Ore‐forming Ages and Sulfur Isotope Study of Hydrothermal Deposits in Kamchatka,Russia

In Kamchatka, Central Koryak, Central Kamchatka and East Kamchatka metallogenic belts are distributed from northwest to southeast. K–Ar age, sulfur isotopic composition of sulfide minerals, and bulk chemical compositions of ores were analyzed for 13 ore deposits including hydrothermal gold‐silver and base metal, in order to elucidate the geological time periods of ore formation, relationship to regional volcanic belts, type of mineralization, and origin of sulfur in sulfides. The dating yielded ore‐forming ages of 41 Ma for the Ametistovoe deposit in the Central Koryak, 17.1 Ma for the Zolotoe deposit and 6.9 Ma for the Aginskoe deposit in the Central Kamchatka, and 7.4 Ma for the Porozhistoe deposit and 5.1 Ma for the Vilyuchinskoe deposit in the East Kamchatka metallogenic belt. The data combined with previous data of ore‐forming ages indicate that the time periods of ore formation in these metallogenic belts become young towards the southeast. The averaged δ³⁴S_CDT of sulfides are ?2.8‰ for the Ametistovoe deposit in Central Koryak, ?1.8‰ to +2.0‰ (av. ?0.1‰) for the Zolotoe, Aginskoe, Baranievskoe and Ozernovskoe deposits in Central Kamchatka, and ?0.7 to +3.8‰ (av. +1.7‰) for Bolshe‐Bannoe, Kumroch, Vilyuchinskoe, Bystrinskoe, Asachinskoe, Rodnikovoe, and Mutnovskoe deposits in East Kamchatka. The negative δ³⁴S_CDT value from the Ametistovoe deposit in Central Koryak is ascribed to the contamination of ³²S‐enriched sedimentary sulfur in the Ukelayat‐Lesnaya River trough of basement rock. Comparison of the sulfur isotope compositions of the mineral deposits shows similarity between the Central Koryak and Magadan metallogenic belts, and East Kamchatka and Kuril Islands belts. The Central Kamchatka belt is intermediate between these two groups in term of sulfur isotopic composition.     

230Th/234U and 14C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.     

Forecasting the ionospheric f0F2 parameter one hour ahead using a support vector machine technique

This paper proposes a method for forecasting the ionospheric critical frequency, f₀F₂, 1 h in advance, using the support vector machine (SVM) approach. The inputs to the SVM network are the time of day, seasonal information, 2 month running mean sunspot number (R2), 3 day running mean of the 3 h planetary magnetic ap index, the solar zenith angle, the present value f₀F₂(t) and its first and second increments, the observation of f₀F₂ at t?23 h, the 30-day mean value at time, t, f_mF₂ (t) and the previous 30 day running mean of f₀F₂ at t?23 h f_mF₂(t?23). The output is the predicted f₀F₂ 1 h ahead. The network is trained to use the ionospheric sounding data at Haikou, Guangzhou, Chongqing, Lanzhou, Beijing, Changchun and Manzhouli stations at high and low solar activities. The performance of the SVM model was verified with observed data. It is shown that the predicted f₀F₂ has good agreement with the observed f₀F₂. The performance of the SVM model is superior to that of the autocorrelation and persistence models, and that it is comparable to that of the neural network model.     

Study of the effect of water-soluble fractions of heavy-oil on coastal marine organisms using enclosed ecosystems,mesocosms

Mesocosm facilities composed of 4 experimental and 2 reservoir tanks (1.5 m in diameter, 3.0 m in depth and 5 tons in capacity) made of FRP plastics, were constructed in the concrete fish rearing pond in the Fisheries Laboratory, The University of Tokyo. The water-soluble fraction of Rank A heavy residual oil was formed by mixing 500 g of the oil with 10 l of seawater, which was introduced to the 5000 l-capacity tanks. Experimental Run 4 was conducted from May 31 to June 7, 2000. Oil concentrations in the tanks were 4.5 microg/l called LOW, and 13.5 microg/l, called HIGH tank. Bacterial growth rates very quickly accelerated in the HIGH tank just after the loading of oil which corresponded with a high increase of bacterial cells in the same tank after 2 days. Later, bacterial numbers in HIGH tank rapidly decreased, corresponding with the rapid increase of heterotrophic nano-flagellates and virus numbers on the same day. Sediment traps were deployed at the bottom of the experimental tanks, and were periodically retrieved. These samples were observed both under light microscope and epi-fluorescent microscope with UV-excitation. It was observed that the main components of the vertical flux were amorphous suspended matter, mostly originating from dead phytoplankton and living diatoms. It was further observed from the pictures that vertical transport of oil emulsions were probably conducted after adsorption to amorphous suspended matter and living diatoms, and were settling in the sediment traps at the bottom of the tanks. This means that the main force which drives the soluble fraction of oil into bottom sediment would be vertical flux of such amorphous suspended particles and phytoplankton. Further incubation of the samples revealed that the oil emulsions were degraded by the activity of autochtonous bacteria in the sediment in aerobic condition.     

