Elemental characteristics of lacustrine oil shale and its controlling factors of palaeo-sedimentary environment on oil yield: a case from Chang 7 oil layer of Triassic Yanchang Formation in southern Ordos Basin

As an important unconventional resource, oil shale has received widespread attention. The oil shale of the Chang 7 oil layer from Triassic Yanchang Formation in Ordos Basin represents the typical lacustrine oil shale in China. Based on analyzing trace elements and oil yield from boreholes samples, characteristics and paleo-sedimentary environments of oil shale and relationship between paleo-sedimentary environment and oil yield were studied. With favorable quality, oil yield of oil shale varies from 1.4% to 9.1%. Geochemical data indicate that the paleo-redox condition of oil shale’s reducing condition from analyses of V/Cr, V/(V + Ni), U/Th, δU, and authigenic uranium. Equivalent Boron, Sp, and Sr/Ba illustrate that paleosalinity of oil shale is dominated by fresh water. The paleoclimate of oil shale is warm and humid by calculating the chemical index of alteration and Sr/Cu. Fe/Ti and (Fe + Mn)/Ti all explain that there were hot water activities during the sedimentary period of oil shale. In terms of Zr/Rb, paleohydrodynamics of oil shale is weak. By means of Co abundance and U/Th, paleo-water-depth of oil shale is from 17.30 to 157.26 m, reflecting sedimentary environment which is mainly in semi deep–deep lake facies. Correlation analyses between oil yield and six paleoenvironmental factors show that the oil yield of oil shale is mainly controlled by paleo-redox conditions, paleoclimate, hot water activities, and depth of water. Paleosalinity and paleohydrodynamics have an inconspicuous influence on oil yield.     

Timing of mineralization at the Shihu gold deposit in the middle segment of the Taihang Mountain,China

The Shihu gold deposit, located in the middle-south section of the core of the Fuping mantle branch structure, is hosted in the Archean Fuping Group and adjacent to the quartz diorite porphyrite. The gold deposit is the only large gold deposit with reserves of more than 30 tons gold discovered in western Hebei Province so far. In order to constrain the timing of mineralization of this ore deposit, this paper focuses on the isotopic dating of zircon and pyrite. Zircons in gold-bearing quartz veins are magmatic in origin and no hydrothermal zircon has been found in such quartz veins, indicating that zircons were derived from the wall rocks. U–Pb ages of zircons fall mainly in the two domains: 2492 ± 82 and 136 ± 4 Ma, respectively, indicative of the contribution of the Fuping-Group TTG gneiss and Yanshanian igneous rocks, respectively. The Re–Os isotopic compositions of pyrites in the gold-bearing quartz veins yield an isochron age of 127 ± 31 Ma. Combined with other dating results, we suggest that the main metallogenic age of the Shihu gold deposit is 120–127 Ma.     

阿尔金中段大通沟花岗岩体年代学、地球化学特征及其成因

出露于阿尔金中段的大通沟花岗岩体,岩性主要为二长花岗岩,LA-ICP-MS锆石U-Pb年龄为(353.7±1.1)Ma。SiO_2为74.5%~76.2%,Al_2O_3为12.62%~14.15%,(Na_2O+K_2O)为7.71%~8.29%,K_2O/Na_2O为0.9~1.22,A/CNK介于1.0~1.19之间,属高钾钙碱性系列的过铝质-强过铝质花岗岩。该岩石富集大离子亲石元素(LILE),亏损素Ba、Nb、Sr、P、Ti等高场强元素(HFSE);∑REE变化范围大(∑REE=85.7×10~(-6)~153.2×10~(-6),平均为111×10~(-6)),具有强烈的负Eu异常(δEu=0.03~0.59,平均0.33),LREE/HREE=3.52~11.9,轻稀土相对富集,轻重稀土分馏明显。微量元素地球化学特征表明,其源区物质主要来源于上地壳的变杂砂岩和变泥质岩类。锆石饱和温度计演算结果显示锆石的结晶温度为722~745℃(平均735℃),估算二长花岗岩源区的压力为0.8~1.6GPa。综合区域地质资料,阿尔金中段大通沟花岗岩体的形成与造山带根部块体的拆沉作用有关。     

川南地区海相页岩气中发现微量硫化氢

正1研究目的(Objective)自2011年在四川南部地区下古生界海相地层中获得页岩气工业性突破以来,在四川盆地进行的海相页岩气开发得到多方的重视和迅速发展,随之而来的是人们对页岩气勘探开发过程中对环境影响的关注。页岩气,它以吸附或游离状态为主要方式赋存于富有机质泥页岩及其夹层中,是一种非常规天然气。与常规天然气相比,页岩气气质优良,甲烷含量更高。页岩气化学成分主要为甲烷(CH4),一般含量在85%以上,最高达到99.8%,另外还含有少量的乙烷(C2H6)、丙烷(C3H8)和丁烷(C4H10)。一般认为我国页岩气中可以存在少量氮     

Flooding a landscape: impact of Holocene transgression on coastal sedimentology and underwater archaeology in Kiladha Bay (Greece)

