Constraints from eclogite and MARID xenoliths on origins of mantle Zr/Hf–Nb/Ta variability

New trace-element data of rutile in kimberlite-borne ~1.85 Ga eclogite and pyroxenite xenoliths from the central Slave craton, as well as ~110 Ma MARID xenoliths from the Kaapvaal craton, provide constraints on the origins of lithospheric and sublithospheric mantle variability in high field strength element ratios. Rutiles in eclogites and pyroxenites have Zr/Hf ranging from 20 to 62 and Nb/Ta ranging from 10 to 40. Rutiles in MARID xenoliths have Zr/Hf from 24 to 33 and Nb/Ta from 10 to 41. Calculated whole-rock Zr/Hf is suprachondritic for eclogites with suggested gabbroic protoliths and subchondritic for boninite-like eclogites; the latter is consistent with cpx-controlled depletion in the protolith source. Within each eclogite type, positive correlations of Zr/Hf with La/Lu and negative correlations with Lu/Hf likely reflect fractionation of cpx and/or plagioclase during crystallisation of the protoliths. Zr/Hf–Nb/Ta relationships of some MARID-type rocks, which are products of lithospheric mantle metasomatism, and eclogite xenoliths plot on a silicate differentiation trend, whereas other samples have higher Nb/Ta at a given Zr/Hf. Fractionation of a few percent rutile from an HFSE-rich mafic melt can generate a trend towards strongly increased Nb/Ta at minimally changed Zr/Hf in the residual melt. Superposition of rutile fractionation on the effects of silicate differentiation, which fractionates Zr/Hf more strongly than Nb/Ta, can explain the Zr/Hf–Nb/Ta relationships of most eclogites from the central Slave craton as well as those of MARID rocks, metasomatised peridotites and group II kimberlites. By contrast, Zr/Hf–Nb/Ta relationships suggest that Group I kimberlites are mixtures between depleted peridotite and carbonatite. Thus, high Nb/Ta is a signature of lithospheric processes and may not be important in deeply subducted eclogites that bypass extended residence in the lithosphere. Conversely, considerable primary Zr/Hf variability was inherited by the eclogites, which is indicative of the compositional diversity of ancient subducted oceanic crust, which is expected to have generated substantial heterogeneity in sublithospheric basalt sources.     

Wages,gender and industrial structure in New Zealand

A variant of shift‐share analysis is applied to manufacturing wages data for 22 districts in New Zealand for 1980 and 1984, to test, via three models, the explanatory power of components representing the gender split and industrial structure of the workforce separately and in combination. These first three components provide a surprisingly low level of explanation in many districts, and, overall, their national performance has declined over time. The consequent rise of a fourth, ‘residual’ element is examined in more detail, and suggestions offered for its observed geography.     

Variations of sea surface temperature and primary productivity during Heinrich and Dansgaard-Oeschger events in the northeastern Arabian Sea

Sea surface temperatures (SST) and primary productivities have been reconstructed for the northeastern Arabian Sea during the past 65,000 years, using C₃₇-alkenones. Comparison of this SST record with '¹⁸O from Greenland ice core GISP2 shows striking similarities, indicating an apparent linkage between the climate of the Arabian Sea with that of the northern North Atlantic, most probably via atmospheric and/or oceanic circulation. These rapid SST changes are in the long term overlain by insolation changes at 30°N.     

High resolution observations of the radio emission from luminous YSOs

New, high-resolution 1.66 GHz MERLIN maps of Cep A2 and LkH101 are presented and discussed.     

Infrared velocity mapping of compact HII regions

We present initial results of a programme to map the velocity field of a sample of compact HII regions using near infrared HI Br emission. Data are shown in particular for the well studied region G29.96-0.02.     

Leveraging correlation across space and time to interpolate geophysical data via CoKriging

Managing geophysical data generated by emerging spatiotemporal data sources (e.g. geosensor networks) presents a growing challenge to Geographic Information System science. The presence of correlation poses difficulties with respect to traditional spatial data analysis. This paper describes a novel spatiotemporal analytical scheme that allows us to yield a characterization of correlation in geophysical data along the spatial and temporal dimensions. We resort to a multivariate statistical model, namely CoKriging, in order to derive accurate spatiotemporal interpolation models. These predict unknown data by utilizing not only their own geosensor values at the same time, but also information from near past data. We use a window-based computation methodology that leverages the power of temporal correlation in a spatial modeling phase. This is done by also fitting the computed interpolation model to data which may change over time. In an assessment, using various geophysical data sets, we show that the presented algorithm is often able to deal with both spatial and temporal correlations. This helps to gain accuracy during the interpolation phase, compared to spatial and spatiotemporal competitors. Specifically, we evaluate the efficacy of the interpolation phase by using established machine-learning metrics (i.e. root mean squared error, Akaike information criterion and computation time).     

