A method for calculating effective bulk composition modification due to crystal fractionation in garnet-bearing schist: implications for isopleth thermobarometry

Quantitative P–T path determination in metamorphic rocks is commonly based on the variation in composition of growth‐zoned garnet. However, some component of growth zoning in garnet is necessarily the result of an effective bulk composition change within the rock that has been generated by crystal fractionation of components into the core of garnet. Therefore, any quantitative calculation of the P–T regime of garnet growth should be completed using an accurate assessment of the composition of the chemical system from which garnet is growing. Consequently, a method for calculating the extent of crystal fractionation that provides a means of estimating the composition of the unfractionated rock at any stage during garnet growth is developed. The method presented here applies a Rayleigh fractionation model based on measured Mn content of garnet to generate composition v. modal proportion curves for garnet, and uses those curves to estimate the vectors of crystal fractionation. The technique is tested by calculating the precision of the equilibrium between three garnet compositional variables within the chemical system determined to be appropriate for each of a series of microprobe analyses from garnet. Application of the fractionation calculations in conjunction with the P–T estimates based on intersecting compositional isopleths provides a means of calculating P–T conditions of garnet growth that is based on individual point‐analyses on a garnet grain. Such spatially precise and easily obtainable P–T data allow for detailed parallel studies of the microstructural, the P–T, and the chemical evolution of metamorphosed pelites. This method provides a means of studying the dynamics of orogenic systems at a resolution that was previously unattainable.     

Retrograded textures and associated mass transfer: evidence for aqueous fluid action during exhumation of the Qinglongshan eclogite, Southern Sulu ultrahigh pressure metamorphic terrane, eastern China

The Qinglongshan eclogites in the Southern Sulu ultrahigh pressure metamorphic (UHPM) terrane show very different retrograded textures from their counterparts in the Northern Sulu terrane, implying a different thermal history. Scanning electron and optical microscope observations indicate that the peak assemblage of the Qinglongshan eclogite is anhydrous, composed of Grt + OmpI + Rt + (Ky + coesite). These primary minerals were replaced by second and third stage minerals, resulting in symplectite pseudomorphs or coronas. The following relationships are inferred: OmpI → OmpII + Ab + Fe‐oxide symplectite (type I) and Rt → Rt + Ilm intergrowth; and, Ky → Pg, OmpII (+Pl) → Amp (+Pl) symplectite (type II), and Grt → Prg (+Fe‐oxide). Mineral chemistry and mass‐balance demonstrate that the pseudomorphed textures were developed by metasomatism involving dissolution and precipitation intensified by fluids along grain boundaries. The formation of symplectite type I produced Fe, Mg and Na but consumed Ca and Si. The Mg and Fe diffused to garnet where exchange of (Mg, Fe) with Ca of the garnet resulted in compositional zonation with decreased Ca towards the edge of garnet grains where Ca was consumed during symplectite formation. The replacement of kyanite by paragonite consumed the extra Na. In the later stage, fluid infiltration partially transformed symplectite type I to type II, and narrow rims of pargasite resorbed garnet from their boundaries. Mass balance suggests that the transformation and resorption would have been coupled during fluid infiltration. In the latest stage, epidote and quartz were precipitated at very late stage as a result of fluid activity along microfractures. Tentative P–T conditions based on mineral reactions and thermocalc software suggest that the retrograded eclogite did not record the granulite facies retrograde evolution characteristic of eclogites from the Northern Sulu terrane. The difference in retrograde evolution between the Southern and Northern Sulu eclogites suggests a different exhumation history.     

Analysis of geomagnetic field along seismic profile P4 of the International Project POLONAISE'97

This paper presents relative secular variations of the total intensity of the geomagnetic field against a background of results of magnetic anomaly interpretation along seismic profile P4. Profile P4 crosses a Variscan folding zone in the Paleozoic Platform (PLZ), the Trans-European Suture Zone (TESZ), and the Polish part of the East European Craton (EEC). Secular geomagnetic field variations measured in 1966–2000 along a line adjacent to seismic profile P4 were analysed. The study of secular variations, reduced to the base recordings at the Belsk Magnetic Observatory, showed that the growth of geomagnetic field at the East European Craton was slower than in the Trans-European Suture Zone and the Paleozoic Platform.A 2D crustal magnetic model was interpreted as a result of magnetic modelling, in which seismic, geological and geothermal data were also used. The modelling showed that there were significant differences in the magnetic model for geotectonic units, which had been earlier determined based on deep seismic survey data. It should be noted that a fundamental change of trend of the relative secular variations was observed at the slope of the Precambrian Platform. After analysing the geomagnetic field observed along profile P4, the hypothesis that the contact between Phanerozoic and Precambrian Europe lies in Poland's territory can be proven.     

