Crude-oil hydrocarbon composition characteristics and oil viscosity prediction in the northern Songliao Basin

Crude oil hydrocarbon composition characteristics and oil viscosity prediction are important bases in petroleum exploration.A total of 54 oil/heavy-oil samples and 17 oil sands were analyzed and quantified using both comprehensive 2D gas chromatography(GC×GC)and comprehensive 2D gas chromatography/time-of-flight mass spectrometry(GC×GC/TOFMS).The results show that crude oil in the West slope is mainly heavy oil and its hydrocarbon composition is characterized overall by paraffinsmono-aromaticsnaphthenesnon-hydrocarbonsdi-aromaticstri-aromaticstetra-aromatics.Aromatics are most abundant and non-hydrocarbons are least abundant,whilst content differences among paraffins,naphthenes,aromatics,and non-hydrocarbons are less than 15%.There are two types of heavy oil,secondary type and mixing type.Biodegradation is the main formation mechanism of heavy oil.Biodegradation levels cover light biodegradation,moderate biodegradation,and severe biodegradation.With increasing biodegradation,paraffin content decreases while contents of aromatics and nonhydrocarbons increase.In contrast,naphthene content increases first and then decreases with increasing biodegradation.In severe biodegradation stage,naphthenes decrease more quickly than aromatics and non-hydrocarbons.This provides a new method for studying oil/heavy-oil biodegradation mechanism and biodegradation resistance of different hydrocarbons at different biodegradation stages.In the Longhupao-Daan terrace and Qijia-Gulong depression,most crude oil is conventional oil.Its composition is dominated by paraffins with the lowest content of aromatics.In some casual oil wells from the Longhupao-Daan terrace,crude oil from Saertu oil reservoirs is moderately biodegraded whereas crude oil from Putaohua oil reservoir is lightly biodegraded.Chemical parameters using saturate hydrocarbons and aromatics are usually not suitable for determining organic type and thermal maturity of biodegraded oil,especially of moderately or severely biodegraded oil,whilst Ts/(Ts+Tm)ratio can be used to determine thermal maturity of both conventional crude oil and heavy oil.     

顺煤层断层的基本特征及其地质意义

顺煤层断层是指顺煤层发育的断面与煤层层面的交角较小或近于平行的断层。它的主要识别标志是断层面、构造煤和煤层厚度的强烈变化。顺煤层断层可独立存在，也可与其它地质构造相互转换，相伴出现。顺煤层断层具有特殊的选层性，这一特征与煤体较低的力学强度、煤层瓦斯压力及形变期顺煤层的剪切作用有关。顺煤层断层在煤田中分布广泛，它所产生的构造煤是瓦斯高聚集区，亦是瓦斯突出的危险区，其研究意义重大。     

2009年初开封市冬小麦大面积干枯死亡原因分析

2009年1-2月,开封市冬小麦出现大面积的枯黄,甚至死亡现象,对2009年全市夏粮总产量和全年粮食总产量的稳定构成了严重的威胁.对麦田实地调查及对麦播以来开封市气候特征分析结果表明,造成2009年初开封市冬小麦出现大面积枯黄死亡的原因主要有以下几个方面:一是小麦播种以后开封市长期干旱少雨,麦田旱情严重,直接影响到冬小麦正常生长;二是2008年12月下旬开封市出现大范围强降温天气,最低气温锐降至-10 ℃以下,全市冬小麦不同程度受冻;三是农户冬季麦田管理措施不到位,普遍未浇越冬水;四是小麦品种选择不当,部分品种抗逆性较差;五是地下害虫危害较为严重;另外还与本地的小麦耕种方式有一定联系.要减少不利因素对冬小麦生长的影响,就要加强对气候变化的认识,及时采取必要的农业技术措施,提高防灾减灾能力,及时关注天气变化,科学合理适时冬灌,加强田间管理,严防冻害发生;加强病虫害的预测预报;科学做好秸秆还田工作.     

