Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.     

Response of single benthic metrics and multi-metric methods to anthropogenic pressure gradients, in five distinct European coastal and transitional ecosystems

In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices.     

Top-down and bottom-up modelling to support low-carbon scenarios: climate policy implications

Bottom-up and top-down models are used to support climate policies, to identify the options required to meet GHG abatement targets and to evaluate their economic impact. Some studies have shown that the GHG mitigation options provided by economic top-down and technological bottom-up models tend to vary. One reason for this is that these models tend to use different baseline scenarios. The bottom-up TIMES_PT and the top-down computable general equilibrium GEM-E3_PT models are examined using a common baseline scenario to calibrate them, and the extend of their different mitigation options and its relevant to domestic policy making are assessed. Three low-carbon scenarios for Portugal until 2050 are generated, each with different GHG reduction targets. Both models suggest close mitigation options and locate the largest mitigation potential to energy supply. However, the models suggest different mitigation options for the end-use sectors: GEM-E3_PT focuses more on energy efficiency, while TIMES_PT relies on decrease carbon intensity due to a shift to electricity. Although a common baseline scenario cannot be ignored, the models’ inherent characteristics are the main factor for the different outcomes, thereby highlighting different mitigation options.

Policy relevance

The relevance of modelling tools used to support the design of domestic climate policies is assessed by evaluating the mitigation options suggested by a bottom-up and a top-down model. The different outcomes of each model are significant for climate policy design since each suggest different mitigation options like end-use energy efficiency and the promotion of low-carbon technologies. Policy makers should carefully select the modelling tool used to support their policies. The specific modelling structures of each model make them more appropriate to address certain policy questions than others. Using both modelling approaches for policy support can therefore bring added value and result in more robust climate policy design. Although the results are specific for Portugal, the insights provided by the analysis of both models can be extended to, and used in the climate policy decisions of, other countries.     

A new approach for measuring surface hydrological connectivity

The development of surface hydrological connectivity is a key determinant of flood magnitude in drylands. Thresholds in runoff response may be reached when isolated runoff-generating areas connect with each other to form continuous links to river channels, enabling these areas to contribute to flood hydrographs. Such threshold behaviour explains observed nonlinearities and scale dependencies of dryland rainfall–runoff relationships and complicates attempts at flood prediction. However, field methods for measuring the propensity of a surface to transmit water downslope are lacking, and conventional techniques of infiltration measurement are often inappropriate for use on non-agricultural drylands. Here, we argue for a reconceptualization of the dryland surface runoff process, suggesting that the downslope transfer of water should be considered alongside surface infiltration; that is, there is a need for the “aggregated” measurement of infiltration and overland flow hydraulics. Surface application of a set volume of water at a standardized rate generates runoff that travels downslope; the distance it travels downslope is determined by infiltration along the flow, integration of flow paths, and flow resistance. We demonstrate the potential of such a combined measurement system coupled with structure-from-motion photogrammetry to identify surface controls on runoff generation and transfer on dryland hillslopes, with vegetation, slope, surface stone cover, and surface roughness all having a significant effect. The measurement system has been used on slopes up to 37° compared with the flat surface typically required for infiltration methods. On average, the field workflow takes ~10–15 min, considerably quicker than rainfall simulation. A wider variety of surfaces can be sampled with relative ease, as the method is not restricted to stone and vegetation-free land. We argue that this aggregated measurement represents surface connectivity and dryland runoff response better than standard hydrological approaches and can be applied on a much greater variety of dryland surfaces.     

Average photon path-length in isotropically scattering finite atmospheres

The determination of the average path-length of photons in a finite isotropically scattering plane-parallel homogeneous atmosphere is discussed. To solve this problem we have used the kernel approximation method which easily allows us to find the derivatives of the intensity with respect to optical depth, optical thickness and albedo of single scattering.In order to check the results we have used another approach by exploiting the set of integrodifferential equations of Chandrasekhar for theX- andY-functions. This approach allows us to find the average path length only at the boundaries of the atmosphere but on the other hand it gives also the dispersion of the path-length distribution function, thus generating the input parameters for determining the approximate path-length distribution function. It occurred that the set so obtained is stable and the results are highly accurate.As a by-product we obtain the first two derivatives of theX- andY-functions with respect to the albedo of single scattering and optical thickness, and the mixed derivative.     

Rayleigh-Cabannes scattering in planetary atmospheres III. The Milne problem in conservative atmospheres

The discrete ordinale method by Chandrasekhar is used to solve the conservative Milne problem in a homogeneous plane-parallel atmosphere which scatters the radiation according to the Rayleigh-Cabannes law.The approximate solution which is supposed to converge uniformly to an exact one when increasing the order of approximation is obtained explicitly. In addition to a tabulation of the Hopf vector for different factors of depolarization, the extrapolation distance, the values of c, q and the Rubenson degrees of polarization at the limb are given.     

