A field evaluation of enhanced reductive dechlorination of chlorinated solvents in groundwater,New York Metropolitan Area

An initial assessment of an old manufacturing site with groundwater impacted by trichloroethene (TCE) contamination in the metropolitan New York area showed that the TCE was being removed naturally by reductive dechlorination. However, complete dechlorination was not expected at the site because the process was progressing too slowly under transitional to aerobic conditions at a degradation constant of –0.0013 and a TCE half life of 533 days. A pilot test was conducted at the site in which a carbohydrate substrate (molasses) was injected into the groundwater to create an In-Situ Reactive Zone (IRZ). Post-pilot test groundwater sampling and analysis indicated that an IRZ was created successfully as the total organic carbon (TOC) content and conductivity increased significantly while oxidation-reduction (REDOX) potential and dissolved oxygen (DO) decreased. The created IRZ caused enhanced reductive dechlorination of TCE at the site, found to proceed with a degradation constant of –0.0158 and a TCE half life of 44 days.     

测井技术在灰岩地区隧道深孔勘探中的应用

鄂西地区完整灰岩地层的视电阻率、密度、声波、自然伽马等曲线形态受灰岩胶结物质成份和泥质含量影响并具有一定的规律性，当灰岩地层受到构造、溶蚀作用产生破碎带、岩溶、裂隙等不良地质体或存在地下含水体时，各测井物理参数发生变化并在曲线形态上呈现异常反映，据此可以对不良地质体的位置、规模、类型进行准确判断。测井技术在鄂西地区灰岩地区隧道深孔勘探中的应用，补充、验证了钻探资料，为隧道设计、施工提供了可靠的依据。     

橄榄岩与榴辉岩中的一种金属合金

对江苏东海橄榄岩与榴辉岩中部分矿物的初步测试分析 ,发现其中存在一种金属矿物。其矿物结构与镍纹石近似。推测该矿物为具地幔特征的铁镁质残留物。     

湖北宜昌石板溪金矿区断层空间结构及其控矿规律研究

断层空间结构包括变形结构和几何结构两部分。本文在解析石板溪金矿区主要断层变形结构和几何结构的基础上，探讨了其空间结构模式和控矿规律。     

多频测深初探

在频率域测深的基础上,提出了多频测深方法,实现一机多频同时观测的目的,以提高观测速度。本文讨论了多频观测方法的理论依据及工作特点,并提示实现这种观测的方案。     

An experimental study of effect of pre‐existing fabric on deformation of foliated mylonite at high temperature and pressure

We performed deformation experiments on a foliated mylonite under high temperature and pressure conditions in this study. To investigate the effect of pre‐existing fabric on the rheology of rocks, our samples were drilled from natural mylonite with the cylinder axis parallel to the foliation (PAR) and perpendicular to the foliation (PER). We performed 25 tests on seven PAR samples and 21 tests on seven PER samples at temperatures ranging from 600 to 890 °C, confining pressures ranging from 800 to 1400 MPa, and steady‐state strain rates of 1 × 10⁻⁴, 1 × 10⁻⁵ and 2.5 × 10⁻⁶ s⁻¹. In the temperatures of 600–700 °C, the deformation is accommodated by semi‐brittle flow, with the average stress exponent being 6–7 assuming power law flow; in the temperature range of 800–890 °C, deformation is mainly by plastic flow, with an average stress exponent of n = 3 and activation energies of Q = 354 ± 52 kJ/mol (PER and PAR samples). The experimental results show that the strengths of PER samples are higher than those of PAR samples. Deformation microstructures have been studied by optical and electron microscopy. The original foliation of PER samples is destroyed by deformation and replaced by a new foliation, but the deformation of PAR samples followed the original foliation. Electron backscatter diffraction (EBSD) measurements show a strong lattice preferred orientation (LPO) of the quartz c axis fabrics of the starting samples and deformed PER and PAR samples. However, the c axis fabric of quartz in experimentally deformed PER and PAR samples varied with temperature and strain rate is different from that seen in the starting mylonite sample. The initial quartz c axis fabric of the starting mylonite sample has been transformed into a new fabric during experimental deformation. Dehydration melting of biotite and hornblende occurred in both PER and PAR samples at temperatures of 800–890 °C. Copyright © 2014 John Wiley & Sons, Ltd.     

