Rift System, is a type locale for studies of high‐elevation, humid‐climate rift basins, as well as magmatic basin development. Interpretations of offshore multi‐channel seismic (MCS) reflection data, terrestrial radar topography, lake bathymetry and seismicity data recorded on a temporary array provide new insights into the structure, stratigraphy and evolution of the Kivu rift. The Kivu rift is an asymmetric graben controlled on its west side by a ca. 110 km‐long, N‐S striking border fault. The southern basins of the lake and the upper Rusizi river basin are an accommodation zone effectively linking 1470 m‐high Lake Kivu to 770 m‐high Lake Tanganyika. MCS data in the eastern Kivu lake basin reveal a west‐dipping half graben with at least 1.5 km of sedimentary section; most of the ca. 2 km of extension in this sub‐basin is accommodated by the east‐dipping Iwawa normal fault, which bounds an intrabasinal horst. Lake Kivu experienced at least three periods of near desiccation. The two most recent of these approximately correlate to the African Megadrought and Last Glacial Maximum. There was a rapid lake level transgression of at least 400 m in the early Holocene. The line load of the Virunga volcanic chain enhances the fault‐controlled basin subsidence; simple elastic plate models suggest that the line load of the Virunga volcanic chain depresses the basin by more than 1 km, reduces flank uplift locally and broadens the depocentre. Not only do the voluminous magmatism and degassing to the lake pose a hazard to the riparian population, but our studies demonstrate that magmatism has important implications for short‐term processes such as lake levels, inflow and outlets, as well as long term modification of classic half‐graben basin morphology.     

Study of a rockfall in a limy conglomerate canyon (Covarrubias, Burgos, N. Spain)

In this paper, a rockfall of some tenths of cubic metres of rock, occurred in a conglomerate canyon in the northern Castilian plateau (N-Central Spain), is described in detail. This includes the basic data (geology, mapping, meteorological data and rock involved), the mechanical mechanism of the instability, the propagation and reach of the fallen rock boulders and the final location of the pieces. The study is based on detailed geological, aerial photography and geotechnical studies and advance topographical measurements. Geological engineering techniques are used to analyze the instability initiation and rockfall propagation. This study contributes to a better understanding of the geological processes leading to the occurrence of calcareous canyons and cliffs in the drainage network of the upper Castilian plateau. It is also helpful to improve our knowledge on natural rockfall phenomena for risk engineering purposes aiming to quantify, control and mitigate associated hazards.     

The structural vulnerability in the framework of natural hazard risk analyses and the exemplary application for storm loss modelling in Tyrol (Austria)

In the context of natural hazard-related risk analyses, different concepts and comprehensions of the term risk exist. These differences are mostly subjected to the perceptions and historical backgrounds of the different scientific disciplines and results in a multitude of methodological concepts to analyse risk. The target-oriented selection and application of these concepts depend on the specific research object which is generally closely connected to the stakeholders’ interests. An obvious characteristic of the different conceptualizations is the immanent various comprehensions of vulnerability. As risk analyses from a natural scientific-technical background aim at estimating potential expositions and consequences of natural hazard events, the results can provide an appropriate decision basis for risk management strategies. Thereby, beside the preferably addressed gravitative and hydrological hazards, seismo-tectonical and especially meteorological hazard processes have been rarely considered within multi-risk analyses in an Alpine context. Hence, their comparative grading in an overall context of natural hazard risks is not quantitatively possible. The present paper focuses on both (1) the different concepts of the natural hazard risk and especially their specific expressions in the context of vulnerability and (2) the exemplary application of the natural scientific-technical risk concepts to analyse potential extreme storm losses in the Austrian Province of Tyrol. Following the corresponding general risk concept, the case study first defines the hazard potential, second estimates the exposures and damage potentials on the basis of an existing database of the stock of elements and values, and third analyses the so-called Extreme Scenario Losses (ESL) considering the structural vulnerability of the potentially affected elements at risk. Thereby, it can be shown that extreme storm events can induce losses solely to buildings and inventory in the range of EUR 100–150 million in Tyrol. However, in an overall context of potential extreme natural hazard events, the storm risk can be classified with a moderate risk potential in this province.     

Fishing for diatoms: fish gut analysis reveals water quality changes over a 75-year period

Defining the reference state of some perturbed streams and rivers is challenging since their non-altered state is undocumented. Despite the near-absence of pristine sites in highly anthropogenic areas, information about aquatic communities that existed prior to human disturbance can be obtained from historic sources. Sediment coring is commonly used in paleolimnology to estimate past environmental conditions of lakes, but this technique is often not appropriate for studies of lotic systems. An alternative is to use diatom assemblages present in the guts of fish that were captured in the streams prior to significant human disturbance. The purpose of the present study was to evaluate the biological integrity of several streams in Ontario and Québec during the early twentieth century based on “paleo” diatom assemblages extracted from the guts of fish stored in museums. The Eastern Canadian diatom index (IDEC: Indice Diatomées de l’Est du Canada) was used to evaluate the biological status of “paleo” and “modern” diatom assemblages. The IDEC shows the position of diatom assemblages on a general pollution gradient. The comparison of IDEC values calculated for the 1925–1948 and the 2003–2007 periods showed that several streams were severely polluted in the early 1900s. In general, present water quality has declined compared to the early 1900s. The biological integrity of only three of the 22 sites has increased. IDEC values were not influenced by the species of fish studied.     

Thermochronology and exhumation rates of granitic intrusions at Mesa Central,Mexico

ABSTRACT

The Mesa Central of Mexico (MC) is an elevated plateau located 2000 m above sea level in central Mexico, where intrusions outcrop that register the history of exhumation-erosion occurring during the Late Cretaceous-Paleogene. The tectonic history of the region records formation of the Late Cretaceous-Paleogene ‘Mexican orogen’; this was followed by extension of the entire region and several plutons were then exhumed. The age and magnitude of the crustal uplift and erosion occurring during exhumation has not been addressed to date. Therefore, this study reports the crystallization and cooling ages of two plutons, the Tesorera Granodiorite and the Comanja Granite, and estimates their emplacement depths. Based on these data, the exhumation age of the Tesorera Granodiorite is estimated to be between ~73 Ma and ~63 Ma at an exhumation rate of ~528 m/m. y. and that of the Comanja Granite is 52 Ma and 48 Ma at an exhumation rate of ~2500 m/m. y. Exhumation-erosion event of the Tesorera Granodiorite was located on the trace of the San Luis-Tepehuanes Fault System and that of the Comanja Granite on the a trace of the El Bajío Fault System. Furthermore, the high exhumation rate in the Comanja Granite suggests that gravitational collapse played an important role during exhumation.