Serpentinization and infiltration metasomatism in the Trinity peridotite,Klamath province,northern California: implications for subduction zones

The Trinity peridotite was emplaced over metabasalts and metasedimentary rocks of the central metamorphic belt along the Devonian Trinity thrust zone. Three metamorphic events can be recognized in the Trinity peridotite: (1) antigorite (D= –63 to –65%.) formation related to regional underthrusting of the central metamorphic belt; (2) contact metamorphism associated with Mesozoic dioritic plutons; and (3) late-stage formation of lizardite ± brucite and chrysotile (D= –127 to –175%.) due to infiltration of meteoric waters. Abundant relict phases indicate incomplete reactions and strongly suggest that the availability of H₂O was a controlling factor during serpentinization.Antigorite (event 1) formed as a result of infiltration into the Trinity peridotite of mixed H₂O-CO₂ fluids derived from the underlying central metamorphic belt. Foliation defined by magnetite veins and shear zones within antigorite serpentinites are subparallel to the Trinity thrust. The assemblage Fo + Atg + Chl + Mag ± Tr ± Carb reflects partial hydration of peridotite at 425–570° C. Talc-rich serpentinite formed along the thrust as a result of the infiltration of silica-bearing fluids. Metasomatic mass-balance calculations based on silica solubilities and the extent of antigorite serpentinization suggest that 80–175 volumes of fluid have passed through a given volume of original peridotite at the Trinity thrust.The Trinity thrust probably represents a Devonian subduction zone. Thermodynamic calculations suggest that hydration reactions account for 30–35% of the total heat released by the cooling Trinity peridotite. By analogy, similar hydration reactions are to be expected in the overlying mantle wedge of a subduction zone which act to retard cooling of the hanging wall, just as dehydration reactions delay heating of the downgoing slab. Metasomatic zones formed in peridotite at the Trinity thrust may reflect similar metasomatic processes to those proposed to occur in the mantle wedge above a subducting slab.     

Man-induced gradient adjustment of the South Fork Forked Deer River,west Tennessee

Channel modifications from 1968 to 1969 on the South Fork Forked Deer River in western Tennessee have caused upstream degradation, downstream aggradation, and bank failures along the altered channels, adjacent reaches, and tributaries. The result of these adjustments is a general decrease in gradient as the channel attempts to absorb the imposed increase in energy conditions created by channelization. Headward degradation at a rate of approximately 2.57 km/yr on the South Fork Forked Deer River caused from 1.52 m to about 3.14 m of incision over a 13.5 km reach from 1969 to 1981. As a consequence of substantially increased sediment supply, approximately 2.13 m of aggradation was induced downstream of this reach during the same period. This accumulation represents a 60% recovery of bed level at the downstream site since the completion of channel work in 1969. Gradient adjustment with time is described by exponential decay functions. The length of time required for adjustment to some new quasi-equilibrium condition is computed by these decay functions and is about 20 years from the completion of channel work. Adjusted slopes are less than predisturbed values, probably because straightened channels dissipate less energy by friction, allowing more energy for sediment transport. An equivalent sediment load, therefore, can be transported at a considerably gentler slope. The predisturbed slope exceeds the adjusted slope by an order of magnitude on the downstream reach of the South Fork Forked Deer River.     

Pb isotopic composition,colour, and microstructure of monazites from a polymetamorphic rock in Antarctica

