Nonlinear kinetic analysis of phenol adsorption onto peat soil

Phenolic compounds are considered as a serious organic pollutant containing in many industrial effluents particularly vulnerable when the plant discharge is disposed on land. In the present study, the phenol removal potential of peat soil as adsorption media was investigated as the adsorption process are gaining popular for polishing treatment of toxic materials in industrial wastewater. Batch experiments were performed in the laboratory to determine the adsorption isotherms of initial concentrations for 5, 8, 10, 15, and 20 mg/L and predetermined quantity of peat soil with size ranges between 425 and 200 μm poured into different containers. The effects of various parameters like initial phenol concentration, adsorbent quantity, pH, and contact time were also investigated. From experimental results, it was found that 42 % of phenol removal took place with optimized initial phenol concentration of 10 mg/L, adsorbent dose of 200 g/L, solution pH 6.0 for the equilibrium contact time of 6 h. The result exhibits that pseudo-first-order (R ² = 0.99) and Langmuir isotherm models are fitted reasonably (R ² = 0.91). Adams–Bohart, Thomas, Yoon–Nelson, and Wolborska models were also investigated to the column experimental data of different bed heights to predict the breakthrough curves and to determine the kinetic coefficient of the models using nonlinear regression analysis. It was found that the Thomas model is the best fitted model to predict the experimental breakthrough curves with the highest coefficient of determination, R ² = 0.99 and lowest root mean square error and mean absolute performance error values.     

Felsic tuff from Rutland Island — A pyroclastic flow deposit in Miocene-sediments of Andaman-Java subduction complex

The bedded felsic tuff exposed in Rutland Island, Andaman, consists of two facies:

Calibration of the carbonate ‘clumped isotope’ paleothermometer for otoliths

Paleothermometry is an essential tool for understanding past changes in climate. The ‘carbonate clumped isotope thermometer’ is a temperature proxy related to ordering of ¹³C and ¹⁸O in the carbonate lattice (based on measurements of ¹³C¹⁸O¹⁶O in CO₂ produced by acid digestion of carbonate). This thermometer has been previously calibrated for inorganic calcite and aragonitic corals [Ghosh P., Adkins J., Affek H., Balta B., Guo W. F., Schauble E. A., Schrag D., and Eiler J. M. (2006) C-13-O-18 bonds in carbonate minerals: a new kind of paleothermometer. Geochim. Cosmochim. Acta70 (6), 1439-1456]. Here we determine the relationship between growth temperatures of aragonitic fish otoliths and abundances of ¹³C¹⁸O¹⁶O produced by acid digestion of those otoliths. Our calibration is based on analyses of otoliths from six species from four genera of modern fish sampled from a latitudinal transect of the Atlantic Ocean between 54° S and 65° N, plus one species from the tropical western Pacific. The temperatures at which fish otoliths precipitated were estimated by the mean temperature in the waters in which they lived, averaged over their estimated lifetimes. Estimated growth temperatures of our samples vary between 2 and 25 °C. Our results show that the abundance of ¹³C¹⁸O¹⁶O in CO₂ produced by acid digestion of fish otolith aragonite is a function of growth temperature, following the relationship: , where Δ₄₇ is the enrichment, in per mil, of ¹³C¹⁸O¹⁶O in CO₂ relative to the amount expected for a stochastic (random) distribution of isotopes among all CO₂ isotopologues, and T is the temperature in Kelvin. This relationship closely approaches that previously documented for inorganic calcite and aragonitic coral (Ghosh et al., 2006).     

Cation distribution in amphiboles synthesized along the Ga analogue of the tremolite–aluminotschermakite join

