Stratigraphic and geochemical controls on naturally occurring arsenic in groundwater,eastern Wisconsin,USA

High arsenic concentrations (up to 12,000 7g/L) have been measured in groundwater from a confined sandstone aquifer in eastern Wisconsin. The main arsenic source is a sulfide-bearing secondary cement horizon (SCH) that has variable thickness, morphology, and arsenic concentrations. Arsenic occurs in pyrite and marcasite as well as in iron oxyhydroxides but not as a separate arsenopyrite phase. Nearly identical sulfur isotopic signatures in pyrite and dissolved sulfate and the correlation between dissolved sulfate, iron, and arsenic concentrations suggest that sulfide oxidation is the dominant process controlling arsenic release to groundwater. However, arsenic-bearing oxyhydroxides can potentially provide another arsenic source if reducing conditions develop or if they are transported as colloids in the aquifer. Analysis of well data indicates that the intersection of the SCH with static water levels measured in residential wells is strongly correlated with high concentrations of arsenic in groundwater. Field and laboratory data suggest that the most severe arsenic contamination is caused by localized borehole interactions of air, water, and sulfides. Although arsenic contamination is caused by oxidation of naturally occurring sulfides, it is influenced by water-level fluctuations caused by municipal well pumping or climate changes, which can shift geographic areas in which contamination occurs. Résumé De fortes concentrations en arsenic, jusqu'à 12000 7g/L, ont été mesurées dans l'eau souterraine d'un aquifère gréseux captif, dans l'est du Wisconsin. La principale source d'arsenic est un horizon à cimentation secondaire (SCH) comportant des sulfures, dont l'épaisseur, la morphologie et les concentrations en arsenic sont variables. L'arsenic est présent dans la pyrite et dans la marcassite, de même que dans des oxy-hydroxydes de fer, mais non pas dans une phase séparée d'arsénopyrite. Les signatures isotopiques du soufre presque identiques dans la pyrite et dans les sulfates dissous et la corrélation entre les concentrations en sulfates, en fer et en arsenic dissous laissent penser que l'oxydation des sulfures est le processus dominant contrôlant la libération de l'arsenic dans les eaux souterraines. Cependant, les oxy-hydroxydes contenant de l'arsenic sont susceptibles d'être une autre source d'arsenic si des conditions réductrices apparaissent ou s'ils sont transportés dans l'aquifère sous forme de colloïdes. L'analyse des données provenant de puits montre que l'intersection entre le SCH et les niveaux statiques des puits domestiques est fortement corrélée à de fortes concentrations en arsenic dans les eaux souterraines. Des données de terrain et de laboratoire conduisent à penser que la contamination en arsenic la plus forte est causée par l'interaction localisée aux forages entre l'air, l'eau et les sulfures. Bien que la contamination en arsenic soit causée par l'oxydation de sulfures présents naturellement, elle est influencée par les fluctuations du niveau piézométrique causées par les pompages du captage municipal ou par les variations climatiques, ce qui peut conduire au déplacement des zones géographiques où se produisent les contaminations. Resumen Se han medido concentraciones de arsénico muy altas (de hasta 12000 7g/L) en las aguas subterráneas de un acuífero confinado, en areniscas, localizado en la parte oriental de Wisconsin (EEUU). La fuente principal de arsénico es un horizonte de cementación secundaria (SCH) con un alto contenido en sulfuros, y con una gran variabilidad en espesor, morfología y concentraciones de As. El arsénico aparece en piritas y marcasitas, además de en oxihidróxidos de hierro, pero no como una fase independiente de arsenopiritas. El hecho que la marca isotópica de piritas y sulfatos disueltos sea muy similar, y que exista una gran correlación entre las concentraciones de sulfato disuelto, hierro y arsénico sugiere que la oxidación de sulfuros es el proceso que controla la aportación de arsénico al agua subterránea. Sin embargo, los oxihidróxidos con alto contenido en arsénico podrían suponer otra fuente de arsénico si se llegaran a desarrollar condiciones reductoras o si se transportaran como coloides por el acuífero. De los datos procedentes de pozos, se ve una fuerte correlación entre la presencia de altas concentraciones de As en el agua y que el nivel freático intersecte el SCH. Los datos de campo y de laboratorio indican que los puntos con mayor contaminación de arsénico son debidos a interacciones de carácter local y en los propios pozos entre aire, agua y sulfuros. Aunque la contaminación por As está causada por la oxidación de sulfuros presentes de manera natural, también está muy influenciada por las fluctuaciones en los niveles freáticos causadas por bombeos o cambios climáticos.     