A moderate- to high-grade regionally metamorphosed paragneiss from Antarctica contains monazites of several different colours — brown, yellow and grey. Each colour type has a distinctive U-Pb isotopic composition which appears to result from different proportions of radiogenic Pb loss. Isotopic differences are neither related to La, Nd, Ce, P, Ca, Ti (and/or Ba), nor to U or Th content. All colour types have similar structures at the submicron scale, as determined by both conventional and high-resolution transmission electron microscopy (TEM). These show that the grains are essenttially non-metamict but are composed of 100 Å crystalline domains misoriented from each other by no more than 2× 10^–3 radians, and separated by narrow confused boundary regions where misorientation is probably accommodated by imperfect atomic arrangements. These regions of mismatch form potential zones of high permeability/diffusivity which are believed to be fundamental to the isotopic and colour differences between grains. Colour type is apparently related to the capacity of different minerals to shield included monazite grains from fluids circulating in the rock system.The well aligned monazite U — Pb analyses produce concordia intercepts of 2429 _–16 ⁺¹⁷ Ma and 1087±29 Ma. Both ages are comparable to those of major geological events in this part of Antarctica. They are interpreted in terms of isotopic resetting through Pb loss, and original monazite crystallisation is thought to have occurred somewhat earlier, possibly at the time this terrain first underwent granulite-facies metamorphism, about 3070 Ma ago.     

Ultraviolet absorption spectrum of trifluoro-bromo-methane,difluoro-dibromo-methane and difluoro-bromo-chloro-methane in the vapor phase

Ultraviolet absorption cross-sections of trifluoro-bromo-methane (CF₃Br-Halon 1301), difluoro-dibromo-methane (CF₂Br₂-Halon 1202) and of difluoro-bromo-chloro-methane (CF₂BrCl-Halon 1211) are measured in the wavelength interval 172–304 nm for temperatures ranging from 210 to 295 K with uncertainties of between 2 and 4%. They are compared with previous measurements available at room temperature. Temperature effects are discussed and parametrical formulae are proposed to compute the absorption cross-sections for wavelengths and temperatures useful in atmospheric modelling calculations. Photodissociation coefficients are presented and their temperature dependence is discussed.     

Fault-induced perturbed stress fields and associated tensile and compressive deformation at fault tips in the ice shell of Europa: implications for fault mechanics

Secondary fractures at the tips of strike-slip faults are common in the ice shell of Europa. Large magnitude perturbed stress fields must therefore be considered to be a viable driving mechanism for the development of part of the fracture sequence. Fault motions produce extensional and compressional quadrants around the fault tips. Theoretically, these quadrants can be associated with tensile and compressive deformational features (i.e. cracks and anti-cracks), respectively. Accordingly, we describe examples of both types of deformation at fault tips on Europa in the form of extensional tailcracks and compressional anti-cracks. The characteristics of these features with respect to the plane of the fault create a fingerprint for the mechanics of fault slip accumulation when compared with linear elastic fracture mechanics (LEFM) models of perturbed stress fields around fault tips. Tailcrack kink angles and curving geometry can be used to determine whether opening accompanies sliding motion. Kink angles in the 50–70° range are common along strike-slip faults that resemble ridges, and indicate that little to no opening accompanied sliding. In contrast, tailcrack kink angles are closer to 30° for strike-slip faults that resemble bands, with tailcrack curvatures opposite to ridge-like fault examples, indicating that these faults undergo significant dilation and infill during fault slip episodes. Anti-cracks, which may result from compression and volume reduction of porous near-surface ice, have geometries that further constrain fault motion history, corroborating the results of tailcrack analysis. The angular separation between anti-cracks and tailcracks are similar to LEFM predictions, indicating the absence of cohesive end-zones near the tips of Europan faults, hence suggesting homogeneous frictional properties along the fault length. Tailcrack analysis can be applied to the interpretation of cycloidal ridges: chains of arcuate cracks on Europa that are separated by sharp kinks called cusps. Cusp angles are reminiscent of tailcrack kink angles along ridge-like strike-slip faults. Cycloid growth in a temporally variable tidal stress field ultimately resolves shear stresses onto the near-tip region of a growing cycloid segment. Thus, resultant slip and associated tailcrack development may be the driving force behind the initiation of the succeeding arcuate segment, hence facilitating the ongoing propagation of the cycloid chain.     