New insights into Late Pleistocene glacial and postglacial history of northernmost Ungava (Canada) from Pingualuit Crater Lake sediments

The Pingualuit Crater was formed by a meteoritic impact ca. 1.4 million years ago in northernmost Ungava (Canada). Due to its geographical position near the center of successive North American ice sheets and its favorable morphometry, the Pingualuit Crater Lake (water depth = 246 m) promises to yield a unique continuous sedimentary sequence covering several glacial/interglacial cycles in the terrestrial Canadian Arctic. In this paper, we suggest the existence of a subglacial lake at least during the Last Glacial Maximum (LGM) by hydraulic potential modeling using LGM ice-surface elevation and bed topography derived from a digital elevation model. These results support the hypothesis that the bottom sediments of the Crater Lake escaped glacial erosion and may contain a long-term continental sedimentary sequence. We also present the stratigraphy of a 9 m-long core retrieved from the deep basin of the lake as well as a multiproxy reconstruction of its deglacial and postglacial history. The base of the core is formed by very dense diamicton reflecting basal melt-out environments marking the end of subglacial conditions at the coring site. The overlying finely laminated silt are related to the onset of proglacial conditions characterized by extremely low lacustrine productivity. Infra Red Stimulated Luminescence and AMS ¹⁴C dating, as well as biostratigraphic data indicate sediment mixing between recent (e.g. Holocene) and much older (pre- to mid-Wisconsinan) material reworked by glacier activity. This process prevents the precise dating of these sediments that we interpret as being deposited just before the final deglaciation of the lake. Two finer grained and organic-rich intervals reflect the inception of lacustrine productivity resulting from the cessation of glacial meltwater inputs and ice-free periods. The lower organic interval corresponds to the early postglacial period (6850–5750 cal BP) and marks the transition between proglacial and postglacial conditions during the Holocene Thermal Maximum, while the uppermost organic-rich core section represents late Holocene sediments (～4200–600 cal BP). The organic intervals are separated by a basin-scale erosive slide occurring around 4200 cal BP and likely related to 1) a seismic event due to the glacio-isostatic rebound following the last deglaciation or 2) slope instabilities associated with rapid discharge events of the lake.     

No significant ice-sheet expansion beyond present ice margins during the past 4500 yr at Rauer Group, East Antarctica

The history of glacial advances and retreats of the East Antarctic ice sheet during the Holocene is not well-known, due to limited field evidence in both the marine and terrestrial realm. A 257-cm-long sediment core was recovered from a marine inlet in the Rauer Group, East Antarctica, 1.8 km in front of the present ice-sheet margin. Radiocarbon dating and lithological characteristics reveal that the core comprises a complete marine record since 4500 yr. A significant ice-sheet expansion beyond present ice margins therefore did not occur during this period.     

Contrasting punctuated zircon growth in two syn-erupted rhyolite magmas from Tarawera volcano: Insights to crystal diversity in magmatic systems

Two mineralogically and chemically distinct rhyolite magmas (T1 and T3) were syn-erupted from the same conduit system during the 21.9 ka basalt intrusion-triggered Okareka eruption from Tarawera volcano, New Zealand. High spatial resolution U–Th disequilibrium dating of zircon crystals at the ~ 3–5 μm scale reveals a protracted yet discontinuous zircon crystallization history within the magmatic system. Both magma types contain zircon whose interiors predate the eruption by up to 200 ka. The dominant age peak in the T1 magma is ~ 30 ka with subordinate peaks at ~ 45, ~ 75, and ~ 100 ka, whereas the T3 magma has a dominant zircon interior age peak at ~ 90 ka with smaller modes at ~ 35 and ~ 150 ka. These patterns are consistent with isolated pockets of crystallization throughout the evolution of the system. Crystal rim analyses yield ages ranging from within error of the eruption age to at least ~ 90 ka prior to eruption, highlighting that zircon crystallization frequently stalled long before the eruption. Continuous depth profiling from crystal rims inward demonstrates protracted growth histories for individual crystals (up to ~ 100 ka) that were punctuated by asynchronous hiatuses of up to 30 ka in duration. Disparate zircon growth histories can result from localized thermal perturbations caused by mafic intrusions into a silicic reservoir. The crystal age heterogeneity at hand-sample scale requires considerable crystal transport and mixing. We propose that crystal mixing was achieved through buoyancy instabilities caused by mafic magma flow through crystal mush. A terminal pre-eruptive rejuvenation event was capable of mobilizing voluminous melts that erupted, but was too short (< 10²–10³ years) to result in extensive zircon growth. The contrasting, punctuated zircon histories argue against closed-system fractional crystallization models for silicic magmatism that require protracted cooling times following a mostly liquid starting condition.