Fate of dissolved aluminum in the oceans

Vertical profiles of dissolved Al in the Atlantic Ocean and Mediterranean Sea are presented. Although dissolved Al appears to be involved in the biochemical cycle of elements, Al does not behave solely as a nutrient within the oceans. Physico-chemical processes (i.e. adsorption and/or chemical precipitation) control the concentration and distribution of Al_aq within the deep waters.A tentative mass balance model of Al_aq in the oceanic system is proposed that takes into account all of the presently known fluxes of Al_aq to and through the oceans. To maintain the deep waters of the ocean at steady state, it is necessary to include in the model, processes that remove Al_aq from these waters. Thus, model calculations support the conclusions drawn from observations that physico-chemical processes remove Al_aq from deep waters. Finally, the proposed model is compatible with the concept that the entire oceanic system is at steady state with respect to dissolved Al.     

Vertical distribution of trace elements in the surface waters offshore Nova Scotia

Concentrations of the trace elements Fe, Al, Mn, Cu, Cd, Zn and Ni were measured in shallow vertical profiles (maximum depth 500 m) off the Scotian Shelf in the western North Atlantic. The distributions of the trace elements show variations with depth, the most consistent of which are for Fe and Zn. A minimum concentration near the surface followed by an increase with depth is attributed to in situ mechanisms.     

A Hybrid Spectral/Finite-Volume Algorithm for Large-Eddy Simulation of Scalars in the Atmospheric Boundary Layer

Pseudospectral methods are frequently used in the horizontal directions in large-eddy simulation of atmospheric flows. However, the same approach often creates unphysical oscillations for scalar fields if there are horizontal heterogeneities in the sources and/or sinks, as is usual in air pollution problems. A hybrid approach is developed to combine the use of pseudospectral representation of the velocity field and bounded finite-volumes for the scalar concentration. An interpolation scheme that yields a divergence-free interpolated velocity field is derived and implemented, and its importance is illustrated by two sample applications.     

The gravitational wave background from star–massive black hole fly-bys

Stars on eccentric orbits around a massive black hole (MBH) emit bursts of gravitational waves (GWs) at periapse. Such events may be directly resolvable in the Galactic Centre. However, if the star does not spiral in, the emitted GWs are not resolvable for extragalactic MBHs, but constitute a source of background noise. We estimate the power spectrum of this extreme mass ratio burst background (EMBB) and compare it to the anticipated instrumental noise of the Laser Interferometer Space Antenna (LISA). To this end, we model the regions close to an MBH, accounting for mass segregation, and for processes that limit the presence of stars close to the MBH, such as GW inspiral and hydrodynamical collisions between stars. We find that the EMBB is dominated by GW bursts from stellar mass black holes, and the magnitude of the noise spectrum  ( fS _GW)^1/2  is at least a factor of ∼10 smaller than the instrumental noise. As an additional result of our analysis, we show that LISA is unlikely to detect relativistic bursts in the Galactic Centre.     

Melting and Sublimation of Planetary Ices Under Low Pressure Conditions: Laboratory Experiments with a Melting Probe Prototype

One possibility to explore the subsurface layers of icy bodies is to use a probe with a “hot tip", which is able to penetrate ice layers by melting. Such probes have been built and used in the past for the exploration of terrestrial polar ice sheets and may also become useful tools to explore other icy layers in the Solar System. Examples for such layers are the polar areas of Mars or the icy crust of Jupiter’s moon Europa. However, while on Earth a heated probe launched into an ice sheet always causes melting with subsequent refreezing, the behaviour of such a probe in a low pressure environment is quite different. We report on the results of some experiments with a simple “melting probe" prototype with two different kinds of hot tips in a vacuum environment. For one of the tips the probe moved into two types of ice samples: (i) compact water ice and (ii) porous water ice with a snow (firn) like texture. It was also found that the penetration behaviour was basically different for the two sample types even when the same kind of tip was used. While in the porous sample the ice was only subliming, the phase changes occurring during the interaction of the tip with the compact ice are much more complex. Here alternating phases of melting and sublimation occur. The absence of the liquid phase has severe consequences on the performance of a “melting probe" under vacuum conditions: In this environment we find a high thermal resistance between the probe surface and the underlying ice. Therefore, only a low percentage of the heat that is generated in the tip is used to melt or sublime the ice, the bulk of the power is transferred towards the rear end of the probe. This is particularly a problem in the initial phases of an ice penetration experiment, when the probe has not yet penetrated the ice over its whole length. In the compact ice sample, phases could be observed, where a high enough gas pressure had built up locally underneath the probe, so that melting becomes possible. Only during these melting periods the thermal contact between the probe and the ice is good and in consequence the melting probe works effectively.     