The stress field in Australia from composite fault plane solutions of the strongest earthquakes in the continent

The purpose of this study is to make an estimate of the stress field in the Australian continent from composite fault plane solutions of the strongest events in the area. 21 seismic events with magnitude greater than 5.0 have been chosen from a database of 400 Australian earthquakes since 1902 for performing composite fault plane solutions. The choice is based on the availability of data for first P-wave arrivals. Using data from ISC bulletins we have calculated composite fault plane solutions for six major earthquake zones in the country. An individual fault plane solution for at least one event in each zone has been computed, too. The space distribution of the focal mechanisms confirms a dominant east-west compression stress in the continent, with different tilt in different areas. The main compression axes in the Tennant Creek area (Northern Australia) are with clear north-south direction. The general direction of the plate motion is north-northeast.     

How to Earn the Status of Honest Broker? Scientists’ Roles Facilitating the Political Water Supply Decision-Making Process

“Honest broker” refers to scientists facilitating complex political decisions from a neutral position, aiming to expand the scope of choice available instead of advocating a certain policy. This article reflects on the experiences of three scientists acting as honest brokers while carrying out a multicriteria evaluation to help politicians choose the water supply option for the city of Oulu, Finland. The process was considered successful and many politicians said that they have never before been that well informed when making a decision. The case primarily shows that besides the common knowledge brokerage roles targeting knowledge exchange, the honest brokerage approach relates more to managing social relationships and balancing political games and rapidly evolving discussions. Trustful relationships increased the perceived credibility of the brokers and ensured two-way communication. On the other hand, the brokers faced ethical dilemmas and difficulties of staying impartial while finding out confidential information related to political strategies.     

Constraints of archaeomagnetic dating and field intensity determinations in three ancient tile kilns in Belgium

The aim of this study is to date by the archaeomagnetic method the last heatingcooling cycle of one Roman and two Medieval tile kilns, discovered in Belgium. The investigation demonstrates the limitations when well-documented local directional secular variation curves of the geomagnetic field in the past are used for dating and the difficulties when trying to determine field intensities from “in situ” baked clays from the kilns. The three kilns yielded very well defined ancient field directions but two possible dating solutions for each of them when no a priori time constraints are taken into account, due to field direction recurrence. As an increase of the dating accuracy and reduction of the number of dating solutions can be expected using the full field vector information, also field intensity determinations on burnt clays from the kilns were attempted. Field intensities from samples of the Roman and of one of the Medieval kilns are quite scattered. On the other hand, results obtained applying the Thellier-Thellier method and the modified method developed by Dekkers and Böhnel on sister samples from the Roman kiln agree fairly well. Rock magnetic properties reveal high variance in the kilns that point to varying spatial heating and cooling conditions in the kilns. Even well burnt material from the kilns shows irreversible changes when heated in air in the laboratory. Reliable field intensities on “in situ” baked materials from kilns themselves can therefore only be obtained when measuring sufficient number of samples from different parts of the kiln, taking into account the spatial-temporal conditions during kiln operation and cooling history. More reference intensity data is needed in our regions in order to improve dating based on directional reference data only.     

A Compact High-Voltage Pulse Generator for Plasma Applications

The design and construction of a compact high-voltage pulse generator for providing input electron beam power for the LAP/INPE 32 GHz gyrotron and for treatment of metal and polymer materials by plasma immersion ion implantation (PIII) are described. The generator was built on a circuit category of Pulse Forming Network (PFN), consisting of nine LC sections with L = 270 H and C = 2.5 nF.The instrument was designed to produce a flat 30 kV, several Amps pulse in 15 s pulse length with pulse repetition frequency (PRF) of 8 to 100 Hz. By means of a resonant charging inductance it is possible to gain an output voltage with a factor of 1.8 higher than the voltage supplied by the pulse generator. The generator is fed with sine-wave, constant current source, and a 60 kV, 15 mA switching power supply.     

