Evidence for mass-dependent isotopic fractionation of strontium in a glaciated granitic watershed

The stable isotope composition of strontium (expressed as δ^88/86Sr) may provide important constraints on the global exogenic strontium cycle. Here, we present δ^88/86Sr values and ⁸⁷Sr/⁸⁶Sr ratios for granitoid rocks, a 150 yr soil chronosequence formed from these rocks, surface waters and plants in a small glaciated watershed in the central Swiss Alps. Incipient chemical weathering in this young system, whether of inorganic or biological origin, has no resolvable effect on the ⁸⁷Sr/⁸⁶Sr ratios and δ^88/86Sr values of bulk soils, which remain indistinguishable from bedrock in terms of Sr isotopic composition. Although due in part to the chemical heterogeneity of the forefield, the lack of a resolvable difference between soil and bedrock isotopic composition indicates that these soils have thus far witnessed minimal net loss of Sr; a low degree of chemical weathering is also implied by bulk soil chemistry. The isotopic composition of Sr in streamwater is more radiogenic than median soil, reflecting the preferential weathering of biotite in the catchment; streamwater δ^88/86Sr values, however, are indistinguishable from bulk soil δ^88/86Sr values, implying that no resolvable fractionation of Sr isotopes takes place during release to the weathering flux in the Damma forefield. Analyses of plant tissue reveal that plants (Rhododendron and Vaccinium) preferentially assimilate the lighter isotopes of Sr such that their δ^88/86Sr values are significantly lower than those of the soils in which they grow. Additionally, δ^88/86Sr values of foliar and floral tissues are lower than those of roots, contrary to observations for Ca, for which Sr is often used as an analogue in weathering studies. We suggest that processes that discriminate against Sr in favour of Ca, due to the different nutritional requirement of plants for these two elements, are responsible for the observed contrast.     

Influence of climatic teleconnections on the temporal isotopic variability as recorded in a firn core from the coastal Dronning Maud Land,East Antarctica

Ice and firn core studies provide one of the most valuable tools for understanding the past climate change. In order to evaluate the temporal isotopic variability recorded in ice and its relevance to environmental changes, stable isotopes of oxygen and hydrogen were studied in a firn core from coastal Dronning Maud Land, East Antarctica. The annual δ ¹⁸O profile of the core shows a close relation to the El Niño Southern Oscillation (ENSO) variability. The ENSO indices show significant correlation with the surface air temperatures and δ ¹⁸O values of this region during the austral summer season and support an additional influence related to the Southern Annular Mode (SAM). The correlation between the combined ENSO-SAM index and the summer δ ¹⁸O record seems to have been caused through an atmospheric mechanism. Snow accumulation in this region illustrates a decreasing trend with opposite relationships with δ ¹⁸O data and surface air temperature prior and subsequent to the year 1997. A reorganization of the local water cycle is further indicated by the deuterium excess data showing a shift around 1997, consistent with a change in evaporation conditions. The present study thus illustrates the utility of ice-core studies in the reconstruction of past climate change and suggests possible influence of climatic teleconnections on the snow accumulation rates and isotopic profiles of snow in the coastal regions of east Antarctica.     

Mobility of potentially harmful metals in latosols impacted by the municipal solid waste deposit of Londrina,Brazil

The contamination of soils by metals issuing from municipal solid waste (MSW) disposal in tropical environments has hardly been studied with regard to the particular problems associated with them, i.e., generally a high permeability of soils despite the abundance of clay, and the role of reactive Fe compounds. From a previous geotechnical and chemical survey, three latosol profiles differently affected by MSW leachates in the region of Londrina (Paraná, Brazil) were selected. The aims were to evaluate the extent of their contamination, to better understand the fate of potentially harmful metals in tropical soils and rank the determining factors. Samples between 0.5 and 7 m depth were analyzed for their physical, mineralogical and chemical properties, and their micro-morphology was described by optical and transmission electron microscopy. Two steps of a sequential extraction procedure helped to assess the mobility of elements and to better discriminate between metals originating from pedogenesis and issued from MSW. These combined approaches showed that exposed soil profiles have been impacted at various depths, down to 7 m, through increased metal content, especially enhanced mobility of Zn, Co, Mn, Cu and Fe, and through increased salinity and organic matter. The mobility of potentially harmful metals should decrease with pH, which significantly increased in some impacted horizons, but other factors can reverse this trend.     