Utility of Landsat 7 satellite data for continued monitoring of forest cover change in protected areas in Southeast Asia

Satellite instruments, particularly the Landsat TM (Thematic Mapper) and ETM+ (Enhanced Thematic Mapper Plus) series of sensors, are important tools in the interdisciplinary study of tropical forests that are increasingly integrated into studies that monitor changes in vegetation cover within tropical forests and tropical protected areas, and also applied with other types of data to investigate the drivers of land cover change. However, further advances in the use of Landsat to study and monitor tropical forests and protected areas are threatened by the scan line corrector failure on the ETM+ sensor, as well as uncertainty about the continuity of the Landsat mission. Given these problems, this paper illustrates how ETM+ data were used in an interdisciplinary study that effectively monitored forest cover change in Gunung Palung National Park in West Kalimantan, Indonesian Borneo. Following 31 May 2003, when the ETM+ sensor's scan line corrector failed, we analysed how this failure impedes our ability to perform a similar study from this date onwards. This analysis uses six simulated post-scan line corrector failure (SLC-off) images and reveals that data gaps caused by SLC-off introduce maximum errors of 1.47 per cent and 4.04 per cent in estimates of forest cover and rates of forest loss, respectively. The analysis also demonstrates how SLC-off has transformed ETM+ data from a complete inventory dataset to a statistical sample with variable sample fraction, and notes how this data loss will confound the use of Landsat data to model land cover change in a spatially explicit manner. We discuss potential limited uses of SLC-off data and suggest alternative sensors that may provide essential remotely sensed data for monitoring tropical forests in Southeast Asia.     

Determining hydraulic resistance in gravel‐bed rivers from the dynamics of their water surfaces

Traditionally, approaches to account for the effect of the boundary roughness of a gravel‐bed river have used a grain‐size index of the bed surface as a surrogate for hydraulic resistance. The use of a single grain‐size does not take into account the spatial heterogeneity in the bed surface and how this heterogeneity imparts resistance on the flow, nor the way in which this relationship changes with variables such as flow stage. A new technique to remotely quantify hydraulic resistance is proposed. It is based on measuring the dynamics of a river's water surface and relating this to the actual hydraulic resistance created by a rough sediment boundary. The water surface dynamics are measured using a new acoustic technique, grazing angle sound propagation (GRASP). This proposed method to measure hydraulic resistance is based on a greater degree of physical reasoning, and this is discussed in the letter. By measuring acoustically the temporal dynamics of turbulent water surfaces over a water‐worked gravel bed in a laboratory flume, a dependency is demonstrated between the temporal variation in the reflected acoustic pressure and measured hydraulic resistance. It is shown that the standard deviation in acoustic pressure decreases with increasing hydraulic resistance. This is shown to apply for a range of relative submergences and bed slopes that are typical of gravel‐bed rivers. This remote sensing technique is both rapid and inexpensive, and has the potential to be applied to natural river channels and to other environmental turbulent flows, such as overland flows. A whole new class of low‐cost, remote and non‐intrusive instruments could be developed as a result and used in a wide range of hydraulic and hydrological applications. Copyright © 2006 John Wiley & Sons, Ltd.     

Anharmonicity of inner-OH stretching modes in hydrous phyllosilicates: assessment from first-principles frozen-phonon calculations

The theoretical anharmonicity of the inner-OH stretching modes of kaolinite and lizardite is determined using a frozen-phonon approach. The anharmonicity parameter, defined as the difference between half the first overtone frequency and the frequency of the fundamental transition, is −95 and −92 cm⁻¹ for kaolinite and lizardite, respectively. These values are consistent with the experimental measurements. The very good agreement usually observed between harmonic calculations of vibrational frequencies at the density functional theory (DFT) level, using the generalized gradient approximation (GGA), and experimental positions of vibrational bands results from the fortuitous, but almost exact, cancelation of two types of errors. One is related to the GGA approximation and the other to the neglect of anharmonicity.