The impact of northern Indian Ocean rivers on the Bay of Bengal using NEMO global ocean model

The effect of river runoff over the northern Indian Ocean(NIO) especially over the Bay of Bengal(Bo B) has been studied using global Nucleus for European Modelling of the Ocean(NEMO). Two sensitivity experiments, with and without river runoff are conducted and the influence of river runoff on the Indian Ocean hydrography,stratification and circulation features are studied. It is found that due to river runoff surface salinity over the northern Bo B decreases by more than 5 and the East India Coastal Current strengthens by 2 cm/s during post monsoon season. The fresh river water reaches up to 15°N in the Bo B and is the main cause for low salinity there.Sea surface temperature in the northwestern Bo B increases by more than 0.2℃ due to the river runoff in summer monsoon while surface cooling upto 0.2℃ is seen in north-west part of Bo B in winter season. The seasonal mixed layer depth in the region is found to be dependent on river runoff. The effect of vertical shear and Brunt Vaisala frequency on stratification is also examined. The ocean water becomes highly stratified up to 3 035 m due to the river runoff. It is found that the energy required for mixing is high in the northern and coastal Bo B.     

Geographical information system-based groundwater quality index assessment of northern part of Kolkata,India for drinking purpose

Groundwater is a resource under stress. In both developed and developing countries, it has been found that increasing human influence has led to the contamination of the groundwater resource. To understand the magnitude of this problem, a study was conducted in 58 wards within Northern part of Kolkata, India, where water samples from tube wells were collected and analysed on essential drinking water quality parameters, prescribed by WHO. Using Principal component analysis, and Water quality index mapping, the aforementioned results have been interpreted. This has helped to depict that not only is the groundwater unsuitable for drinking, but that the parametric values have a tendency to increase abruptly within the shortest of ranges, indicating urban pollution as the root cause of contamination. This paper shall thus discuss the spatial change in groundwater quality in northern Kolkata and suggest measures which might be implemented to secure a sustainable future for the city.     

Estimation of Partial Pressure of Carbon Dioxide and Air-Sea Fluxes in Hooghly Estuary Based on In Situ and Satellite Observations

An empirical model is developed and used with remotely sensed predictors: sea surface temperature (SST) and chlorophyll-a concentration (Chl-a), to compute surface water partial pressure of carbon dioxide (pCO_2w) and air-sea fluxes of CO₂ in the Hooghly estuary and its adjacent coastal oceans. In situ observations used here were based on measurements carried out in this region during winter and summer periods in 2008. The estimated pCO_2w compares well with the in situ observations at root mean square error ±18 μatm. In winter, estimated pCO_2w ranges between 320 and 500 μatm with large values (>400 μatm) on the south-western and south-eastern flanks of the coastal domain and lower values (340–375 μatm) on the main-channel. In summer, it remained spatially uniform at 450 μatm. Extrapolation of the results over the study region based on the Moderate Imaging Specroradiometer (MODIS) measured SST and Chl-a suggests that the region is a strong source of atmospheric CO₂ during the summer with net release of 0.095 Tg C year^?1 (equivalent to mean flux of 90 molC m^?2 year^?1) and is a weak source during the winter with net release of 0.006 Tg C yr^?1 (0.5 molC m^?2 year^?1) from the geographical extent of 6000 Km² area.     

On the scavenging of SO2 by cloud and raindrops: II. An experimental study of SO2 absorption and desorption for water drops in air