Mobility of metals in nickel mine spoil materials

An understanding of the biogeochemical behaviour of metals in mine spoil materials is a prerequisite to rehabilitate Ni mining sites. The objective of this study was to characterize the fate of metals in different Ni ore spoil materials as influenced by hydrological conditions and fertilisation practices. In tropical ultramafic complexes, the different stages of lateritic weathering lead to two types of ores, and therefore, to two spoil types. They are mainly either a clay-rich saprolite, so-called “garnierite”, enriched in phyllosilicates, or a limonitic material, enriched in Fe oxides. Lysimeter columns were designed to monitor leaching waters through both spoil materials. The garnieritic spoil released higher concentrations of Mg (mean = 2.25 mg L⁻¹), Ni (0.39 mg L⁻¹) and Cr (1.19 mg L⁻¹) than the limonitic spoil (Mg = 0.5 mg L⁻¹; Ni = 0.03 mg L⁻¹ and Cr = 0.25 mg L⁻¹). Chromium was mainly in an anionic form in leaching solutions. As exchangeable pools of Cr(VI) in limonite (980 mg kg⁻¹ of KH₂PO₄-extractable Cr) are considerable its release in water may still occur in the case of a pH increase. In mixed spoil, metal concentrations were almost as low as in the limonitic one. The effect of mineral-N fertilisation was a strong release of cations (Ni, Mg) into the leachate. Phosphate amendment did not affect the soil solution composition under experimental conditions.     

Recent Changes Occurred in the Terminus of the Debris-covered Bilafond Glacier in the Karakoram Himalayas Using Remotely Sensed Images and Digital Elevation Models (1978-2011)

Recent changes occurred in terminus of the debris-covered Bilafond Glacier in the Karakoram Range in the Himalayas, Northern Pakistan was investigated in this research. Landsat MSS, TM and ETM＋ images were used for this study. Digital elevation models derived from ASTER GDEM and SRTM were also utilized. Visible, infrared and thermal infrared channels were utilized in order to get accurate glacier change maps. Three methods were tried to map this debris-covered glacier in this research. The glacier has been mapped successfully and the changes in the glacier terminus from 1978 to 2011 have been calculated. Manual, semi-automatic and thermal methods were found to give similar results. It was found that the glacier has undergone serious ablation during this period despite of the fact that many of the larger glaciers in the Hindu Kush and Karakoram mountain regions in the Upper Indus Basin were reported to be expanding. The terminus has been moved back about 600 meters during this period and there was an abrupt change in the glacier terminus during 1990-2002. We propose that debris thickness is not the only factor that influences the glacier ablation but the altitude of the debris-covered glacier as well. Many glaciers in the Karakoram region reported to be expanding were having higher altitudes compared to the study area.     

Combined influence of PDO and ENSO on northern Andean glaciers: a case study on the Cotopaxi ice-covered volcano,Ecuador

This paper describes the application of remote sensing in monitoring the fluctuations in one of the mountain glaciers in the Ecuadorean Andes during the past few decades using ASTER, EO-1 ALI, Landsat MSS, TM and ETM + images. Satellite images were used to calculate the snow line altitudes (SLAs) during the period 1979–2013. Cotopaxi ice covered volcano was studied as representative of Ecuadorian glaciers in the eastern cordillera. Precipitation and air temperature data from various gauging stations within the range of 30 km from the study site and monthly discharge and water level data from a gauging station were also utilized in this study. Anomalies in precipitation and temperature were found to be slightly different in the Cotopaxi region compared to nearby Antizana in the same cordillera and Chimborazo region in the western cordillera. An attempt to correlate the El Niño—southern oscillation phenomenon with the glacier fluctuations in Ecuadorian Andes was done successfully. Cold and warm regimes of Pacific Decadal Oscillation is also considered. The calculated glacier fluctuations obtained were similar to that performed on the nearby Antizana 15 in the eastern cordillera during 1995–2002. Precipitation and temperature anomalies were similar with Antizana 15. It is evident from the research that SLAs were highly fluctuated between the period of occurrence of El Niño and La Niña events. It is also seen that the glacier fluctuations show a negative mass balance trend in during the warm regime of Pacific Decadal Oscillation during the past three decades. Glaciated areas were advanced during the La Nina events in the cold regime of PDO during 1998–2002.     

