Coronal Density Structures and CMEs: Superior Solar Conjunctions of Mars Express, Venus Express, and Rosetta: 2004, 2006, and 2008

Coronal radio-sounding experiments were carried out using the S-band (2.3 GHz) and X-band (8.4 GHz) signals of the ESA Mars Express, Venus Express, and Rosetta spacecraft during five superior conjunctions occurring in 2004, 2006 (3×), and 2008/2009. Differential frequency and propagation delay (ranging) observations were recorded during these opportunities over the better part of a solar cycle, yielding information on the large-scale structure of the coronal electron-density distribution and its variations, including fluctuations on time scales from seconds to hours. These results concern primarily regions of slow solar wind because the radio propagation path is generally confined to the low heliolatitude regions by the conjunction. The mean frequency fluctuation and total electron content are determined as a function of heliocentric distance, and, with a few exceptions caused by streamers and CMEs, are found to be consistent with previous results from experiments on Ulysses. Dense coronal streamers and several coronal mass ejection (CME) events were identified in the radio-frequency data, some of which were observed in white light by the LASCO coronagraphs onboard SOHO. For those events with sufficient mutual coverage, good correlations are found between the electron-content fluctuations and structure imaged by the LASCO instrument.     

Millennial-scale shifts in microtidal ecosystems during the Holocene: dynamics and drivers of change from the Po Plain coastal record (NE Italy)

Framed into a robust stratigraphic context, multivariate analyses on the Holocene palaeobiological record (pollen, benthic foraminifers, ostracods) of the Po coastal plain (NE Italy) allowed the investigation of microtidal ecosystems variability and driving parameters along a 35-km-long land–sea transect. Millennial-scale ecosystem shifts are documented by coeval changes in the meiofauna, reflecting variations in organic matter–water depth (shallow-marine environments) and degree of confinement-salinity (back-barrier settings). In-phase shifts of vegetation communities track unsteady water-table levels and river dynamics in freshwater palustrine areas. Five environmental–ecological stages followed one another crossing four tipping points that mark changes in relative sea level (RSL), climate and/or fluvial regime. At the culmination of Mediterranean RSL rise, after the 8200 event, remarkable growth of peatlands took place in the Po estuary, while low accumulation rates typified the shelf. At the transgressive–regressive turnaround (~7000 cal a bp ), the estuary turned into a delta plain with tidally influenced interdistributary embayments. River flow regime oscillations after the Climate Optimum (post-5000 cal a bp ) favoured isolation of the bays and the development of brackish wetlands surrounded by wooded peatlands. The youngest threshold (~800 cal a bp ), which led to the establishment of the modern delta, reflects a major avulsion of the Po River.     

The Planktonic foraminifera <Emphasis Type="Italic">Globigerinoides eoconglobatus</Emphasis> n. sp. in a glacial–interglacial context: IODP359 Sites U1467 and U1468

Here we define a new morphospecies of planktonic foraminifera Globigerinoides eoconglobatus n. sp., identified from International Ocean Discovery Program (IODP) expedition 359 samples from drift deposits of the Maldives, Inner Sea. Through biostratigraphic analysis, we infer it may be the direct ancestor of Globigerinoides conglobatus evolving from Globigerinoides obliquus in the Late Miocene (Subzone M13a). Globigerinoides eoconglobatus n. sp. can be distinguished from G. conglobatus through both its morphological traits and stable isotopic signature (δ¹⁸O and δ¹³C) in pre-adult and adult specimens. The most defining characteristic being its aperture height (AH). A variance in adult stable isotopic signals shows a possible difference in life strategies, possibly related to symbionts (presence/absence or concentration) and/or depth habitat. This work also tentatively shows G. eoconglobatus n. sp. and G. conglobatus abundances are linked to glacial–interglacial stages. Its low abundances and similarities to its descendent Globigerinoides conglobatus has likely accounted for it being unreported, until present, in both modern and fossil studies.     

Presence of plastic debris in loggerhead turtle stranded along the Tuscany coasts of the Pelagos Sanctuary for Mediterranean Marine Mammals (Italy)

This work evaluated the presence and the frequency of occurrence of marine litter in the gastrointestinal tract of 31 Caretta caretta found stranded or accidentally bycaught in the North Tyrrhenian Sea. Marine debris were present in 71% of specimens and were subdivided in different categories according to Fulmar Protocol (OSPAR 2008). The main type of marine debris found was user plastic, with the main occurrence of sheetlike user plastic. The small juveniles showed a mean ± SD of marine debris items of 19.00 ± 23.84, while the adult specimens showed higher values of marine litter if compared with the juveniles (26.87 ± 35.85). The occurrence of marine debris observed in this work confirms the high impact of marine debris in the Mediterranean Sea in respect to other seas and oceans, and highlights the importance of Caretta caretta as good indicator for marine litter in the Marine Strategy Framework Directive (MSFD) of European Union.     

Particulate Thiol Peptides Along a Salinity Gradient of a Metal-Contaminated Estuary

The thiol peptide phytochelatins (PC2; the polymer with n = 2) are efficient metal-chelating compounds produced by phytoplankton and higher plants. Both PC2 and their precursor glutathione (GSH) are related to detoxification mechanisms. GSH and PC2 were quantified using liquid chromatography with fluorescent detection and observed in the particulate phase along a salinity gradient of the Tamar Estuary (SW UK), a heavily metal impacted site, at concentrations up to 274 and 16.5 μmol (g chl a)⁻¹, respectively. The peptides predominated within low (0–5) and mid-salinities (5–20). Down-estuary, at sites farther from metal sources and salinities higher than 20, PC2 showed a sharp decrease or were not detected. High PC2/GSH ratios indicated areas with augmented concentrations of bioavailable metals at the tidal limit, near Cu mines and the mid-estuary where resuspension of sediments occurs. By following typical partitioning patterns previously reported for dissolved Cu and Zn, the production of thiol peptides, notably PC2, reflected a rapid interaction between the particulate and dissolved phases.     

