Winkler's method overestimates dissolved oxygen in seawater: Iodate interference and its oceanographic implications

Dissolved oxygen in seawater has been determined by using the Winkler's reaction scheme for decades. An interference in this reaction scheme that has been heretofore overlooked is the presence of naturally occurring iodate in seawater. Each mole of iodate can result in an apparent presence of 1.5 mol of dissolved oxygen. At the concentrations of iodate in the surface and deep open ocean, it can lead to an overestimation of 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 of oxygen in these waters respectively. In coastal and inshore waters, the effect is less predictable as the concentration of iodate is more variable. The solubility of oxygen in seawater was likely overestimated in data sources that were based on the Winkler's reaction scheme for the determination of oxygen. The solubility equation of García and Gordon [Garcia H.E., Gordon, L.I., 1992. Oxygen solubility in seawater: Better fitting equations. Limnol. Oceanogr. 37, 1307–1312] derived from the results of Benson and Krause [Benson, F.B., Krause, D. Jr., 1984. The concentration and isotopic fractionation of oxygen dissolved in freshwater and seawater in equilibrium with the atmosphere. Limnol. Oceanogr. 29, 620–632] is free from this source of error and is recommended for general use. By neglecting the presence of iodate, the average global super-saturation of oxygen in the surface oceans and the corresponding efflux of oxygen to the atmosphere both have been overestimated by about 8%. Regionally, in areas where the degree of super-saturation or under-saturation of oxygen in the surface water is small, such as in the tropical oceans, the net air–sea exchange flux can be grossly under- or overestimated. Even the estimated direction of the exchange can be reversed. Furthermore, the presence of iodate can lead to an overestimation of the saturation anomaly of oxygen in the upper ocean attributed to biological production by 0.23 ± 0.07%. AOU may have been underestimated by 0.52 ± 0.15 and 0.63 ± 0.05 μmol kg^− 1 in the surface mixed layer and deep water, while preformed phosphate and preformed nitrate may have been overestimated by 0.004 ± 0.001 and 0.06 ± 0.02 μmol kg^− 1 in the surface mixed layer, and 0.005 ± 0.0004 and 0.073 ± 0.006 μmol kg^− 1 in the deep water. These are small but not negligible corrections, especially in areas where the values of these parameters are small. At the increasing level of sophistication in the interpretation of oxygen data, this source of error should now be taken into account. Nevertheless, in order to avoid confusion, an internationally accepted standard needs to be adopted before these corrections can be applied.     

未饱和砂土含水量GPR反射波法检测研究

未饱和砂土含水量变化会引起介电性质改变,影响土体中电磁波传播速度。利用GPR反射波法测得土体电磁波速后,基于正确的土体介电常数模型可求得含水量,这一过程具有快速、连续、无损特点。为实现目标,以不同粒径组成的3组典型砂土为样品,利用探地雷达反射波法测定其介电常数,研究影响土样介电常数的关键因素和遵循的介电常数模型,讨论基于介电理论的土体含水量求取方法。研究表明粒径级配差异不会引起砂土介电常数较大变化;含水量是决定其介电常数的关键因素,两者关系可采用拟合的Topp或Alharathi型公式表示;砂土介电常数遵循Looyenga混合介电常数模型。研究成果在土方路基含水量连续检测中得到有效应用。     

星座美洲海鞘次级代谢产物的研究

从采自青岛近海的星座美洲海鞘(Amaroucium constellatum)70%乙醇提取物中分离得到9个次级代谢产物.经波谱(MS、NMR)分析和文献比对,确定了它们的化学结构分别为尿嘧啶(1)、胆甾醇(2)、十九碳甘油醚(3)、胸腺嘧啶(4)、反-4-对羟基苯基-3-丁烯-2-酮(5)、反-4-苯基-3-丁烯-2-酮(6)、对胺基苯乙酸(7)、胸腺嘧啶脱氧核苷(8)和N-甲基尿嘧啶核苷(9).其中,化合物2～3,5～7,9均为首次从该海鞘中分离得到.     