For the purpose of testing our previously described theory of SO₂ scavenging a laboratory investigation was carried out in the UCLA 33 m long rainshaft. Drops with radii between 250 and 2500 m were allowed to come to terminal velocity, after which they passed through a chamber of variable length filled with various SO₂ concentrations in air. After falling through a gas separating chamber consisting of a fluorocarbon gas the drops were collected and analyzed for their total S content in order to determine the rate of SO ₂ absorption.The SO₂ concentration in air studied ranged between 1 and 60% (v). Such relatively large concentrations were necessary due to the short times the drops were exposed to SO₂ in the present setup. The present experimental results were therefore not used to simulate atmospheric conditions but rather to test our previously derived theory which is applicable to any laboratory or atmospheric condition. Comparison of our studies with the results from our theory applied to our laboratory conditions led to predicted values for the S concentration in the drops which agreed well with those observed if the drops had radii smaller than 500 m. In order to obtain agreement between predicted and observed S concentrations in larger drops, an empirically derived eddy diffusivity for SO₂ in water had to be included in the theory to take into account the effect of turbulent mixing inside such large drops.In a subsequent set of experiments, drops initially saturated with S (IV) were allowed to fall through S-free air to determine the rate of SO ₂ desorption. The results of these studies also agreed well with the results of our theoretical model, thus justifying the reversibility assumption made in our theoretical models.In a final set of experiments, the effects of oxidation on SO₂ absorption was studied by means of drops containing various amounts of H₂O₂. For comparable exposure times to SO₂, the S concentration in drops with H₂O₂ was found to be up to 10 times higher than the concentration in drops in which no oxidation occurred.     

The lesser Himalayan Duplex in Sikkim: Implications for variations in Himalayan shortening

Thrust duplexes account for large fractions of the total shortening in most fold-thrust belts (FTBs). They also provide an efficient mechanism for transferring slip upward from the basal decollement and for transporting roof thrust sheets over long distances. The Lesser Himalayan duplex (LHD) plays a prominent role in the overall evolution of the Himalayan FTB and has been described from Garhwal-Kumaon to Bhutan. In Sikkim the LHD shows unique structural geometry and has been responsible for transporting crystalline thrust sheets (MCT 1 and MCT 2) farther southward than other parts of the Himalaya. Such lateral variations in LHD geometry imply variations in the kinematic history of the Lesser Himalaya and variations in shortening and shortening history along the length of the Himalayan arc, and these are reflected in observable large scale structural patterns.     

Influence of forest fire episodes on the distribution of gaseous air pollutants over Uttarakhand,India

ABSTRACT

Widespread forest fire events occurred in the foothills of North Western Himalaya during 24 April to 2 May 2016 (Event-1) and 20–30 May 2018 (Event-2). Their impacts were investigated on the distribution of pollutant gases ozone (O₃), carbon monoxide (CO), and oxides of nitrogen (NOx) over Uttarakhand using simulations of Weather Research and Forecasting model coupled with chemistry (WRF-Chem) and in-situ observations of these gases over Dehradun, the capital of Uttarakhand. During Event-1, the observed CO mixing ratio over Dehradun increased from 25 April 2016 onwards, attained maximum (705.8 ± 258 ppbv) on 2 May 2016 and subsequently decreased. The rate of increase of daily baseline CO was 29 ppbv/day during HFAP (High Fire Activity Period). During Event-2, daily average concentrations of CO, O₃, and NOx showed systematic increase over Dehradun during HFAP period. The rate of increase of CO was 9 ppbv/day, while it was very small for NOx and O₃. To quantitatively estimate the influence of forest fire emissions, two WRF-Chem simulations were made: one with biomass burning (BB) emissions and other without BB emissions. These simulations showed 52% (34%) enhancement in CO, 52% (32%) enhancement in NOx, and 11% (9%) enhancement in O₃ during HFAP for Event-1 (Event-2). A clear positive correlation (r = 0.89 for Event-1, r = 0.69 for Event-2) was found between ?O₃ (O_{3with BB} minus O_{3without BB}) and ?CO (CO_{with BB} minus CO_{without BB}), indicating rapid production of ozone in the fire plumes. For both the events, the vertical distribution of ?O₃, ?CO, and ?NOx showed that forest fire emissions influenced the air quality upto 6.5 km altitude. Peaks in ?O₃, ?CO, and ?NOx during different days suggested the role of varying dispersion and horizontal mixing of fire plumes.     