Decomposition of Polycyclic Aromatic Hydrocarbon （PAHs） on Mineral Surface under Controlled Relative Humidity

The fate of Polycyclic Aromatic Hydrocarbons （PAHs） residing in the atmosphere has received enormous attention in recent years due to their mutagenic and carcinogenic risks on human health. In this context, the stability of pyrene （as a representative PAHs） on quartz, alumina, montmorillonite, kaolinite, humic acid and quartz coated with sorbed humic acid was investigated at controlled relative humidity （RH： i.e. 5% and 30%） without light irradiation in order to detect the presence of catalytic effect of mineral surface on PAHs decomposition. The stability of pyrene was found to depend strongly on the physicochemical properties of the substrates. Quartz showed a strong catalytic effect for the decomposition of pyrene even though it was coated with sorbed humic acid. Pyrene sorbed on montmorillonite and humic acid remained stable during the experimental period （i.e. 3 days）. Moisture in the experimental cell also affected the stability of pyrene in particular minerals. Especially, pyrene sorbed on alumina was rapidly decomposed at higher RH. However, there were almost no effect in the case of quartz, kaolinite and humic acid. Depending on the physicochemical properties of aerosols and RH, PAHs associated with minerals in the atmosphere would be decomposed and/or stably reside in the atmosphere.     

Modelling Microbial Degradation Coupled to Reactive Transport in Groundwater: A Benchmark Analysis

Microbes are ubiquitous in groundwater systems, and they play an important role in the redox state of groundwater and especially on the fate of organic contaminants. In this context, numerical simulations that couple microbial processes to reactive transport models are becoming more popular. In the present work, we revisit the mathematical ground of microbial redox reactions and perform a benchmark analysis of the simulation of aerobic benzene degradation in a shallow and oxidizing aquifer. Numerical results indicate that the two codes tested (one using the finite elements approach and the other using the finite differences approach) lead to very similar results. In addition, the coupling of heterogeneous geochemical reactions to the benchmarked example problem provides a solid basis for the understanding of the redox reactions and the changes on the carbon system triggered by the aerobic degradation of benzene.     

A Challenge of Water Purification in Dokai Bay, Japan

A history of water pollution and countermeasures for water purification in Dokai Bay, Japan are reviewed. Now, Dokai Bay suffers from the occurrences of red tides and oxygen-deficiency in summer. In order to prevent the occurrences of red tides and oxygen-deficiency, an ecological numerical model has been developed. The model experiments forecast that when the phosphorus or nitrogen load from land will be cut by 90% or 95%, respectively, red tides and oxygen-deficiency will not occur in Dokai Bay. If the industrial and sewage facilities are not sufficient to cut the nutrients load to the necessary degree, we have to consider other countermeasures such as cultivating bivalves and algae in order to decrease the nutrients concentration in the bay. International co-operation related to coastal zone management is also discussed.     

Seismic velocity structure around the Hyuganada region, Southwest Japan, derived from seismic tomography using land and OBS data and its implications for interplate coupling and vertical crustal uplift

The Hyuganada region, a forearc region of Southwest Japan, is characterized by several interesting geological and geophysical features, i.e., significant aseismic crustal uplift of 120 m during the past 120 thousand years at the Miyazaki Plain, negative free-air gravity anomalies with the maximum magnitude of −130 mgal, and relatively less cohesive interplate coupling compared with that for off the Shikoku and Kii Peninsula. In order to examine the causes of these observations, we determined a detailed three-dimensional seismic velocity structure based on the seismic data observed by ocean bottom seismometers (OBS) and land stations. P- and S-wave tomographic velocity structures clearly indicate the subducting slab and also the zones of high Poisson's ratio at 25–35 km depth along the coastline of the northeastern part of the Hyuganada. The region with high Poisson's ratio may correspond to the serpentinized mantle wedge as suggested for other mantle wedges, and appears to be coincident with the zone for observed aseismic slips such as the slow-slip and after-slip events. Also, the detection may be related to a relatively weak interplate coupling in the Hyuganada region. The tomographic structures also indicate low velocity zones with a horizontal scale comparable to the Kyushu-Palau Ridge in and around the subducting slab. If we assume that the low velocity zones correspond to the subducted Kyushu-Palau Ridge, then the predicted gravity anomaly due to the density contrast between the low velocity zones and the surrounding region can explain about 60% of the gravity anomaly in the Hyuganada region. The buoyancy is probably an important factor for the crustal uplift observed in the Miyazaki Plain, the steep bending of the subducting slab and the normal fault-type earthquakes around the Hyuganada region.     

Control law for variable damping device defined by a non-linear differential equation

This paper proposes a non-linear control law for a variable damping device (VDD) aimed at reducing structural seismic responses. The VDD is attached to the structure by an auxiliary spring element composing a non-linear Maxwell element. The VDD's damping coefficient is adjusted to control the reactive internal force in the non-linear Maxwell element. A large controlled force is thus produced with little external power required to adjust the VDD's damping coefficient. The proposed control law defines the rate or increment of the VDD's damping coefficient at a certain moment by a differential equation or its discretized form. The controlled force vs. deformation relation plots parallelogram-like hysteretic curves, which indicates quick action and energy dissipation. Fundamental characteristics of an SDOF model with the VDD controlled by the proposed law are examined for impulse, sin and seismic excitations. The law for the SDOF model is extended to one for an MDOF model. The control effect for a 3DOF model is examined by numerical experiments. Copyright © 1999 John Wiley & Sons, Ltd.