The palaeoenvironmental and palaeohydrological evolution of Padul Peat Bog (Granada, Spain) over one million years, from elemental, isotopic and molecular organic geochemical proxies

The elemental (concentration of organic carbon, atomic H/C and C/N ratios), isotopic (δ¹³C values of organic matter) and molecular (predominant n-alkane chain length and carbon preference index (CPI)) organic components were measured for 600 samples taken from a 107-m long core from the Padul Basin (Andalusia, Spain). The record runs from the Lower Pleistocene (ca. 1 Ma B.P.) to the mid-Holocene (ca. 4.5 ka B.P.) with, in general, little diagenesis (removal of components). Two markedly different hydrogeological scenarios were interpreted: (1) From ca. 1 Ma to ca. 400 ka B.P. run-off recharge was significant and water depths were greater (lacustrine scenario). From ca. 400 to 4.5 ka B.P., the Padul Basin became a peat bog s.s. with the major water input coming from groundwater inflow. From ca. 400 to ca. 180 ka B.P. alternating episodes with either predominant grasses, trees or aquatic macrophytes which were linked to wet/dry phases, took place. An important deglaciation episode has been interpreted to occur between ca. 180 and 170 ka B.P. The global climatic changes occurring from ca. 170 to 25 ka B.P. were not recorded in the proxies, though they do show important variations linked to the Last Glacial Maximum and the beginning of the Holocene (ca. 25–10 ka B.P.): (2) Cold phases coexisting with dry periods produced the recession of forests and the development of grasses. After these periods, as both temperature and precipitation increased, forests expanded and the water level, linked to thaw, rose, especially at ca. 20 ka B.P. Few changes occurred during the Holocene, although there were short alternations between wet and dry episodes. Overall, the techniques applied proved to be excellent palaeoenvironmental proxies for studying the basin’s palaeoclimatological and palaeohydrological evolution.     

Triaxial stress state deep in orogenic belts: an example from Turkey

A rare metachert pebble containing amphibole grains with microboudin structures in a wide range of orientations provides an opportunity to perform stress analysis in two orthogonal orientations on the foliation surface. The sample was analysed by the microboudin method to infer the triaxial stress state during microboudinage. Stress parameters proportional to the far-field differential stress were determined for sodic amphibole grains in the two orientations. The ratio of the stresses in the two orthogonal orientations (σ₁−σ₂)/(σ₁−σ₃) was calculated to be 0.64, indicating that σ₂ lies closer to the midpoint between σ₁ and σ₃ than to σ₃.     

Fold-Thrust-Belt Structure of the Proterozoic Eastern Ghats Mobile Belt: A Proposed Correlation Between India and Antarctica in Gondwana

The Proterozoic Eastern Ghats Mobile Belt along the east coast of India shares a thrusted lower contact with the surrounding cratons. The thrust, known as the Terrane Boundary shear zone, is associated with two large lateral ramps resulting in a curved outline on the northwestern corner of the mobile belt. The Eastern Ghats Mobile Belt is divided into two lithotectonic units, the Lathore Group and the Turekela Group, based on their lithological assemblages and deformational history. On the basis of published data from a Deep Seismic Sounding (DSS) profile of the Eastern Ghats crust, the Terrane Boundary Shear Zone is considered to be listric in nature and acts as the sole thrust between craton and mobile belt. The Lathore and Turekela Groups are nappes. With this structural configuration the NW part is described as a fold thrust belt. However, the thrusting postdates folding and granulite metamorphism that occurred in the Eastern Ghats, as in the Caledonide type of fold thrust belt of NW Scotland. The Terrane Boundary Shear Zone is interpreted to be contiguous with the Rayner-Napier boundary of the Enderby Land in a Gondwana assembly.     