P–T–fO2 controls on a partly inverse chromite-bearing ultramafic intrusive: an evaluation from the Sukinda Massif, India

The chromites from the alpine type ultramafic intrusive of Sukinda, India, display a typical partly inverse spinel form and occur in two distinct zones: Brown Ore Zone (BOZ) and Grey Ore Zone (GOZ). The host ultramafites are mostly altered and are represented by the serpentinite, tremolite-talc(chlorite) schist, talc-serpentine schist and chlorite rock. The less altered variants are dunite, harzburgite and websterite. A dyke of orthopyroxenite runs through the main ultramafic body.The composition of olivine (Fo₉₂), orthopyroxene (En_92–89) and Al₂O₃ contents of the parental liquid (10.40–11.45%) determined from chromites, suggest that the parent melt is of boninitic affinity. The chemical plot of TiO₂ content against cr# of chromites corroborates a boninitic parental melt. The Fe–Mg partitioning in olivine and chromite depicts the temperature for chromitites as 1200 °C. A compositional plot of mg# and cr# suggests crystallization at high pressure conditions, corresponding to the kimberlite xenolith field. From the P–T diagram of pyrolite melting and mineral assemblage, the pressure of crystallization is stipulated to be ≥1.2 GPa. The f_O2 values estimated from Fe³⁺/Cr+Al+Fe³⁺ ratios range from 10^−8.3 to 10^−9.3 for the GOZ and 10^−7.1 to 10^−7.3 for the BOZ. The f_O2 values together with the pressure range suggest crystallization at upper mantle conditions. The heterogeneity in chemical composition and f_O2 conditions for the GOZ and BOZ could be linked to heterogeneity in the upper mantle.     

Solubility and dissolution rate of silica in acid fluoride solutions

We performed 57 batch reactor experiments in acidic fluoride solutions to measure the dissolution rate of quartz. These rate data along with rate data from published studies were fit using multiple linear regression to produce the following non-unique rate law for quartz

where 10^−5.13 < a_HF < 10^1.60, −0.28 < pH < 7.18, and 298 < T < 373 K. Similarly, 97 amorphous silica dissolution rate data from published studies were fit by multiple linear regression to produce the following non-unique rate law for amorphous silica

where 10^−2.37 < a_HF < 10^1.61, −0.32 < pH < 4.76 and 296 < T < 343 K. Regression of the rates versus other combinations of solution species, e.g.  + H⁺, F⁻ + H⁺, HF + , HF + F⁻, or  + F⁻, produced equally good fits. Any of these rate laws can be interpreted to mean that the rate-determining step for silica dissolution in fluoride solutions involves a coordinated attack of a Lewis acid, on the bridging O atom and a Lewis base on the Si atom. This allows a redistribution of electrons from the Si–O bond to form a O–H group and a Si–FH group.     

On the scavenging of gaseous nitrogen compounds by large and small rain drops I. A wind tunnel and theoretical study of the uptake and desorption of NH3 in the presence of CO2

An experimental study has been carried out in the Mainz vertical wind tunnel to determine the rate at which NH₃ in the presence of CO₂ is absorbed by freely suspended water drops. The experimental uptake rates were found to be in good agreement with the rates predicted by the Kronig-Brink convective diffusion model and, for gas concentrations in the ppbv range also by the model in which it is assumed that the absorbed gas is well mixed inside the drop (henceforth called well mixed model). The same conclusion was shown to apply also to the desorption of NH₃ from a drop previously exposed to NH₃. The latter result is in contrast to the desorption of SO₂ which must be described by a model which accounts for the diffusion of the species inside the drop. Comparison of our experimental results with theory show further that the uptake of NH₃ in presence of CO₂ is significantly overestimated if the slow reaction CO_2(aq)+H₂OHCO ₃ ^– +H⁺ is neglected in the theoretical computation.     

Exact solution of the source problem for a finite threedimensional source

Summary In this note the surface displacement for an elastic half-space due to a finite cylindrical source has been calculated in exact terms. The source consists of outward body forces acting on the surface of the right circular cylinder, one end of which is parallel to the free surface of the half-space.