Franchthi Cave, bordering Kiladha Bay, in Greece, is a key archaeological site, due to its long occupation time, from?~?40,000 to?~?5000 year BP. To date, no clear evidence of Neolithic human dwellings in the cave was found, supporting the assumption that Neolithic people may have built a village where there is now Kiladha Bay. During the Neolithic period/Early Holocene, wide areas of the bay were indeed emerged above sea level. Bathymetric and seismic data identified a terrace incised by a valley in?~?1 to 2 m sediment depth. Eight sediment cores, up to 6.3-m-long, were retrieved and analysed using petrophysical, sedimentological, geochemical, and chronostratigraphic methods. The longest core extends into the exposure surface, consisting of a layer of carbonate rubble in a finer matrix, representing weathering processes. Dated organic remains place this unit at?~?8500 cal year BP. It is overlain by stiff silty mud representing an estuarine environment. This mud is capped by reduced sediments with roots marking an exposure surface. A shell-layer, dated to?~?6300 cal year BP, overlies this terrestrial sequence, reflecting the marine transgression. This layer occurs at 10.8 mbsl, 7.7 m deeper than the global sea level at that time, suggesting tectonic subsidence in the area. It is overlain by finer-grained marine carbonate-rich sediments. The top of the core shows traces of eutrophication, pebbles and marine shells, all likely a result of modern anthropogenic processes. These results are interpreted in the context of human occupation: the exposed surface contains pottery sherds, one dating to the Early to Middle Neolithic period, indicating that Neolithic people were present in this dynamic landscape interacting with a migrating coastline. Even if the artefacts are isolated, future investigations of the submerged landscape off Franchthi Cave might lead to the discovery of a Neolithic village, which eventually became buried under marine sediments.     

新疆哈密地区早泥盆世珊瑚动物群及其地质意义

新疆哈密地区下泥盆统发育,南部图拉尔根地区下泥盆统为大南湖组,北部三道白杨沟地区为卓木巴斯套组。在大南湖组中共发现四射珊瑚2属5种,床板珊瑚7属12种,并建立四射珊瑚组合Syringaxon moriense和床板珊瑚组合Pseudofavosites giganteus;在卓木巴斯套组共发现四射珊瑚5属7种,床板珊瑚2属2种,并建立四射珊瑚组合Orthopaterophyllum junggarense和床板珊瑚组合Pachyfavosites junggarensis。通过珊瑚在地层中的分布及组合的时代对比,确定前者的时代为早泥盆世埃姆斯期早期,后者的时代为埃姆斯期中晚期。通过与国内外典型的早泥盆世埃姆斯期珊瑚动物群的对比,认为哈密地区的珊瑚动物具有典型的早泥盆世温带动物群特征,在生物古地理区系上属于北方大区准噶尔-兴安省。     

The Fragmentation in a Protoplanetary Disk and the Properties of the Resultant Self-Gravitating Clumps

We study the fragmentation properties in the protoplanetary disk and properties of the resultant self-gravitating clumps using our newly constructed disk model. Our disk model includes the mass inflall term from a molecular cloud core and the photoevaporation winds effect. We adopt the conventional fragmentation criterion to judge whether a protoplanetary disk can fragment. In this work, we follow our previous work to investigate the properties of the resultant self-gravitating clumps. In our calculation, the initial masses of the resultant self-gravitating clumps lie in the range of tens of M_J to more than one hundred of M_J, where M_J is the Jupiter mass. These initial masses can seemingly account for the masses of extrasolar planets in magnitude. We also calculate the subsequent gas accretion of clumps in 1.27 × 10⁴ yr after the formation of self-gravitating clumps. We find that the subsequent gas accretion of self-gravitating clumps is very efficient, and the clump masses grow to hundreds of M_J and the physical radii R_c of clumps increase to about 10 AU. Additionally, we also calculate the orbital migration of clumps. We find that most clumps have short migration timescale to be accreted onto the protostar, and only a small fraction of clumps have long migration timescale (>10⁶ yr) to successfully become gas giant planets. These results are consistent with previous studies.     

Adjoint analysis of Buckley-Leverett and two-phase flow equations

This paper analyzes the adjoint equations and boundary conditions for porous media flow models, specifically the Buckley-Leverett equation, and the compressible two-phase flow equations in mass conservation form. An adjoint analysis of a general scalar hyperbolic conservation law whose primal solutions include a shock jump is initially presented, and the results are later specialized to the Buckley-Leverett equation. The non-convexity of the Buckley-Leverett flux function results in adjoint characteristics that are parallel to the shock front upstream of the shock and emerge from the shock front downstream of the shock. Thus, in contrast to the behavior of Burgers’ equation where the adjoint is continuous at a shock, the Buckley-Leverett adjoint, in general, contains a discontinuous jump across the shock. Discrete adjoint solutions from space-time discontinuous Galerkin finite element approximations of the Buckley-Leverett equation are shown to be consistent with the derived closed-form analytical solutions. Furthermore, a general result relating the adjoint equations for different (though equivalent) primal equations is used to relate the two-phase flow adjoints to the Buckley-Leverett adjoint. Adjoint solutions from space-time discontinuous Galerkin finite element approximations of the two-phase flow equations are observed to obey this relationship.