Influence of the properties of tropical soils in the toxicity and bioavailability of heavy metals in sewage sludge-amended lands

The toxicity and potential bioavailability of heavy metals were studied in sewage sludge-amended ferralsols and chernosols, using bioassays with earthworms (Eisenia andrei). Acute toxicity tests and avoidance assays were performed according to standard protocols. Potentially bioavailable concentrations of heavy metals were estimated by quantifying their concentrations in tissues of survival earthworms. The results revealed that soil properties played an important role in the toxicity and bioavailability of heavy metals. In this respect, higher levels of toxicity were detected for the ferralsol. The abundance of 2:1 clay minerals, high fertility and more basic values of pH seem to be very important in the reduction of toxicity levels for earthworms. Organisms exposed to the chernosols were able to uptake higher amount of metals. In that case, higher contents of nutrients in chernosols may have influenced such bioavailability processes. Avoidance responses were the most sensible indicator of toxicity. In the near future, such data can subsidize the establishment of toxic reference concentrations able to reflect the characteristics of important tropical pedological occurrences, supporting the definition of sustainable indicators for using sewage sludge in the tropical agriculture.     

Tectono-stratigraphic evolution of an inverted extensional basin: the Cameros Basin (north of Spain)

The Cameros Basin is a part of the Mesozoic Iberian Rift. It is an extensional basin formed during the late Jurassic and early Cretaceous, in the Mesozoic Iberian Rift context, and it was inverted in the Cenozoic as a result of the Alpine contraction. This work aims to reconstruct the tectono-stratigraphic evolution of the basin during the Mesozoic, using new and revised field, geophysical and subsurface data. The construction of a basin-wide balanced section with partial restorations herein offers new insights into the geometry of the syn-rift deposits. Field data, seismic lines and oil well data were used to identify the main structures of the basin and the basin-forming mechanisms. Mapping and cross-sectional data indicate the marked thickness variation of the depositional sequences across the basin, suggesting that the extension of the depositional area varied during the syn-rift stage and that the depocentres migrated towards the north. From field observation and seismic line interpretation, an onlap of the depositional sequences to the north, over the marine Jurassic substratum, can be deduced. In the last few decades, the structure and geometry of the basin have been strongly debated. The structure and geometry of the basin infill reconstructed herein strongly support the interpretation of the Cameros Basin as an extensional-ramp synclinal basin formed on a blind south-dipping extensional ramp. The gradual hanging-wall displacement to the south shifted the depocentres to the north over time, thus increasing the basin in size northwards, with onlap geometry on the pre-rift substratum. The basin was inverted by means of a main thrust located in a detachment located in the Upper Triassic beds (Keuper), which branched in depth with the Mesozoic extensional fault flat. The reconstruction of the tectono-stratigraphic evolution of the Cameros Basin proposed herein represents a synthesis and an integration of previous studies of the structure and geometry of the basin. This study can be used as the basis for future basin-scale research and for modelling the ancient petroleum system of the basin.     

Indigenous perception of changes in climate variability and its relationship with agriculture in a Zoque community of Chiapas, Mexico

This study analyses the perceptions of Zoque indigenous men and women of changes in climate variability, indicated by rainfall and temperature records from the region. Peasant farmers perceive decreases in rainfall and increases in temperature as these factors are related to modifications in the corn planting season and the introduction of crops which were usually only found in hot regions. The climate changes in the zone are attributed to vegetation loss and the eruption of the Chichón volcano in 1982. The Zoque perception is structured according to cultural and individual experience, tied to agriculture and the annual weather calendar. The volcanic eruption offers a significant chronological reference point in order to explain different environmental transformations, such as climate, within Zoque territory. Perception is the mental picture of local climate variability changes and the responses in seasonal agriculture modifications, utilizing individual and cultural experiences which are vulnerable to economic and environmental change.     

Trace element distribution in annual stalagmite laminae mapped by micrometer-resolution X-ray fluorescence: Implications for incorporation of environmentally significant species

Stalagmite ER78, from Grotta di Ernesto cave in NE Italy displays clear annual lamination consistent with its shallow depth below a forest ecosystem subject to autumnal peaking of water infiltration. Synchrotron radiation scanning micro-X-ray fluorescence analyses of heavy elements at European Synchrotron Radiation Facility beamline ID22, and light elements at ID21, with 1-3 μm resolution has been combined with data from ion microprobe analyses to reveal chemical variability across the visible layers of these annual laminae. A series of elements display a symmetrical peak, centered around the thin, dark layer at the top of each lamina. The peak concentration is ordered Y > Zn, Cu and Pb > P and Br. This hierarchy is thought to reflect the selectivity of transport of these elements, possibly by organic colloids flushed from the soil zone during autumn infiltration. Ion microprobe analysis indicates Na and F also increase, as does H, the latter reflecting increased microporosity. Sr displays a trough around the dark and thin autumn layer implying that its incorporation may be limited by competition with other elements. Mg and S show a different pattern of annual variation and Fe displays none. The trace metals, Br and Y display peak abundance in the early 20th century, which appears to reflect a period of tree-felling rather than a climatic anomaly. The results demonstrate the power of the high spatial resolution and low detection limits of the synchrotron technique, and its ability to produce quantitative maps that allow distinction of layered structure from that of isolated particles, or irregular inhomogeneities.