柴达木盆地东北缘中中新世以来古气候变化

全球变冷、青藏高原隆升以及特提斯洋海退被认为是控制亚洲大陆新生代气候变化的三大因素,然而由于长时间尺度古气候记录的匮乏,对于三者影响的认识并不清晰。柴达木盆地是青藏高原北部最大的一个封闭盆地,发育巨厚且连续的新生代地层,详细记录了周缘山体构造隆升过程和区域气候演化历史。本文通过柴达木盆地东北缘怀头他拉剖面的中中新世-早更新世沉积物气候代用指标碳酸盐、硫酸根和氯离子含量分析,显示该研究区中中新世以来气候变化经历了15.3~13.0Ma相对湿润、13.0~6.6Ma半干旱-半湿润和6.6~1.8Ma干旱的3个演化阶段。结合生物特征和前人研究成果,认为柴达木盆地干旱化历史可能从中中新世13Ma左右开始逐步发展,而真正意义上的干旱化始于6.6Ma以来。全球变冷是控制柴达木盆地干旱气候形成和发展的主导因素,同时青藏高原晚期持续阶段性的强烈隆升起到了催化剂的作用。     

不同模式模拟的降水稳定同位素效应的比较和评估

利用引入水稳定同位素循环的ECHAM4、GISS E、HadCM3、MUGCM以及iAWBM的模拟数据,分析了全球降水中稳定同位素效应的空间分布特征,对不同模式的模拟结果之间以及模拟结果与GNIP（Global Network of Isotopes in Precipitation）的实际监测结果之间进行了比较,旨在对稳定同位素大气环流模式的模拟有效性进行评价,改善对水循环中水稳定同位素效应的理解和认识。结果显示,5个模式均很好地再现了全球降水中平均δ18O和平均δ18O季节差的空间分布特征,降水中稳定同位素的温度效应、降水量效应的分布特点以及全球大气水线GMWL（Global Meteoric Water Line）均被很好地模拟出。比较而言,ECHAM4模拟的降水中的平均δ18O以及δ18O平均季节差的空间分布与GNIP的实际分布最接近,拟合水平也最高;ECHAM4、GISS E、MUGCM和iAWBM再现全球温度效应空间分布的能力较强,拟合水平大致相当;由iAWBM模拟的降水量效应空间分布与实际分布之间的相关性最强,5个模式模拟的与实测的δ18O/P相关系数符号相同的站点数大致位于同一水平;GISS E和iAWBM模拟的全球大气水线与实测的GMWL最接近。     

The Taihua group on the southern margin of the North China craton: further insights from U–Pb ages and Hf isotope compositions of zircons

The "Taihua Group" is a collective term for a series of old terranes scattered along the southern margin of the North China Craton. The timing of formation and thermal overprinting of the Taihua Group have long been contentious, and its relationship with the Qinling orogenic belt has been unclear. In this study, new data from integrated in-situ U–Pb dating and Hf isotope analysis of zircons from an amphibolite (from the Xiong’ershan terrane) and a biotite gneiss (from the Lantian-Xiaoqinling terrane) indicate that the Upper Taihua Group formed during the Paleoproterozoic (2.3–2.5 Ga) and thus was originally part of the southern edge of North China Craton, detached during the Mesozoic Qinling orogeny and displaced about 100 km north from its original location. This suggests that the Taihua Group became part of the tectonic terrane associated with the Qinling orogeny and now forms part of the overthrust basement section of the Qinling belt. Before the Qinling orogeny, the Taihua Group was metamorphosed at 2.1 Ga. The initial Hf-isotope compositions of zircons, together with positive εNd(t) values for the whole-rocks, imply that the original magmas were derived from a juvenile source with some assimilation of an Archean crustal component.     

水准网中起算点的选用方法探讨

水准网平差中起算点质量好坏不仅影响平差精度,而且如果采用不好的点位,直接影响成果的使用,带来严重后果。该文以青州市水准网的布设为例,分析讨论了起算点对水准网精度的影响,提出了根据较差中误差大小选用起算点的方法,阐述了该方法的步骤,达到的效果,以及水准网布设方法等。