农业重大气象灾害监测预警与控制技术研究

1.北方农业低温冷害监测预警技术研究 "北方农业低温冷害监测预警技术研究"2007年在以下4个方面取得了较显著的进展.     

Three-dimensional analysis of ozone and PM<Subscript>2.5</Subscript> distributions obtained by observations of tethered balloon and unmanned aerial vehicle in Shanghai,China

A lightweight unmanned aerial vehicle (UAV) and a tethered balloon platform were jointly used to investigate three-dimensional distributions of ozone and PM_2.5 concentrations within the lower troposphere (1000 m) at a localized coastal area in Shanghai, China. Eight tethered balloon soundings and three UAV flights were conducted on May 25, 2016. Generalized additive models (GAMs) were used to quantitatively describe the relationships between air pollutants and other obtained parameters. Field observations showed that large variations were captured both in the vertical and horizontal distributions of ozone and PM_2.5 concentrations. Significant stratified layers of ozone and PM_2.5 concentrations as well as wind directions were observed throughout the day. Estimated bulk Richardson numbers indicate that the vertical mixing of air masses within the lower troposphere were heavily suppressed throughout the day, leading to much higher concentrations of ozone and PM_2.5 in the planetary boundary layer (PBL). The NO and NO₂ concentrations in the experimental field were much lower than that in the urban area of Shanghai and demonstrated totally different vertical distribution patterns from that of ozone and PM_2.5. This indicates that aged air masses of different sources were transported to the experimental field at different heights. Results derived from the GAMs showed that the aggregate impact of the selected variables for the vertical variations can explain 94.3% of the variance in ozone and 94.5% in PM_2.5. Air temperature, relative humidity and atmospheric pressure had the strongest effects on the variations of ozone and PM_2.5. As for the horizontal variations, the GAMs can explain 56.3% of the variance in ozone and 57.6% in PM_2.5. The strongest effect on ozone was related to air temperature, while PM_2.5 was related to relative humidity. The output of GAMs also implied that fine aerosol particles were in the stage of growth in the experimental field, which is different from ozone (aged air parcels of ozone). Geographical parameters influenced the horizontal variations of ozone and PM_2.5 concentrations by changing underlying surface types. The differences of thermodynamic properties between land and sea resulted in quick changes of PBL height, air temperature and dew point over the coastal area, which was linked to the extent of vertical mixing at different locations. The results of GAMs can be used to analyze the sources and formation mechanisms of ozone and PM_2.5 pollutions at a localized area.     

极地记录冰川和达尔克冰川流速的遥感监测研究

测定南极冰川的流速 ,对于研究南极冰雪物质平衡、南极环境变化及其对全球环境的影响有重大意义。本文论述了利用多时相卫星遥感影像监测冰川变化的原理和方法 ,通过对英格里特 .克里斯泰森海岸不同时期的遥感影像进行几何纠正和配准及叠加处理 ,测量和计算出极地记录冰川和达尔克冰川的平均流速 ,并对它们的变化特点进行了初步的分析和评价。     

Metallogenic and Metamorphic Age of the Hongtoushan Copper–Zinc Massive Sulfide Deposit,Liaoning Province,China

The Hongtoushan copper–zinc deposit is the only large Archean volcanogenic massive sulfide (VMS) deposit in China. This paper presents new information on the timing of metallogenesis and metamorphism of the deposit, including new cathodoluminescence (CL) images, and Th U^?1 and LA–ICP–MS U–Pb dating on zircons of the biotite–plagioclase gneiss and plagioclase–amphibole gneiss that host the deposit. The CL images and Th U^?1 ratios indicate that the zircons within the gneiss are of metamorphic origin. LA–ICP–MS dating of the plagioclase–amphibole gneiss yielded the upper intercept ages of 2549 Ma, and the biotite–plagioclase gneiss yielded the upper intercept ages of 2552 Ma and 2550 Ma correspondingly, indicating that the mineralization of the deposit occurred at around 2550 Ma. The rims of zircons within these host rocks yielded younger U–Pb ages at 2529, 2520 and 2515 Ma, identical to the age of felsic intrusive rocks in the study area. This suggests that the Hongtoushan VMS deposit underwent initial metamorphism and deformation at around 2520 Ma by the intrusion of granite magmas.     