Western Palaearctic palaeoenvironmental conditions during the Early and early Middle Pleistocene inferred from large mammal communities,and implications for hominin dispersal in Europe

Large-scale fluctuations in global climate and resulting changes in ecology had a profound effect on human evolution and dispersal. Though hominin remains are scarce, studies focussing on the more abundant records of fossil land mammal communities can contribute greatly to our knowledge of the palaeoenvironmental circumstances that influenced and directed the global spread of hominins. To produce a comprehensive and accurate account of the evolution of western Palaearctic habitat diversity between 2.6 and 0.4 Ma BP, information generated from large mammal communities from 221 key sites has been included in this study.The palaeoecological conditions of the western Palaearctic during the Early and early Middle Pleistocene were principally controlled by the following key factors: (1) a widespread trend of temperature decrease, (2) the periodicity of the global temperature record, (3) the intensity of single climatic stages, (4) the temporal pattern of climatic variation, (5) geographical position, and (6) the distribution of continental water resources. A general picture of the evolution of western Palaearctic habitat diversity saw the replacement of extensive forested terrain by an alternating sequence of varied savannah-like and forested habitats during the 2.6–1.8 Ma span, as well as an alternation between different types of predominantly open habitats between 1.8 and 1.2 Ma. Both of these processes were governed by 41 ka temperature periodicity. During the 1.2–0.9 Ma time span, irregular climatic fluctuations were more common and habitat variability increased. The subsequent 0.9–0.4 Ma interval, a period controlled by 100 ka periodicity, was by comparison more stable, with longer climatic cycles alternating between open and forested landscapes. During the entire Early and early Middle Pleistocene, assemblages of large mammal communities reveal a distinct trend of decreasing continentality between Eastern and South-Eastern Europe on the one hand, and South-Western and North-Western Europe on the other. This trend was due to the effect of the Atlantic Ocean, while in Southern Europe the relatively low continentality was balanced by influences from the Mediterranean Sea.When plotted against evidence of hominin occurrence, the data on western Palaearctic habitat diversity inferred from large mammal communities indicate clear environmental stimuli for the earliest human dispersal in Europe. These are: (1) a wide range of habitats, implying a high diversity of resources; (2) mild climates with low seasonality, implying a lack of strong environmental fluctuations. Around 1.8 Ma at the latest, hominins of African origin entered the western Palaearctic for the first time, taking advantage of the diversity of habitats and resources, particularly along large river systems. Their subsequent westward spread between 1.7 and 1.3 Ma was restricted to Mediterranean-influenced areas, which offered a high variability of habitats and relatively low seasonality. The increase in environmental diversity, which occurred from 1.2 Ma onwards, opened up South-Eastern and Eastern Europe for hominin occupation. According to the available records, North-Western and Central Europe were initially colonized during late Early to early Middle Pleistocene interglacials, when these regions experienced periods of low seasonality and considerable habitat diversity.     

Tectonic, eustatic and environmental controls on mid-Cretaceous carbonate platform deposition, south-central Pyrenees, Spain

Cenomanian–Turonian strata of the south‐central Pyrenees in northern Spain contain three prograding carbonate sequences that record interactions among tectonics, sea level, environment and sediment fabric in controlling sequence development. Sequence UK‐1 (Lower to Upper Cenomanian) contains distinct lagoonal, back‐margin, margin, slope and basin facies, and was deposited on a broad, flat shelf adjacent to a deep basin. The lack of reef‐constructing organisms resulted in a gently dipping ramp morphology for the margin and slope. Sequence UK‐2 (Upper Cenomanian) contains similar shallow‐water facies belts, but syndepositional tectonic modification of the margin resulted in a steep slope and deposition of carbonate megabreccias. Sequence UK‐3 (Lower to Middle Turonian) records a shift from benthic to pelagic deposition, as the shallow platform was drowned in response to a eustatic sea‐level rise, coupled with increased organic productivity. Sequences UK‐1 to UK‐3 are subdivided into lowstand, transgressive and highstand systems tracts based on stratal geometries and facies distribution patterns. The same lithologies (e.g. megabreccias) commonly occur in more than one systems tract, indicating that: (1) the depositional system responded to more than just sea‐level fluctuations; and (2) similar processes occurred during different times throughout sequence development. These sequences illustrate the complexity of carbonate platform dynamics that influence sequence architecture. Rift tectonics and flexural subsidence played a major role in controlling the location of the platform margin, maintaining a steep slope gradient through syndepositional faulting, enhancing slope instability and erosion, and influencing depositional processes, stratal relationships and lithofacies distribution on the slope. Sea‐level variations (eustatic and relative) strongly influenced the timing of sequence and parasequence boundary formation, controlled changes in accommodation and promoted platform drowning (in conjunction with other factors). Physico‐chemical and climatic conditions were responsible for reducing carbonate production rates and inducing platform drowning. Finally, a mud‐rich sediment fabric affected platform morphology, growth geometries (aggradation vs. progradation) and facies distribution patterns.