Factors contributing to heavy metal accumulation in sediments and in the intertidal mussel Perna perna in the Gulf of Annaba (Algeria)

This paper presents the results of a seasonal survey of heavy metals accumulated in sediments and in the soft parts of the body of the mussel Perna perna at four stations in the Gulf of Annaba (Algeria). Pooled soft tissues from 10 mussels representing the entire range of sizes were digested in nitric acid. Statistical analysis reveals a significant seasonal effect on all the measured metals, the highest values being recorded in winter. With the exception of Cr, the levels for all metals were significantly higher in the east, at the outlet of the Seybouse River, than at all other monitoring stations. The study also shows that north-western waters are subject to a significantly lower degree of heavy metal pollution than elsewhere in the gulf. Levels were nevertheless within the limits of public health standards.     

Constraints of archaeomagnetic dating and field intensity determinations in three ancient tile kilns in Belgium

The aim of this study is to date by the archaeomagnetic method the last heatingcooling cycle of one Roman and two Medieval tile kilns, discovered in Belgium. The investigation demonstrates the limitations when well-documented local directional secular variation curves of the geomagnetic field in the past are used for dating and the difficulties when trying to determine field intensities from “in situ” baked clays from the kilns. The three kilns yielded very well defined ancient field directions but two possible dating solutions for each of them when no a priori time constraints are taken into account, due to field direction recurrence. As an increase of the dating accuracy and reduction of the number of dating solutions can be expected using the full field vector information, also field intensity determinations on burnt clays from the kilns were attempted. Field intensities from samples of the Roman and of one of the Medieval kilns are quite scattered. On the other hand, results obtained applying the Thellier-Thellier method and the modified method developed by Dekkers and Böhnel on sister samples from the Roman kiln agree fairly well. Rock magnetic properties reveal high variance in the kilns that point to varying spatial heating and cooling conditions in the kilns. Even well burnt material from the kilns shows irreversible changes when heated in air in the laboratory. Reliable field intensities on “in situ” baked materials from kilns themselves can therefore only be obtained when measuring sufficient number of samples from different parts of the kiln, taking into account the spatial-temporal conditions during kiln operation and cooling history. More reference intensity data is needed in our regions in order to improve dating based on directional reference data only.     

Geophysical Constraints on the Location and Nature of the North Saharan Flexure in Southern Tunisia

Gravity data, integrated with seismic refraction/reflection data, well data and geological investigations, were used to determine the location of the paleogeographic boundary between the Precambrian Saharan domain and the younger Tunisian Atlas domain. This boundary (North Saharan Flexure or NSF) has not been as clearly defined as it has been to the west in Algeria and Morocco. The gravity data analysis, which included the construction of complete Bouguer and residual gravity anomaly maps, revealed that the Atlasic domain is characterized by relative negative gravity anomalies and numerous linear gravity trends implying a thick and deformed sediment cover. The Saharan domain is characterized by relatively positive gravity anomalies with few gravity trends implying a thin and relatively undeformed sediment cover. An edge-enhancement analysis of the residual gravity anomalies revealed that the NSF is characterized by a series of discontinuous east- and northwest-trending linear anomalies south of 34°N that are not related to the well-known faults within the Gafsa and Accident de Medenine regions. Based on the continuity of the amplitudes of seismic reflection data and the trends of the residual gravity anomalies, the NSF is not an abrupt discontinuity but a series of step faults dipping toward the Atlasic domain. To obtain a more quantitative representation of the southern edge of Tunisian Atlas, a regional gravity model constrained by two wells and seismic reflection/refraction data was constructed along a north-south trending profile which confirms the presence of thicker sediments north of the NSF. Our analysis shows that the NSF has controlled the depositional environment of the sedimentary rocks within the region since at least Triassic time and has acted as a barrier to Atlasic deformation south of the NSF. The NSF is considered an important tectonic feature that has controlled the paleogeographic evolution of the southern margin of the Tethys Ocean, and it continues to be active today based on seismicity hazard studies.     

