Contaminant exposures at the 4H shell mounds in the Santa Barbara Channel

Remobilization, bioavailability, and potential toxicity of chemical contaminants were evaluated at the 4H shell mounds – the site of abandoned offshore oil and gas production platforms in the Santa Barbara Channel region of the Southern California Bight. Evaluations used a weight-of-evidence approach based on results from bulk phase chemical analyses and laboratory toxicity testing of shell mound cores, in situ field bioassays using caged mussels, and surficial sediment chemistry. Shell mound cores contained elevated concentrations of metals associated with drilling wastes (e.g., Ba, Cr, Pb, and Zn), as well as monocyclic and polycyclic aromatic hydrocarbons (PAHs). The highest concentrations along with pockets of free oil were associated with the middle “cuttings” stratum. Sediments composited from all core strata caused significant acute toxicity and bioaccumulation of Ba and PAHs in test organisms during laboratory exposures. In contrast, caged mussels placed at each of the shell mounds for a period of 57–58 days had greater than 90% survival, and there were no significant differences in survival of mussels placed at the shell mounds and corresponding reference sites. While all mussel samples exhibited increases in shell length, whole animal weight, and tissue lipid content, in some cases growth metrics for the shell mound mussels were significantly higher than those for the reference sites. Concentrations of metals, PAHs, and polychlorinated biphenyls (PCBs) in tissues of the shell mound mussels were not significantly different from those at reference sites. The presence of labile aromatic hydrocarbons in shell mound cores and absence of significant contaminant accumulation of tissues of caged mussels indicated that chemical contaminants are not being remobilized from the 4H shell mounds. Surficial bottom sediments near the shell mounds contained elevated Ba concentrations that probably were associated with drilling wastes. However, concentrations did not exhibit clear spatial gradients with distance from the shell mounds. Despite a number of storm events during the mussel exposures, maximum currents were 34 cm s⁻¹ and unlikely to erode materials from the shell mounds. Thus, Ba distributions in bottom sediments probably were due to episodic disturbance such as platform removal or trawling rather than ongoing erosion and dispersion of shell mound solids by near-bottom currents. These results suggest that, in the absence of physical disturbances, contaminants are expected to remain sequestered in the shell mounds.     

Influence of irrigated agriculture on diurnal surface energy and water fluxes, surface climate, and atmospheric circulation in California

The impact of land use change on regional climate can be substantial but also is variable in space and time. Past observational and modeling work suggests that in a ‘Mediterranean’ climate such as in California’s Central Valley, the impact of irrigated agriculture can be large in the dry season but negligible in the wet season due to seasonal variation in surface energy partitioning. Here we report further analysis of regional climate model simulations showing that diurnal variation in the impact of irrigated agriculture on climate similarly reflects variation in surface energy partitioning, as well as smaller changes in net radiation. With conversion of natural vegetation to irrigated agriculture, statistically significant decreases of 4–8?K at 2?m occurred at midday June–September, and small decreases of ~1?K occurred in winter months only in relatively dry years. This corresponded to reduced sensible heat flux of 100–350?W?m^?2 and increased latent heat fluxes of 200–450?W?m^?2 at the same times and in the same months. We also observed decreases of up to 1,500?m in boundary layer height at midday in summer months, and marginally significant reductions in surface zonal wind speed in July and August at 19:00 PST. The large decrease in daytime temperature due to shifts in energy partitioning overwhelmed any temperature increase related to the reduced zonal sea breeze. Such changes in climate and atmospheric dynamics from conversion to (or away from) irrigated agriculture could have important implications for regional air quality in California’s Central Valley.     

Can ensembles of regional climate model simulations improve results from sensitivity studies?

