Mercury dynamic simulation of Minamata Bay by using a three-dimensional numerical model

Ocean Dynamics - Residual mercury dynamic has been the research emphasis since mercury contamination was publicly recognized in Minamata Bay. Simulation of mercury distribution and transport...     

Anthropogenic Pb in settling particulate matter in the Northwestern Pacific examined using stable isotopes of Pb

We have investigated Pb concentrations and isotopic compositions in settling particles collected by sediment traps experiments over a period of two years, from May 2005 to April 2007, at two depths, 770 and 5100 m, at station KNOT in the Northwestern Pacific Ocean (44°N, 155°E). To the identify provenances of Pb, the samples were separated into two fractions by chemical leaching techniques, with the leachate expected to contain Pb of anthropogenic origin. Isotopic compositions of Pb and concentrations of Pb, Sc, Mn, La, Yb, and Th were measured by quadrupole ICP-MS. The isotope ratios of leachable Pb in settling particles were ²⁰⁷Pb/²⁰⁶Pb = 0.860 ± 0.001; ²⁰⁸Pb/²⁰⁶Pb = 2.116 ± 0.002 (mean ± 95% confidence intervals), which are similar to those of aerosols in China that are greatly affected by pollution from coal combustion. We estimated the mean contribution from anthropogenic Pb sources to the Pb in settling particles, using the conventional binary (anthropogenic and natural Pb) mixing equation for Pb isotopes, as 90% in the upper trap and 78% in the lower trap. Furthermore, we found a significant negative correlation between the isotope ratios of Pb and concentrations of leachable Mn, normalized to those of leachable Pb, suggesting that manganese oxides play an important role in transporting Pb from the upper layers of the ocean to the deeper layers. Our results support the speculation published in a previous study that Pb might be scavenged by Mn oxides in the Northwestern Pacific Ocean.     

Laboratory measurements of guided‐wave propagation within a fluid‐saturated fracture

A fluid‐saturated flat channel between solids, such as a fracture, is known to support guided waves—sometimes called Krauklis waves. At low frequencies, Krauklis waves can have very low velocity and large attenuation and are very dispersive. Because they propagate primarily within the fluid channel formed by a fracture, Krauklis waves can potentially be used for geological fracture characterization in the field. Using an analogue fracture consisting of a pair of flat slender plates with a mediating fluid layer—a trilayer model—we conducted laboratory measurements of the velocity and attenuation of Krauklis waves. Unlike previous experiments using ultrasonic waves, these experiments used frequencies well below 1 kHz, resulting in extremely low velocity and large attenuation of the waves. The mechanical compliance of the fracture was varied by modifying the stiffness of the fluid seal of the physical fracture model, and proppant (fracture‐filling high‐permeability sand) was also introduced into the fracture to examine its impact on wave propagation. A theoretical frequency equation for the trilayer model was derived using the poroelastic linear‐slip interface model, and its solutions were compared to the experimental results.     

Economic consequences of global climate change and mitigation on future hydropower generation

Hydropower generation plays a key role in mitigating GHG emissions from the overall power supply. Although the maximum achievable hydropower generation (MAHG) will be affected by climate change, it is seldom incorporated in integrated assessment models. In this study, we first used the H08 global hydrological model to project MAHG under two physical climate change scenarios. Then, we used the Asia-Pacific Integrated Model/Computable General Equilibrium integrated assessment model to quantify the economic consequences of the presence or absence of mitigation policy on hydropower generation. This approach enabled us to quantify the physical impacts of climate change and the effect of mitigation policy—together and in isolation—on hydropower generation and the economy, both globally and regionally. Although there was little overall global change, we observed substantial differences among regions in the MAHG average change (from ??71% in Middle East to 14% in Former Soviet Union in RCP8.5). We found that the magnitude of changes in regional gross domestic product (GDP) was small negative (positive) in Brazil (Canada) by 2100, for the no mitigation policy scenario. These consequences were intensified with the implementation of mitigation policies that enhanced the price competitiveness of hydropower against fossil fuel-powered technologies. Overall, our results suggested that there would be no notable globally aggregated impacts on GDP by 2100 because the positive effects in some regions were canceled out by negative effects in other regions.     

Relationship between Composition of Settling Particles and Organic Carbon Flux in the Western North Pacific and the Japan Sea

Settling particles play an important role in transporting organic carbon from the surface to the deep ocean. It is known that major components of settling particles are biogenic silicates (opal), biogenic carbonate (CaCO₃), lithogenic clays and organic matter. Since each component aggregates and/or takes in organic carbon, all of these components have the ability to transport particulate organic carbon (POC) to the interior of the ocean. In this study, sediment trap experiments were carried out in four areas of the western North Pacific (including a marginal sea). Factors are proposed that correlate the composition of settling particles with POC flux. Annual mean organic carbon fluxes at 1 km depth in the western North Pacific Basin, Japan Sea, Hidaka Basin and northern Japan Trench were found to be 14.9, 18.1, 13.0 and 6.6 mg/m²/day, respectively. Organic carbon flux in the western North Pacific was greater than that in the Eastern North Pacific (7.4), the Equatorial Pacific (4.2), the Southern Ocean (5.8) and the Eastern North Atlantic (1.8). In the western North Pacific, it was calculated that 52% of POC was carried by opal particles. Opal is known to be a major component even in the Eastern North Pacific and the Southern Ocean, and the opal fluxes in these areas are similar to those in the western North Pacific. However, the organic carbon flux that was carried by opal particles (OC_opalflux) in the western North Pacific was greater than that in the Eastern North Pacific and the Southern Ocean. These results indicate that the ability of opal particles to transport POC to the deep ocean in the western North Pacific is greater than that in the other areas.     

Deep sea circulation of particulate organic carbon in the Japan Sea

Seasonal and spatial variations of particulate organic carbon (POC) flux were observed with sediment traps at three sites in the Japan Sea (western and eastern Japan Basin and Yamato Basin). In order to investigate the transport processes of POC, radiocarbon (¹⁴C) measurements were also carried out. Annual mean POC flux at 1 km depth was 30.7 mg m⁻²day⁻¹ in the western Japan Basin, 12.0 mg m⁻²day⁻¹ in the eastern Japan Basin and 23.8 mg m⁻²day⁻¹ in the Yamato Basin. At all stations, notably higher POC flux was observed in spring (March–May), indicating biological production and rapid sinking of POC in this season. Sinking POC in the high flux season showed modern Δ¹⁴C values (>0‰) and aged POC (Δ¹⁴C < −40‰) was observed in winter (December–January). The Δ¹⁴C values in sinking POC were negatively correlated with aluminum concentration, indicating that Δ¹⁴C is strongly related to the lateral supply of lithogenic materials. The Δ¹⁴C values also showed correlations with excess manganese (Mn_xs) concentrations in sinking particles. The Δ¹⁴C-Mn_xs relationship suggested that (1) the majority of the aged POC was advected by bottom currents and incorporated into sinking particles, and (2) some of the aged POC might be supplied from the sea surface at the trap site as part of terrestrial POC. From the difference in the Δ¹⁴C-Mn_xs relationships between the Japan Basin and the Yamato Basin, we consider that basin-scale transport processes of POC occur in the Japan Sea.