基于岩石物理模型的页岩孔隙结构反演及横波速度预测

准确预测储层的等效孔隙纵横比对页岩储层岩石物理建模及横波速度预测具有重要意义。为分析页岩储层孔隙纵横比及预测横波速度,提出了基于岩石物理模型的页岩孔隙纵横比反演及横波速度预测方法。本文首先通过岩石物理模型建立岩石的纵、横波速度与孔隙纵横比、孔隙度和矿物组分等参数之间的定量关系,寻找最佳孔隙纵横比;然后通过使理论预测与实际测量的纵波速度之间误差达到最小的方式反演孔隙纵横比,并以此为约束预测横波速度。实际测井数据反演结果表明,龙马溪组页岩地层的孔隙纵横比稳定,而围岩的孔隙纵横比变化范围较大;说明与围岩相比,页岩的孔隙结构更为稳定。同时,预测得到的页岩横波速度与实测横波速度的误差较小,另外对于缺少矿物组分资料的页岩层段,用平均矿物组分预测得到的横波速度误差仍较小;说明与矿物组分相比,龙马溪组页岩的纵、横波速度对孔隙纵横比参数更敏感。综上所述,利用该方法可预测到较为准确的等效孔隙纵横比和横波速度。     

The role of anthropogenic activities in karst spring discharge volatility

The traditional hydrological time series methods tend to focus on the mean of whichever variable is analysed but neglect its time‐varying variance (i.e. assuming the variance remains constant). The variances of hydrological time series vary with time under anthropogenic influence. There is evidence that extensive well drilling and groundwater pumping can intercept groundwater run‐off and consequently induce spring discharge volatility or variance varying with time (i.e. heteroskedasticity). To investigate the time‐varying variance or heteroskedasticity of spring discharge, this paper presents a seasonal autoregressive integrated moving average with general autoregressive conditional heteroskedasticity (SARIMA‐GARCH) model, whose the SARIMA model is used to estimate the mean of hydrological time series, and the GARCH model estimates its time‐varying variance. The SARIMA‐GARCH model was then applied to the Xin'an Springs Basin, China, where extensive groundwater development has occurred since 1978 (e.g. the average annual groundwater pumping rates were less than 0.20 m³/s in the 1970s, reached 1.20 m³/s at the end of the 1980s, surpassed 2.0 m³/s in the 1990s and exceeded 3.0 m³/s by 2007). To identify whether human activities or natural stressors caused the heteroskedasticity of Xin'an Springs discharge, we segmented the spring discharge sequence into two periods: a predevelopment stage (i.e. 1956–1977) and a developed stage (i.e. 1978–2012), and set up the SARIMA‐GARCH model for the two stages, respectively. By comparing the models, we detected the role of human activities in spring discharge volatility. The results showed that human activities caused the heteroskedasticity of the Xin'an Spring discharge. The predicted Xin'an Springs discharge by the SARIMA‐GARCH model showed that the mean monthly spring discharge is predicted to continue to decline to 0.93 m³/s in 2013, 0.67 m³/s in 2014 and 0.73 m³/s in 2015. Copyright © 2014 John Wiley & Sons, Ltd.     

冀北侏罗系上统火山岩中宇宙尘的发现及其地质意义

在冀北丰宁、沽源、赤城一带的上侏罗统火山岩中发现有不同形态的铁质及玻璃质微球粒。经电镜扫描及外貌结构构造的鉴定，显示有熔融、碰撞、逸气、旋纹、冷疑、收缩等特征；经电子探针及Ｘ射线粉晶衍射分析，认为是宇宙尘。对其进行研究不仅有重要的地质意义，而且有找矿意义。