Late Jurassic Cu-Mo Mineralization at the Zhashui-Shanyang District, South Qinling, China: Constraints from Re-Os Molybdenite and Laser Ablation-Inductively Coupled Plasma Mass Spectrometry U-Pb Zircon Dating

The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism. Laser Ablation-Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) U-Pb zircon dating of two granodiorite intrusions (Xiaohekou and Lengshuigou deposits) was investigated in the Zhashui-Shanyang district and the rock-forming ages obtained from 148.3±2.8?to 152.6±1.2?Ma, averaging 150.5 Ma, accompanied by a younger disturbance age of 144.3±1.7?Ma in the Lengshuigou intrusion, which is in excellent agreement with published sensitive high resolution ion micro-probe (SHRIMP) zircon date on the later monzodiorite porphyry phase in the Lenshuigou deposit. Two samples were selected for molybdenite ICP-MS Re-Os isotopic analyses from the Lengshuigou granodiorite porphyry, yielding Re-Os model ages from 149.2±2.7 Ma to 150.6±3.4 Ma, with a weighted mean age of 149.7±2.1 Ma. These mineralization ages overlap rock-forming ages of the host intrusions within the error range. This implies that the mineralization occurred in the Late Jurassic, which belongs to the tectonic phase B event of the Yanshan Movement, not Cretaceous as previously thought. Therefore, the Late Jurassic mineralization of the Zhashui-Shanyang district could be connected to the large-scale Yanshan molybdenum metallogenic period, the geodynamic regime of which is attributable to the far field response of convergence of surrounding plates, perhaps the approximately westward subduction of the Izanagi plate beneath the Eurasian continent.     

Simulation and Improvements of Oceanic Circulation and Sea Ice by the Coupled Climate System Model FGOALS-f3-L

This study documents simulated oceanic circulations and sea ice by the coupled climate system model FGOALS-f3-L developed at the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics, Chinese Academy of Sciences, under historical forcing from phase 6 of the Coupled Model Intercomparison Project (CMIP6). FGOALS-f3-L reproduces the fundamental features of global oceanic circulations, such as sea surface temperature (SST), sea surface salinity (SSS), mixed layer depth (MLD), vertical temperature and salinity, and meridional overturning circulations. There are notable improvements compared with the previous version, FGOALS-s2, such as a reduction in warm SST biases near the western and eastern boundaries of oceans and salty SSS biases in the tropical western Atlantic and eastern boundaries, and a mitigation of deep MLD biases at high latitudes. However, several obvious biases remain. The most significant biases include cold SST biases in the northwestern Pacific (over 4°C), freshwater SSS biases and deep MLD biases in the subtropics, and temperature and salinity biases in deep ocean at high latitudes. The simulated sea ice shows a reasonable distribution but stronger seasonal cycle than observed. The spatial patterns of sea ice are more realistic in FGOALS-f3-L than its previous version because the latitude–longitude grid is replaced with a tripolar grid in the ocean and sea ice model. The most significant biases are the overestimated sea ice and underestimated SSS in the Labrador Sea and Barents Sea, which are related to the shallower MLD and weaker vertical mixing.     

CAS-FGOALS Datasets for the Two Interglacial Epochs of the Holocene and the Last Interglacial in PMIP4

Two versions of the Chinese Academy of Sciences Flexible Global Ocean–Atmosphere–Land System model(CASFGOALS), version f3-L and g3, are used to simulate the two interglacial epochs of the mid-Holocene and the Last Interglacial in phase 4 of the Paleoclimate Modelling Intercomparison Project(PMIP4), which aims to study the impact of changes in orbital parameters on the Earth's climate. Following the PMIP4 experimental protocols, four simulations for the mid-Holocene and two simulations for the Last Interglacial have been completed, and all the data, including monthly and daily outputs for the atmospheric, oceanic, land and sea-ice components, have been released on the Earth System Grid Federation(ESGF) node. These datasets contribute to PMIP4 and CMIP6(phase 6 of the Coupled Model Intercomparison Project) by providing the variables necessary for the two interglacial periods. In this paper, the basic information of the CAS-FGOALS models and the protocols for the two interglacials are briefly described, and the datasets are validated using proxy records. Results suggest that the CAS-FGOALS models capture the large-scale changes in the climate system in response to changes in solar insolation during the interglacial epochs, including warming in mid-to-high latitudes, changes in the hydrological cycle, the seasonal variation in the extent of sea ice, and the damping of interannual variabilities in the tropical Pacific. Meanwhile, disagreements within and between the models and the proxy data are also presented. These datasets will help the modeling and the proxy data communities with a better understanding of model performance and biases in paleoclimate simulations.     