 Amphiboles were synthesized from bulk compositions prepared along the join Ca_1.8Mg_5.2Si₈O₂₂(OH)₂–Ca_1.8Mg₃Ga₄Si₆O₂₂(OH)₂ hydrothermally at 750–850 °C and 1.0–1.8 GPa, and along the join Ca₂Mg₅Si₈O₂₂F₂–Ca₂Mg₃Ga₄Si₆O₂₂F₂, anhydrously at 1000 °C and 0.7 GPa to document how closely the tschermak-type substitution is obeyed in these analogues of aluminous amphiboles. Electron-microprobe analyses and Rietveld X-ray diffraction structure refinements were performed to determine cation site occupancies. The extent of Ga substitution was found to be limited in both joins, but with the fluorine series having about twice the Ga content (0.6 atoms per formula unit, apfu) of the hydroxyl-series amphiboles (0.3 apfu). The tschermak-type substitution was followed very closely in the hydroxyl series with essentially equal partitioning of Ga between tetrahedral and octahedral sites. The fluorine-series amphiboles deviated significantly from the tschermak-type substitution and, instead, appeared to follow a substitution that is close to a Ca-pargasite substitution of the type: ^[6]Ga³⁺+2^[4]Ga³⁺+1/2^[A] Ca²⁺ = ^[6]Mg²⁺+2^[4]Si⁴⁺+1/2^[A]□. Infrared spectroscopy revealed an inverse correlation between the intensity of the OH-stretching bands and the Ga content for the hydroxyl- and fluorine-series amphiboles. The direct correlation between the Ga and F content and inverse relationship between the Ga and OH content may be a general phenomenon present in other minerals and suggests, for example, that high F contents in titanite are controlled by the Al content of the host rock and that there may be similar direct Al–F correlations in tschermakitic amphiboles. Evidence for the possibility that Al (Ga) might substitute onto only a subset of the tetrahedral sites in tschermakitic amphiboles was sought but not observed in this study. Received: 5 March 2001 / Accepted: 31 July 2001     

Effect of soil interaction on the performance of liquid column dampers for seismic applications

The effects of soil–structure interaction (SSI) while designing the liquid column damper (LCD) for seismic vibration control of structures have been presented in this study. The formulation for the input–output relation of a flexible‐base structure with attached LCD has been presented. The superstructure has been modelled by a single‐degree‐of‐freedom (SDOF) system. The non‐linearity in the orifice damping of the LCD has been replaced by equivalent linear viscous damping by using equivalent linearization technique. The force–deformation relationships and damping characteristics of the foundation have been described by complex valued impedance functions. Through a numerical stochastic study in the frequency domain, the various aspects of SSI on the functioning of the LCD have been illustrated. A simpler approach for studying the LCD performance considering SSI, using an equivalent SDOF model for the soil–structure system available in literature by Wolf (Dynamic Soil–Structure Interaction. International Series in Civil Engineering and Engineering Mechanics. Prentice‐Hall: Englewood Cliffs, NJ, 1985) has also been presented. Copyright © 2005 John Wiley & Sons, Ltd.     

Fall,classification and cosmogenic records of the Sabrum (LL6) chondrite

Abstract— The petrographic and chemical characteristics of a fresh Indian meteorite fall at Sabrum are described. Its mean mineral composition is defined by olivine (Fa_31.4), orthopyroxene (Fs_25.1,Wo_2.0), clinopyroxene (Wo₄₅En_45.6Fs_9.4) and plagioclase (An_10.6Ab_83.6Or_5.8). The meteorite shows moderate shock features, which indicate that it belongs to the S4 category. Based on mineralogical and chemical criteria the meteorite is classified as an LL6 brecciated veined chondrite. Several cosmogenic radioisotopes (⁴⁶Sc, ⁷Be, ⁵⁴Mn, ²²Na and ²⁶Al), noble gas (He, Ne, Ar, Kr and Xe), nitrogen isotopes, and particle tracks density have been measured. Concentrations of cosmogenic ²¹Ne and ³⁸Ar indicate that its cosmic‐ray exposure age is 24.8 Ma. Small amounts of trapped Kr and Xe, consistent with petrologic class 5/6, are present. The track density in olivines is found to be (1.3 ± 0.3) × 10⁶/cm². Activities of most of the short‐lived isotopes are lower than those expected from solar cycle variation. ²²Na/²⁶Al (1.12 ± 0.02) is found to be significantly anomalous, being ?25% lower than expected from the Climax neutron monitor data. These results indicate that the cosmic‐ray flux during the terminal segment of the meteoroid orbit was low. The activities of ²⁶Al and ⁶⁰Co and the track density indicate small meteoroid size with a radius ?15 cm.     

Evidence for the thrust emplacement of the ‘Lesser Himalaya’ Chur granite,Himachal Pradesh

Numerous peraluminous and porphyritic granitic bodies and augen gneisses of granitic compositions occur in the nappe sequences of the Lower Himalaya. They are Proterozoic-to-lower Paleozoic in age and have been grouped into the ‘Lesser Himalaya granite belt’. The mode of emplacement and tectonic significance of these granites are as yet uncertain but they are generally considered to be sheet-like intrusions into the surrounding rocks. The small and isolated granite body (the Chur granite) that crops out around the Chur peak in the Himachal Himalaya is one of the more famous of these granites. Several lines of evidence have been adduced to show that the Chur granite has a thrust (the Chur thrust) contact with the underlying metasedimentary sequence (locally called the Jutogh Group). The Chur granite with restricted occurrence at the highest topographic and structural levels represents an erosional remnant of a much larger sub-horizontal thrust sheet. The contact relations between the country rocks and many of the other granite and granitic augen gneisses in the Lesser Himalaya belt are apparently similar to that of the Chur granite suggesting that at least some of them may also represent thrust sheets.     