Micro‐Raman spectroscopic study of fine‐grained,shock‐metamorphosed rock fragments from the Australasian microtektite layer

Abstract— –Shock‐metamorphosed rock fragments have been found in the Australasian microtektite layer from the South China Sea. Previous X‐ray diffraction (XRD) studies indicate that the most abundant crystalline phases in the rock fragments are coesite, quartz, and a 10 Å phase (mica/clay?). In addition, the presence of numerous other phases was suggested by scanning electron microscopy (SEM) and energy‐dispersive X‐ray (EDX) analysis. In the present research, ten of the rock fragments, which had previously been studied using SEM/EDX, were studied by micro‐Raman spectroscopy. The presence of K‐feldspar, plagioclase, rutile, ilmenite, titanite, magnetite, calcite, and dolomite were confirmed. In addition, the high‐pressure TiO₂ polymorph with an α‐PbO₂ structure (i.e., TiO₂II) was found in several rock fragments. Two grains previously thought to have been zircon, based on their compositions, were found to have Raman spectra that do not match the Raman spectra of zircon, reidite, or any of the possible decomposition products of zircon or their high‐pressure polymorphs. We speculate that the ZrSiO₄ phase might be a previously unknown high‐pressure polymorph of zircon or one of its decomposition products (i.e., ZrO₂ or SiO₂). The presence of coesite and TiO₂ II, and partial melting and vesiculation suggest that the rock fragments containing the unknown ZrSiO₄ phase must have experienced shock pressures between 45 and 60 GPa. We conclude that micro‐Raman spectroscopy, in combination with XRD and SEM/EDX, is a powerful tool for the study of small, fine‐grained impact ejecta.     

Geomasking sensitive health data and privacy protection: an evaluation using an E911 database

Geomasking is used to provide privacy protection for individual address information while maintaining spatial resolution for mapping purposes. Donut geomasking and other random perturbation geomasking algorithms rely on the assumption of a homogeneously distributed population to calculate displacement distances, leading to possible under-protection of individuals when this condition is not met. Using household data from 2007, we evaluated the performance of donut geomasking in Orange County, North Carolina. We calculated the estimated k-anonymity for every household based on the assumption of uniform household distribution. We then determined the actual k-anonymity by revealing household locations contained in the county E911 database. Census block groups in mixed-use areas with high population distribution heterogeneity were the most likely to have privacy protection below selected criteria. For heterogeneous populations, we suggest tripling the minimum displacement area in the donut to protect privacy with a less than 1% error rate.     

Comparison of environmental tracers including organic micropollutants as groundwater exfiltration indicators into a small river of a karstic catchment

Understanding groundwater–surface water (GW–SW) interactions is vital for water management in karstic catchments due to its impact on water quality. The objective of this study was to evaluate and compare the applicability of seven environmental tracers to quantify and localize groundwater exfiltration into a small, human-impacted karstic river system. Tracers were selected based on their emission source to the surface water either as (a) dissolved, predominantly geogenic compounds (radon-222, sulphate and electrical conductivity) or (b) anthropogenic compounds (predominantly) originating from wastewater treatment plant (WWTP) effluents (carbamazepine, tramadol, sodium, chloride). Two contrasting sampling approaches were compared (a) assuming steady-state flow conditions and (b) considering the travel time of the water parcels (Lagrangian sampling) through the catchment to account for diurnal changes in inflow from the WWTP. Spatial variability of the concentrations of all tracers indicated sections of preferential groundwater inflow. Lagrangian sampling techniques seem highly relevant for capturing dynamic concentration patterns of WWTP-derived compounds. Quantification of GW inflow with the finite element model FINIFLUX, based on observed in-stream Rn activities led to plausible fluxes along the investigated river reaches (0.265 m³ s⁻¹), while observations of other natural or anthropogenic environmental tracers produced less plausible water fluxes. Important point sources of groundwater exfiltration can be ascribed to locations where the river crosses geological fault lines. This indicates that commonly applied concepts describing groundwater–surface water interactions assuming diffuse flow in porous media are difficult to transfer to karstic river systems whereas concepts from fractured aquifers may be more applicable. In general, this study helps selecting the best suited hydrological tracer for GW exfiltration and leads to a better understanding of processes controlling groundwater inflow into karstic river systems.     

Innovative Techniques for Measuring the Oil Content of Oil-Contaminated Porous Media

The oil content of oil-contaminated porous media is an important parameter for the assessment and remediation of oil pollution in soil and groundwater. However, an accurate measurement method is not available. In this study, we propose a new equation to calculate the oil content of water-bearing media based on traditional extraction–ultraviolet spectroscopy. Further, an improved experimental method was developed. The results indicate that the pure solid weight and oil content of oil-contaminated media can be accurately determined by introducing the oil drying loss coefficient (γ). The average relative errors of the improved method range from −0.14% to −0.96%. They are much smaller than errors of −4.49% to −10.97% of the original methods, indicating that the accuracy of measured oil content is enhanced. In addition, the accuracy of the new method does not depend on oil volatility and oil content.