Character and Causes of Population Distribution in Shenyang City, China

1 Introduction Research on the character of urban population distribu- tion is one of the focuses of western urban geography. From the 1950s, the research has attracted the attention of many western researchers, and a series of classical theoretical models were put forward. For example, Clark (1951) found that with the increase of distance from the city center, the urban population density tends to de- crease in exponential. Through the statistical analysis of more than 20 cities, he put forw…     

Formation process of mid-Neoproterozoic mafic rocks from the western Jiangnan Orogen,South China: insights from SHRIMP U–Pb dating and geochemical analysis

The mid-Neoproterozoic tectonic setting of the Jiangnan Orogen (JO) is uncertain due to the ongoing debate regarding the history of interactions between the Yangtze and Cathaysia Blocks. Extensive magmatic rocks with ages >830 Ma are observed in the eastern JO and are reported to indicate their formation conditions; however, such magmatic rocks are rare in the western JO. This paper presents data from samples collected from two ultramafic intrusions in northern Guangxi province that yield SHRIMP U–Pb ages of 848 ± 7 and 836 ± 5 Ma. These two intrusions have similar geochemical compositions; are enriched in LILE (Rb, Ba, Th, and Pb) relative to HFSE (Hf, Zr, Nb, Ta, and Y), reflecting an arc-like signature; and are derived from the same source. The intrusions have positive εNd(t) and εHf(t) values, implying a depleted mantle source. Comparing the Neoproterozoic mafic–ultramafic rocks of the JO, differences exist between the rocks that formed at 860–830, 830–800, and 800–740 Ma in terms of their mantle sources and formation conditions. Considering the geochemical composition and ages of formation of the strata and the deep structure of the western JO, we speculate that the western JO was a back-arc foreland basin, which experienced shallow subduction-related and arc-like magmatism during the period between 860 and 830 million years. In contrast to the western JO, the eastern JO may have been a back-arc basin with oceanic crustal basement during that time. The JO formed between 830 and 800 million years in association with subduction-related collisional magmatism due to the amalgamation of the Yangtze and Cathaysia Blocks. Subsequently, magmatism occurred in the JO that resulted from the post-orogenic extension.     

Late Mesozoic high-K calc-alkaline magmatism in Southeast China: the Tongling example

ABSTRACT

We report new zircon U–Pb ages, Hf isotopic and geochemical results for the Tongling granitic plutons of Southeast China. SHRIMP U–Pb ages for the Miaojia quartz monzodiorite porphyrite,the Tianebaodan and Tongguanshan quartz monzodiorites, the Xinqiaotou granodiorite porphyry, and the Shatanjiao and Nanhongchong granodiorite are 143 ± 2, 141 ± 1 and 142 ± 1, 147 ± 1, and 145 ± 1 and 139 ± 1 Ma, respectively. Combined with previous geochronological data, our results indicate that the porphyritic rocks are older than rocks of the same type lacking porphyritic texture. Geochemically, these high-K calc-alkaline intrusive rocks are characterized by arc-like trace element distribution patterns, with significant enrichment in LILE and LREE but depletion in HFSE. Lu–Hf isotopic compositions of zircons from the high-K calc-alkaline (HKCA) rocks have ε_Hf(t) values of magmatic 139–147 Ma zircons from ?8.1 to ?25.6, with two-stage model ages (t_DM2) of 1.71–2.67 Ga, whereas ε_Hf(t) values of inherited 582–844 Ma zircons range from 5.4 to ?9.5, with t_DM2 of 1.39–2.22 Ma, younger than t_DM2 values of igneous zircon, indicating that newly formed mantle material was added to the continental crust of the Yangtze Block. Moreover, ε_Hf(t) values of inherited zircon cores older than 1000 Ma are from ?7.8 to ?26, similar to magmatic zircons, and the t_DM2 values are all greater than 3.0 Ga (3.16–3.75 Ga), reflecting partial melting of ancient sialic material. We conclude that the plutonic melts were derived from both the enriched mantle and the ancient crust. The HKCA Tongling intrusions coincide temporally with the J₃–K₁ magmatic event that was widespread in Southeast China. This igneous activity may have accompanied sinistral slip along the Tan-Lu fault due to oblique subduction of the Palaeo-Pacific plate.     