Intrinsic variability (IV) in regional climate models (RCMs) is often assumed to be small because at climatological timescales, the model solutions tend to be dominated by the model??s lateral boundary conditions. Recent studies have indicated that this IV may actually be large in certain instances for some variables. Direct interpretation of anomalies from RCM sensitivity studies relies on the assumption that differences between model simulations are entirely due to a physical forcing. However, if IV is as large or larger than the physical signal, then this assumption is violated. Using a 20 member ensemble of RCM simulations, we verify that IV of precipitation within a RCM can be large enough to violate the sensitivity study assumption, and we show that generating ensembles of simulations can help reduce the level of IV. We also present two indicators that can rule out the influence of IV when it is ambiguous whether anomalies within a sensitivity study are due to the sensitivity perturbation or whether they are due to IV.     

A review of the feasibility, costs, and benefits of platform-based open ocean aquaculture in the Gulf of Mexico

Platform-based open ocean aquaculture (or mariculture) is a fledgling industry with a unique set of risks and uncertainties. In the past two decades, several commercial and experimental platform-based mariculture projects have been launched in the United States, however, all these projects failed or were abandoned because of operational problems or legal issues. The oil and gas infrastructure in the Gulf of Mexico is well suited for mariculture systems as these platforms are large, sturdy and long lasting, and designed to operate in the offshore environment. The purpose of this paper is to discuss the costs and benefits of a open ocean aquaculture industry in the Gulf of Mexico with particular focus on platform-based aquaculture. The opportunities for the use of idle oil and gas structures for open ocean aquaculture are limited, but the reuse of previously removed structures may have more promise.     

Propagation and source of Pc5 frequency range pulsation at cusp latitude

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Argon‐40‐argon‐39 chronology and petrogenesis along the eastern limb of the Moon from Luna 16, 20 and 24 samples

Abstract— Eighteen new lithic fragments from the Soviet Luna missions have been analyzed with electron microprobe and ⁴⁰Ar‐³⁹Ar methods. Luna 16 basalt fragments have aluminous compositions consistent with previous analyses, but have two distinct sets of well‐constrained ages (3347 ± 24 Ma, 3421 ± 30 Ma). These data, combined with other Luna 16 basalt ages, imply that there were multiple volcanic events filling Mare Fecunditatis. The returned basalt fragments have relatively old cosmicray exposure (CRE) ages and may have been recovered from the ejecta blanket of a young (1 Ga), nearby crater. A suite of highlands rocks (troctolites and gabbros) is represented in the new Luna 20 fragments. One fragment is the most compositionally primitive (Mg# = 91–92) spinel troctolite yet found. Both troctolites have apparent crystallization ages of 4.19 Ga; other rocks in the suite have progressively younger ages and lower Mg#s. The age and composition progression suggests that these rocks may have crystallized from a single source magma, or from similar sources mobilized at the same time. Within the new Luna 24 basalt fragments is a quench‐textured olivine vitrophyre with the most primitive composition yet analyzed for a Luna 24 basalt, and several much more evolved olivine‐bearing basalts. Both new and previously studied Luna 24 very low‐Ti (VLT) basalt fragments have a unimodal age distribution (3273 ± 83 Ma), indicating that most returned samples come from a single extrusive episode within Mare Crisium much later than the Apollo 17 VLT basalts (3.6–3.7 Ga).     

Coupled atmosphere–ocean data assimilation experiments with a low-order model and CMIP5 model data

Climate Dynamics - Coupled atmosphere–ocean data assimilation (DA) experiments are performed for estimating the Atlantic meridional overturning circulation (AMOC). Recovery of the AMOC with...     

Recommendations for the processing and storage of water samples before polymerase chain reaction (PCR) analysis

A range of options for the storage and partial processing of water samples before polymerase chain reaction (PCR) analysis were evaluated. In addition, temporal storage of extracted DNA at 4 °C was investigated. Filtering the water sample and then storing that filter at ?20 °C for up to six months before DNA extraction was equivalent to extracting DNA immediately. Freezing a water sample resulted in an immediate 1 log loss of PCR signal, although thereafter the sample was stable for at least three months. A rapid loss of detectable PCR product was found when storing a water sample at 4 °C for longer than one week. Extracted DNA could be stored at 4 °C for at least six months without considerable loss of PCR signal.