Strategy of photo-protection in phytoplankton assemblages in the Kongsfjorden,Svalbard, Arctic

Photo-protective functions were investigated in phytoplankton assemblages at Kongsfjorden, Svalbard in spring, using their UV-absorbing compounds (mycosporine-like amino acids (MAAs)), xanthophyll pigments (diadinoxanthin (DD) and diatoxanthin (DT)) and < beta >- dimethylsulphoniopropionate (< beta >_-DMSP). The dominant phytoplankton species in the inner bay were dominated by Phaeocystis spp. and nanoflagellates, while the offshore waters were dominated by Thalassiosira spp. In the inner bay, UVabsorbing compounds and xanthophyll pigments exhibited higher ratios of MAA to chlorophyll a (MAA:chl a ratio), and both DD and DT to chlorophyll a (DD:chl a ratio and DT:chl a ratio), respectively. Thus, the photoprotective-pigments such as DD and DT appear to complement MAAs in the natural phytoplankton assemblage. However, the ratio of < beta >_-DMSP to chlorophyll a (< beta >_-DMSP:chl a ratio) did not show a distinct spatial distribution according to environmental factors or interspecies differences. In this study, we found that photoprotective compounds occurred in a manner dependent on the phytoplankton species composition in Kongsfjorden Bay, where Phaeocystis is the dominant species.     

Composition of barian mica in multiphase solid inclusions from orogenic garnet peridotites as evidence of mantle metasomatism in a subduction zone setting

Multiphase solid inclusions in minerals formed at ultra-high-pressure (UHP) provide evidence for the presence of fluids during deep subduction. This study focuses on barian mica, which is a common phase in multiphase solid inclusions enclosed in garnet from mantle-derived UHP garnet peridotites in the Saxothuringian basement of the northern Bohemian Massif. The documented compositional variability and substitution trends provide constraints on crystallization medium of the barian mica and allow making inferences on its source. Barian mica in the multiphase solid inclusions belongs to trioctahedral micas and represents a solid solution of phlogopite KMg₃(Si₃Al)O₁₀(OH)₂, kinoshitalite BaMg₃(Al₂Si₂)O₁₀(OH)₂ and ferrokinoshitalite BaFe₃(Al₂Si₂)O₁₀(OH)₂. In addition to Ba (0.24–0.67 apfu), mica is significantly enriched in Mg (X_Mg ~ 0.85 to 0.95), Cr (0.03–0.43 apfu) and Cl (0.04–0.34 apfu). The substitution vector involving Ba in the I-site which describes the observed chemical variability can be expressed as BaFe^IVAlClK_?1Mg_?1Si_?1(OH)_?1. A minor amount of Cr and ^VIAl enters octahedral sites following a substitution vector ^VI(Cr,Al)₂□^VI(Mg,Fe)_?3 towards chromphyllite and muscovite. As demonstrated by variable Ba and Cl contents positively correlating with Fe, barian mica composition is partly controlled by its crystal structure. Textural evidence shows that barian mica, together with other minerals in multiphase solid inclusions, crystallized from fluids trapped during garnet growth. The unusual chemical composition of mica reflects the mixing of two distinct sources: (1) an internal source, i.e. the host peridotite and its garnet, providing Mg, Fe, Al, Cr, and (2) an external source, represented by crustal-derived subduction-zone fluids supplying Ba, K and Cl. At UHP–UHT conditions recorded by the associated diamond-bearing metasediments (c. 1100 °C and 4.5 GPa) located above the second critical point in the pelitic system, the produced subduction-zone fluids transporting the elements into the overlying mantle wedge had a solute-rich composition with properties of a hydrous melt. The occurrence of barian mica with a specific chemistry in barium-poor mantle rocks demonstrates the importance of its thorough chemical characterization.     

Effects of flexibility on propulsive force acting on a heaving foil

The hybrid Cartesian/immersed boundary method is applied to simulate effects of flexibility on propulsive force acting on a heaving foil in a viscous flow. Immersed boundary nodes are distributed inside an instantaneous fluid domain. Velocity vector is reconstructed at the immersed boundary node based on an interpolation along a local normal line. Using the staggered/non-staggered grid method, the demand for pressure at boundary nodes is removed. Elastic deformation of the flexible foil is modelled based on the dynamic thin-plate mechanics. The developed code is validated through comparisons with other computations on flow fields around a flapping foil. The generation of the reverse Karman vortex street is investigated. Forces acting on heaving foils are compared for flexible and rigid cases and the increased thrust of the flexible foil is attributed to the deformed configuration near the tip. The flexibility of the heaving foil decreases vertical force and improves propulsion efficiency. The variations of force and deformation are investigated according to bending stiffness of the foil.     

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.     

Early deformation fabrics of melange in the Mesozoic Waipapa Terrane, North Island, New Zealand

Abstract The Waipapa Terrane in northern North Island, New Zealand, is a Mesozoic accretion-ary complex formed along the Gondwana margin. It contains abundant melange rocks with distinctive characteristics. Precise analyses of their mesoscopic fabrics in Waiheke Island near Auckland have revealed the following sequence of deformation. The earliest phase of deformation of the sandstone/mudstone association, which is the main constituent of this terrane, originated by chaotic mixing of sand and mud due to liquidization of water-saturated, poorly consolidated sediments. The second phase was characterized by hydrofracturing and subsequent forceful injection of ductile mud into rather brittle sand. Local intrusions of sand forming dykes and sills followed these events, as well as intrusions of pelagic/hemipelagic green argillite originally underlying the sandstone/mudstone association. An abundant occurrence of these mixing and multi-stage injection/intrusion fabrics strongly suggest that the Waipapa Terrane around the study area was a site of high pore-fluid pressure. Scaly-foliated melange fabrics with monoclinic symmetry, originating from layer-parallel shearing, were then locally superimposed on the pre-existing melange fabrics. Similar scaly-foliated fabrics also developed in the chert beds originally intercalated between the green argillite and the uppermost part of the oceanic crust. These scaly fabrics might have been related to the regional stacking and juxtaposition of the accreted sediments. The sequence and variation in style of deformation forming the melange fabrics presumably reflected changes in porosity and state of compaction of accreted sediments in a shallow tectonic level.     

Revision of magnitudes of large shallow earthquakes, 1897–1912

In previous research, trace amplitudes of surface wave maxima recorded by undamped Milne seismographs were used to determine the surface-wave magnitudes M_s of large shallow earthquakes which occurred prior to 1912. For this purpose, the effective gain of these instruments was calibrated by using the surface-wave magnitudes M_s(GR) which were calculated from the unpublished worksheets for Seismicity of the Earth of Gutenberg and Richter. In this paper, the real quality of M_s(GR) is critically re-evaluated by using independent sets of data. It is found that M_s(GR) for the period 1904–1909 is considerably overestimated. The average excess from the real M_s is 0.5 units for 1904–1906, 0.4 for 1907, 0.3 for 1908–1909 and 0.0 for 1910–1912. This overestimation is so systematic and large that the previous results are all redetermined. The average effective gain of Milne instruments is revised to be 21.9; previously, the gain depended on M_s. This revision results in systematic reduction in the previously assigned magnitudes. The revised values of M_s for 264 shallow earthquakes, with M_s=6.8 and over in the period 1897–1912 inclusive, are listed. The present revision is large enough to preclude the possibility of the high activity of large shallow earthquakes around the turn of the century. The present results have a direct effect on all the magnitude catalogues of shallow earthquakes which occurred prior to 1909.