Climatic zoning for the calculation of the thermal demand of buildings in Extremadura (Spain)

The present work reports on a methodology to assess the climatic severity of a particular geographic region as compared to specific information available in the current regulations. The viability for each of the 387 municipalities in the Autonomous Community of Extremadura (Spain) is analysed, making a distinction between those with reliable climate reports and those for which no such information is available. In the case study, although the weather conditions in Extremadura are quite homogeneous according to the Spanish Technical Building Code (STBC 2015) classification and most areas are associated to zone C4 (soft winters and hot summers), the southern area in the region is associated to zone D1, similar to the north of Spain, where winters and summers are cool, which does not coincide with the actual climate in the south of Extremadura. The general climatic homogeneity in Extremadura was also highlighted with the new procedure, predominating zone C4, but unexpected or unreal climatic zoning was not generated, giving place to a consistent spatial distribution of zones throughout the region. Consequently, the proposed method allows a more accurate climatic zoning of any region in agreement with the Spanish legislation on energy efficiency in buildings, which would enhance the setting of thermal demand rates according to the actual climatic characterisation of the area in which a particular municipality is located.     

Recent trends in annual snowline variations in the northern wet outer tropics: case studies from southern Cordillera Blanca,Peru

TL-moments approach has been used in an analysis to identify the best-fitting distributions to represent the annual series of maximum streamflow data over seven stations in Johor, Malaysia. The TL-moments with different trimming values are used to estimate the parameter of the selected distributions namely: Three-parameter lognormal (LN3) and Pearson Type III (P3) distribution. The main objective of this study is to derive the TL-moments (t ₁,0), t ₁?=?1,2,3,4 methods for LN3 and P3 distributions. The performance of TL-moments (t ₁,0), t ₁?=?1,2,3,4 was compared with L-moments through Monte Carlo simulation and streamflow data over a station in Johor, Malaysia. The absolute error is used to test the influence of TL-moments methods on estimated probability distribution functions. From the cases in this study, the results show that TL-moments with four trimmed smallest values from the conceptual sample (TL-moments [4, 0]) of LN3 distribution was the most appropriate in most of the stations of the annual maximum streamflow series in Johor, Malaysia.     

Average photon path-length of radiation emerging from finite atmospheres

The determination of the average path-length of photons emerging from a finite planeparallel atmosphere with molecular scattering is discussed. We examine the effects of polarisation on the average path-length of the emergent radiation by comparing the results with those obtained for the atmosphere where the scattering obeys the scalar Rayleigh function. Only the axial radiation field is considered for both cases.To solve this problem we have used the integro-differential equations of Chandrasekhar for the diffuse scattering and transmission functions (or matrices). By differentiation of these equations with respect to the albedo of single scattering we obtain new equations the solution of which gives us the derivatives of the intensities of the emergent radiation at the boundaries.As in the case of scalar transfer the principles of invariance by Chandrasekhar may be used to find an adding scheme to obtain both the scattering and transmission matrices and their derivatives with respect to the albedo of single scattering. These derivatives are crucial in determining the average path length.The numerical experiments have shown that the impact of the polarisation on the average pathlength of the emergent radiation is the largest in the atmospheres with optical thickness less than, or equal to, three, reaching 6.9% in the reflected radiation.     

Estimating airborne heavy metal concentrations in Dunkerque (northern France)

This work aims to estimate the levels of lead (Pb), nickel (Ni), manganese (Mn), vanadium (V) and chromium (Cr) corresponding to a 3-month PM₁₀ sampling campaign conducted in 2008 in the city of Dunkerque (northern France) by means of statistical models based on partial least squares regression (PLSR), artificial neural networks (ANNs) and principal component analysis (PCA) coupled with ANN. According to the European Air Quality Directives, because the levels of these pollutants are sufficiently below the European Union (EU) limit/target values and other air quality guidelines, they may be used for air quality assessment purposes as an alternative to experimental measurements. An external validation of the models has been conducted, and the results indicate that PLSR and ANNs, with comparable performance, provide adequate mean concentration estimations for Pb, Ni, Mn and V, fulfilling the EU uncertainty requirements for objective estimation techniques, although ANNs seem to present better generalization ability. However, in accordance with the European regulation, both techniques can be considered acceptable air quality assessment tools for heavy metals in the studied area. Furthermore, the application of factor analysis prior to ANNs did not yield any improvements in the performance of the ANNs.