Evidence for Triassic salt domes in the Tunisian Atlas from gravity and geological data

Detailed gravity data were analyzed to constrain two controversial geological models of evaporitic structures within the Triassic diapiric zone (Triassic massifs of Jebel Debadib and Ben Gasseur) of the northern Tunisian Atlas. Based on surface observations, two geological models have been used to explain the origin of the Triassic evaporitic bodies: (1) salt dome/diapiric structure or (2) a “salt glacier”. The gravity analysis included the construction of a complete Bouguer gravity anomaly map, horizontal gravity gradient (HGG) map and two and a half-dimensional (2.5D) forward models. The complete Bouguer gravity anomaly map shows a prominent negative anomaly over the Triassic evaporite outcrops. The HGG map showed the location of the lateral density changes along northeast structural trends caused by Triassic/Cretaceous lithological differences. The modeling of the complete Bouguer gravity anomaly data favored the diapiric structure as the origin of the evaporitic bodies. The final gravity model constructed over Jebel Debadib indicates that the Triassic evaporitic bodies are thick and deeply rooted involving a dome/diapiric structure and that the Triassic material has pulled upward the younger sediment cover by halokinesis. Taking in account kinematic models and the regional tectonic events affecting the northern margin of Africa, the above diapirs formed during the reactive to active to passive stages of continental margin evolution with development of sinks. Otherwise, this study shows that modeling of detailed gravity data adds useful constraints on the evolution of salt structures that may have an important impact on petroleum exploration models.     

Groundwater resources of a multi-layered aquiferous system in arid area: Data analysis and water budgeting

The Maknassy basin in central Tunisia receives insignificant precipitation (207 mm/y), but the hydrological system retain very small quantities of water due to the steep topography and surface water resource partially mobilised witch is evacuated toward the basin outlet. However, the Maknassy plain support agriculture based on ground water irrigation with increasing water demand last decades. These developments have boosted agricultural productivity in the region. While these problems are mainly due to poor surface water management strategies in the region, the groundwater resources in this basin should be properly assessed and suitable measures taken for uniform surface water mobilization. As a first step in this direction, groundwater resources have been assessed. Regional specific yield (0.017) and groundwater recharge have been estimated on the basis of water table fluctuation method. Groundwater recharge amounting to 61.5 10⁶ m³ in a year takes place in the region through infiltration of rainwater (48.1*10⁶ m³ for phreatic aquifer and 13.4*10⁶ m³ for the deep one), and recharge due to the infiltration in the Leben quady bed (1.57*10⁶ m³). Recharge to deeper aquifers has been estimated at 0.1*10⁶ m³ during dry seasons. Assuming that at least 40 % (102.61*10⁶ m³) of the total precipitation water (256.64*10⁶ m³) makes the runoff water, this important resource can be mobilized in order to increase groundwater recharge. Subject to an arid climate, such region requires an integrated water resource management. It permits to keep aquiferous system equilibrium and participate to the sustainable development which integrates natural resource management.     

Study of the interaction between U(VI) and the anoxic corrosion products of carbon steel

The objective of this study was to investigate the removal mechanism of U(VI) from groundwater by magnetite as the main product of anoxic steel corrosion. For this purpose, a systematic sequence of batch experiments was conducted to focus the active role of magnetite in the reduction of U under different conditions. Results indicated that under anoxic conditions U(VI) was sorbed at the magnetite surface, whereas under reducing conditions at different H₂(g) pressures, U was present in tetravalent form as amorphous UO₂.     

Probabilistic seismic hazard assessment of Switzerland: best estimates and uncertainties

We present the results of a new genera tion of probabilistic seismic hazard assessment for Switzerland. This study replaces the previous intensity-based generation of national hazard maps of 1978. Based on a revised moment-magnitude earthquake catalog for Switzerland and the surrounding regions, covering the period 1300–2003, sets of recurrence parameters (a and b values, M _max ) are estimated. Information on active faulting in Switzerland is too sparse to be used as source model. We develop instead two models of areal sources. The first oriented towards capturing historical and instrumental seismicity, the second guided largely by tectonic principles and express ing the alterative view that seismicity is less stationary and thus future activity may occur in previously quiet regions. To estimate three alterna tive a and b value sets and their relative weighting, we introduce a novel approach based on the modified Akaike information criterion, which allows us to decide when the data in a zone deserves to be fitted with a zone-specific b value. From these input parameters, we simulate synthetic earthquake catalogs of one-million-year duration down to magnitude 4.0, which also reflect the difference in depth distribution between the Alpine Foreland and the Alps. Using a specific predictive spectral ground motion model for Switzerland, we estimate expected ground motions in units of the 5% damped acceleration response spectrum at frequencies of 0.5–10 Hz for all of Switzerland, referenced to rock sites with an estimated shear wave velocity of 1,500 m/s² in the upper 30 m. The highest hazard is found in the Wallis, in the Basel region, in Graubünden and along the Alpine front, with maximum spectral accelerations at 5 Hz frequency reaching 150 cm/s² for a return period of 475 years and 720 cm/s² for 10,000 years. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users.