An attenuation relationship based on Turkish strong motion data and iso-acceleration map of Turkey

This paper presents an attenuation relationship of peak ground acceleration (PGA) derived from Turkish strong motion data for rock, soil and soft soil sites and an iso-acceleration map of Turkey based on this relationship. For the purpose, among all the three-component accessible records, 221 records from 122 earthquakes that occurred in Turkey between 1976 and November 2003 were selected. The database was compiled for earthquakes with moment magnitudes (M_w) and PGA values ranging between 4.1 and 7.5, and 20 and 806 gal, and distances to epicenter considered in the database were between 5 and 100 km. From the regression analysis of the data, an attenuation equation of PGA considering rock, soil and soft soil conditions was developed. The PGA values predicted from the equation suggested in this study and those both from a few domestic equations and some imported equations were compared. In addition, an iso-acceleration map of Turkey was constructed using the suggested attenuation equation and considering both known active faults and epicenter locations of the earthquakes that have occurred in Turkey.     

Effective resource estimates for primary diamond deposits from the EKATI Diamond Mine™, Canada

Primary economic diamond deposit modelling has rarely been documented in the public domain. This paper presents information collected from significantly diamondiferous kimberlite pipes located near Lac de Gras in the Arctic region of Canada's Northwest Territories. The resource estimation process is widely accepted as a cyclical iteration of data collection and evaluation processes. A resource database is typically assembled from a large inventory of exploration data. These data must be methodically quality checked before accepting the information for interpretive analysis. The foundation of a mineral resource model is based on clear understanding of the geology model along with subsidiary grade, volume, and density models. Defining these models is an iterative process of statistical analyses and interpretation. As a deposit progresses along a path towards development, reducing risk to acceptable levels is critical for identifying and realizing its maximum value.     

Low-frequency 3-D seismic survey of upper crustal magmatic intrusions in the northeastern Pannonian basin of Hungary

A specially designed 700-km² grid survey, deploying 1000 regularly distributed low-frequency seismic recording systems, successfully investigated one of the most complex geologic environments of the Pannonian basin. The wide-angle signals penetrated through over 1000 m of multi-phase igneous lithology and recognized, for the first time, the underlying enigmatic Permian to Early Triassic basement rocks. Tomographic inversion of the first arrival grid data resulted in determination of an accurate three-dimensional (3-D) velocity field, to a depth of 4 km. The anomalous changes of the spatial velocity data outline the regional extent of the Late Miocene magmatic intrusions, which are covered by over 2000 m of Mid-Miocene to Pleistocene clastics. Complex relationship was found between the surface potential data and the intrusive bodies. This multi-faceted geophysical data analysis established a functional technique for mapping a subsurface with intricate acoustic and structural complexity.     

Organic matter in a low productivity anoxic intraplatform basin in the Triassic Tethys

This paper presents isotopic, bulk geochemical and biomarker data measured on organic matter accumulated in a narrow extensional basin developed at the oceanward margin of the huge Triassic carbonate platform in the Alps–Appenines domain. The integration of isotope signatures, organic petrographical and biomarker evidence together with the composition of kerogen pyrolysates suggests immature organic matter predominantly of algal origin with a minor, but not negligible, higher plant derived and moderate bacterial contribution for the entire sequence. The mineral sources are dominated by platform-derived subtidal Dachstein limestone with a minor palaeosol input and a moderate contribution of autochtonous quartz. Nevertheless, parallel variations observed in the mineral content, as well as in the amount and the quality of the organic matter reflect variations in the palaeoenvironment. The increased humidity, existing in the period of the accumulation of the upper section of the sequence, led to the restriction of dolomitization. A slightly greater higher plant derived contribution, in this section, is evidenced by the composition of bitumen and the results on GC and GC/MS analyses on the non-aromatic hydrocarbon fraction of bitumen. Moreover, the climate-induced weathering enchanced the primary productivity and resulted in a pronounced increase in the TOC content. The average estimated value of the planktonic productivity is about three times higher for the calcite-rich sequence than the dolomite-rich one, being 44.2 and 15.3 tC_org/m²/Ma, respectively. The low to moderate planktonic productivity shows that anoxic conditions, observed for the entire succession, are a consequence of the stagnant water stratification rather than high planktonic productivity. Depth trends in the data measured on kerogens (HI, OI, δ¹³Corg values, composition of pyrolysate) together with the δ¹⁸O excursions and Δδ¹³C values appear to be controlled by sea-level fluctuations. Consistent with the high abundance of alkyltiophenes in kerogen pyrolysates, the high S_org/C ratios (ranging between 0.05 and 0.10) suggest the importance of natural sulfurization in the formation of the sulfur-rich type-II-S kerogen occurring in all of the samples.