Tectonic inversion assessed by integration of geological and geophysical data: The intracontinental Rio do Peixe Basin,NE Brazil

Common basin models assume that the post‐rift tectonic evolution of most basins is usually associated with tectonic quiescence. However, tectonic inversion during the post‐rift phase has been proposed for several sedimentary basins worldwide, but how and why it happens is still a matter of debate, especially in intracontinental settings where the lithosphere is old and thick. Here, we use geological and geophysical data from the Rio do Peixe Basin in NE Brazil to show evidence that intracontinental sedimentary basins can be tectonically inverted by far‐field compressive stresses acting on pre‐existing weakness zones of lithospheric‐scale where stresses can concentrate and inversion can occur. Geomorphological and field data combined with seismic reflection, gravimetric and borehole data show that: (a) inversion occurred along two main Precambrian lithospheric‐scale shear zones, the Patos (E‐W trending) and Portalegre (NE‐SW trending), which had already been reactivated as basin‐bounding faults during the earlier rift stage; (b) post‐rift reactivation affected (mostly) the original master normal faults with the largest rift displacements, and locally produced new reverse faults; (c) during contraction, deformation was partitioned between fault reactivation and buckling of the incompetent sediment pushed against the hard basement; (d) all these signs of inversion have been observed in the field and can be demonstrated on seismic reflection profiles; and (e) combined gravimetric and seismic data show that the main structures of the basin were followed by an inversion. These data are consistent with the operation of WSW‐ENE horizontal maximum compressive stress as a result of combined pushes of the Mid‐Atlantic Ridge (towards the W) and the Andes (towards the E), responsible for the post‐rift oblique inversion of normal faults inherited from the rift phase and formed with vertical maximum compressive stress.     

Morphology and dynamics of the intertidal floodplain along the Amazon tidal river

Depositional environments along the tidal river downstream of Óbidos have been proposed as important sinks for up to one third of the sediment discharge from the Amazon River. However, the morphology of the intertidal floodplain and the dynamics of sediment exchange along this reach have yet to be described. River-bank surveys in five regions along the Amazon tidal river reveal a distinct transition in bank morphology between the upper, central and lower reaches of the tidal river. The upper tidal-river floodplain is defined by prominent natural levees that control the transfer of water and sediment between the mainstem Amazon River and its floodplain. Greater tidal influence in the central tidal river suppresses levee development, and tidal currents increase sediment transport into the distal parts of the floodplain. In the lower tidal river, the floodplain morphology closely resembles marine intertidal environments (e.g. mud flats, salt marshes), with dendritic tidal channels incising elevated vegetated flats. Theory, morphology and geochronology suggest that the dynamics of sediment delivery to the intertidal floodplain of the Amazon tidal river vary along its length due to the relative influence and coupling of fluvial and tidal dynamics. © 2018 John Wiley & Sons, Ltd.     

Modeling flocculation in a hypertidal estuary

When fine particles are involved, cohesive properties of sediment can result in flocculation and significantly complicate sediment process studies. We combine data from field observations and state-of-the-art modeling to investigate and predict flocculation processes within a hypertidal estuary. The study site is the Welsh Channel located at the entrance of the Dee Estuary in Liverpool Bay. Field data consist of measurements from a fixed site deployment during 12–22 February 2008. Grain size, suspended sediment volume concentration, and current velocity were obtained hourly from moored instruments at 1.5 m above bed. Near-bottom water samples taken every hour from a research vessel are used to convert volume concentrations to mass concentrations for the moored measurements. We use the hydrodynamic model Proudman Oceanographic Laboratory Coastal Ocean Modelling System (POLCOMS) coupled with the turbulence model General Ocean Turbulence Model (GOTM) and a sediment module to obtain three-dimensional distributions of suspended particulate matter (SPM). Flocculation is identified by changes in grain size. Small flocs were found during flood and ebb periods—and correlate with strong currents—due to breakup, while coarse flocs were present during slack waters because of aggregation. A fractal number of 2.4 is found for the study site. Turbulent stresses and particle settling velocities are estimated and are found to be related via an exponential function. The result is a simple semiempirical formulation for the fall velocity of the particles solely depending on turbulent stresses. The formula is implemented in the full three-dimensional model to represent changes in particle size due to flocculation processes. Predictions from the model are in agreement with observations for both settling velocity and SPM. The SPM fortnight variability was reproduced by the model and the concentration peaks are almost in phase with those from field data.