U–Pb geochronology and Lu–Hf isotopes of zircons from newly identified Permian–Early Triassic plutons in western Liaoning province along the northern margin of the North China Craton: constraints on petrogenesis and tectonic setting

Mafic to felsic gneisses along the northern margin of the North China Craton (NMNCC), in western Liaoning province, China, were previously assumed to be part of Archean metamorphic basement but are here identified as younger (Permian–Early Triassic) intrusions. LA–ICP–MS zircon U–Pb isotopic dating reveals that the magmatic precursors of the mafic gneisses were emplaced from 295 ± 3 to 259 ± 2 Ma and that the magmatic precursors of the dioritic and monzogranitic gneisses were emplaced at 267 ± 1 and 251 ± 2 Ma, respectively, thus recording a continuum of Permian to Early Triassic magmatism. The mafic and dioritic rocks exhibit zircon ε_Hf(t) values from ?20.7 to ?3.3, suggesting they were mainly derived from a metasomatized lithospheric mantle source, possibly involving some crustal contamination. The monzogranitic rocks display their zircon ε_Hf(t) values of +0.9 to +4.7, indicating the acidic magma was derived from partial melting of juvenile crustal materials from the depleted mantle source. Crustal model ages (T _DM ^C ) obtained from zircon Hf isotopes of these monzogranitic rocks range from 976 to 1,215 Ma, with an average of 1,074 ± 32 Ma, possibly implying an episode of Grenvillian crustal growth in western Liaoning province. These new lines of evidence show that the NMNCC witnessed abundant magmatic activity and interaction of the crust and mantle during the Permian and Early Triassic and that the mafic magmatism was earlier than the monzogranitic activity. These findings indicate that the monzogranitic activity was the result of underplating of mafic magma with an enriched mantle source. In the context of regional Late Paleozoic to Early Mesozoic magmatic activity, the Permian magmatism occurred in an Andean-style continental margin setting when the Paleo-Asian oceanic plate was subducted beneath the NMNCC, and in this context, the Late Permian to Early Triassic magmatism may have been linked to post-collisional extension and asthenospheric upwelling, suggesting that the western Liaoning province in the NMNCC may be an eastward extension of the Late Paleozoic to Early Mesozoic active continental margin.     

长江中下游庐枞盆地火山岩的SHRIMP锆石U-Pb年龄：对扬子克拉通东部晚中生代岩石圈减薄机制的约束

庐枞盆地位于扬子克拉通的东北缘、大别-苏鲁印支期碰撞造山带的前陆地区、郯庐断裂与长江断裂带的交会处附近,构造位置独特。盆地内的中生代火山/潜火山岩以富碱和高钾为特征,地球化学上表现为富集Rb、Th、U、K等强不相容元素和轻稀土元素,属典型的橄榄玄粗岩系列,Sr-Nd同位素组成显示它们主要形成于陆下富集型岩石圈地幔的部分熔融。盆地内的火山岩按形成的先后分为龙门院组、砖桥组、双庙组和浮山组,各组之间有明显的喷发间断。本文用SHRIMP法测得4个组火山岩的锆石U-Pb年龄分别为131±1Ma、133±1Ma、130±1Ma和127±1Ma,年龄测试结果表明整个庐枞盆地内的火山岩是在很短的时间内(≤6Ma)形成的。结合整个长江中下游地区中生代火山活动的时间非常集中,意味着火山活动具有"突发性",指示机械拆沉可能是区内岩石圈减薄的主要机制。但庐枞盆地西北缘沙溪一带的侵入岩具埃达克质(adakitic),形成于加厚地壳的部分熔融,其侵位时间(≥136Ma)略早于盆地内橄榄玄粗质岩浆的活动时间,指示区内约133～136Ma时间段构造环境和动力学机制发生了重大转变。