Spatio‐temporal prediction of land surface temperature using semantic kriging

Spatio‐temporal prediction and forecasting of land surface temperature (LST) are relevant. However, several factors limit their usage, such as missing pixels, line drops, and cloud cover in satellite images. Being measured close to the Earth's surface, LST is mainly influenced by the land use/land cover (LULC) distribution of the terrain. This article presents a spatio‐temporal interpolation method which semantically models LULC information for the analysis of LST. The proposed spatio‐temporal semantic kriging (ST‐SemK) approach is presented in two variants: non‐separable ST‐SemK (ST‐SemK_NSep) and separable ST‐SemK (ST‐SemK_Sep). Empirical studies have been carried out with derived Landsat 7 ETM+ satellite images of LST for two spatial regions: Kolkata, India and Dallas, Texas, U.S. It has been observed that semantically enhanced spatio‐temporal modeling by ST‐SemK yields more accurate prediction results than spatio‐temporal ordinary kriging and other existing methods.     

Lithology-dependent seismic anisotropic amplitude variation with offset correction in transversely isotropic media

Analysis of amplitude variation with offset is an essential step for reservoir characterization. For an accurate reservoir characterization, the amplitude obtained with an isotropic assumption of the reservoir must be corrected for the anisotropic effects. The objective is seismic anisotropic amplitude correction in an effective medium, and, to this end, values and signs of anisotropic parameter differences (Δδ and Δε) across the reflection interfaces are needed. These parameters can be identified by seismic and well log data. A new technique for anisotropic amplitude correction was developed to modify amplitude changes in seismic data in transversely isotropic media with a vertical axis of symmetry. The results show that characteristics of pre-stack seismic data, that is, amplitude variation with offset gradient, can be potentially related to the sign of anisotropic parameter differences (Δδ and Δε) between two layers of the reflection boundary. The proposed methodology is designed to attain a proper fit between modelled and observed amplitude variation with offset responses, after anisotropic correction, for all possible lithofacies at the reservoir boundary. We first estimate anisotropic parameters, that is, δ and ε, away from the wells through Backus averaging of elastic properties resulted from the first pass of isotropic pre-stack seismic inversion, on input data with no amplitude correction. Next, we estimate the anisotropic parameter differences at reflection interfaces (values and signs of Δδ and Δε). We then generate seismic angle gather data after anisotropic amplitude correction using Rüger's equation for the P-P reflection coefficient. The second pass of isotropic pre-stack seismic inversion is then performed on the amplitude-corrected data, and elastic properties are estimated. Final outcome demonstrates how introduced methodology helps to reduce the uncertainty of elastic property prediction. Pre-stack seismic inversion on amplitude-corrected seismic data results in more accurate elastic property prediction than what can be obtained from non-corrected data. Moreover, a new anisotropy attribute (ν) is presented for improvement of lithology identification.     

Deformation Modulus of Fly Ash Modified with Lime and Gypsum

Deformation modulus of fly ash is one of the most important mechanical properties generally used in different design problems and also as an input parameter to sophisticated numerical techniques employed to assess the response of different structures resting on fly ash fill or embankment made of fly ash. Deformation modulus is usually expressed in terms of compressive strength. This paper presents the deformation modulus of fly ash modified with lime alone or in combination with gypsum at different strain levels. The values of deformation modulus obtained from both unconfined compression test and unconsolidated undrained triaxial test results are presented herein. The specimens for unconfined compression test and for undrained triaxial tests were cured up to 90 and 28 days, respectively. The effects of addition of lime (4–10%) and gypsum (0.5 and 1.0%) on the deformation modulus of class F fly ash are highlighted. With addition of lime and gypsum, the class F fly ash achieved the deformation modulus in the range of 190 MPa in UCS test and up to 300 MPa in triaxial test specimens tested under all round pressure of 0.4 MPa. Based on the present test results empirical relationships are developed to estimate deformation modulus of modified fly ash from unconfined compressive strength and relationships between initial tangent modulus and secant modulus at different strain levels are also developed.