印度洋-太平洋暖池海域表层水温分析

利用1951~2003年HadISST资料集的表层海水温度（SST）资料,讨论了印度洋-西太平洋暖池（IPWP）海域,尤其是印度尼西亚贯穿流（ITF）及其周边海域SST的季节及年际变化的时空特征.研究结果表明,整个研究海域SST的年际变化均与ENSO相关,但印度洋与南海的响应特征与西太平洋的相反且不同步.前者海温变化滞后Nio3指数3~6个月,而热带太平洋西边界和ITF流经海域海温则超前1~3个月.沿ITF及其东印度洋出口,SST的年际变化规律不同于热带印度洋而与太平洋的相似,分析表明其在较大程度上受到ITF海洋桥的影响.在季节尺度上,印度洋和太平洋赤道海域SST的波动规律也有明显不同.以巽他岛弧（苏门答腊、爪哇和小巽他群岛）为界,从赤道西太平洋向西沿ITF流径,太平洋一侧SST的季节变化以0.5a周期的波动占主导,印度洋一侧则以1a周期占主导.     

Fully Coupled Effects of Hull, Mooring and Risers Model in Time Domain Based on An Innovative Deep Draft Multi-Spar

The coupled hull, mooring and riser analysis techniques in time domain are widely recognized as the unique approach to predict the accurate global motions. However, these complex issues have not been perfectly solved due to a large number of nonlinear factors, e.g. forces nonlinearity, mooring nonlinearity, motion nonlinearity and so on. This paper investigates the coupled effects through the numerical uncoupled model, mooring coupled model and fully coupled model accounting mooring and risers based on a novel deep draft multi-spar which is especially designed for deepwater in 2009. The numerical static-offset, free-decay, wind-action tests are executed, and finally three hours simulations are conducted under 100-year return period of GOM conditions involving wave, wind and current actions. The damping contributions, response characteristics and mooring line tensions are emphatically studied.     

非线性效应对浅水水波变形的影响

本文采用波数矢量无旋和波能守恒方程建立了一个考虑非线性作用的浅水水波变形数值模型,模型中采用Ｂａｔｔｊｅｓ关系与波数矢量无旋,波能守恒方程一起来求解波浪在浅水中变形的波浪要素,在波能守恒方程中考虑了底摩擦的影响。利用本文提出的数值模型对一个斜坡浅滩水域波浪折射绕射现象进行了验证,验证计算中用一个非线性经验弥散关系近似浅水水波变形的非线性效应并与用线性弥散关系的计算结果进行了比较,结果说明使用非线性     

“联合国教科文组织中国海洋生物工程中心”简介

BRIEFINTRODUCTIONONTHECHINESECENTEROFMARINEBIOTECHNOLOGY/UNESCOLIJunQIZi－zhong(CollegeofMarineLife,OceanUniversityofQingdao,Qingdao,266003)1995年初,联合国教科文组织生物工程委员会决定在世界范围内挑选和资助建立5个地区性“植物与水生生物工程中。乙”,以促进发展中国家的科学发展与进步。联合国教科文组织生物工程委员会主席DrIndfaKVasil教授通知青岛海洋大学海洋生命学院徐怀恕教授提交工作计划。联合国教科文组织生命学部召开会议讨论通过了中国的活动计划书,决定在青岛海洋大学成立…     

论海水养殖的养殖容量

养殖容量应是一个包含环境、生态和经济等诸多因素的综合概念。养殖容量可定义为：单位水体内在保护环境、节约资源和保证应有效益等各个方面都符合可持续发展要求的最大养殖量。合理地利用养殖容量就是要形成一个结构优化和功能高效的养殖生态系统,使所投入的物质得到反复循环、初级生产力得到多途径利用,从而提高生产效益和养殖效益,避免物质的浪费及自身和环境的污染。从养殖生态系统运转的驱动因素来分析,主要靠太阳辐射直接提供能源的系统,如海带养殖系统、扇贝筏式养殖系统等,可称为自养型或自然营养型养殖系统;主要靠人工投饲来提供能源的系统,如对虾池塘养殖系统、吃食性鱼类网箱养殖系统等,可称为异养型或人工营养型养殖系统。这两类养殖系统在生态学上有很多互补性,它们的复合可提高养殖水体的养殖容量。     

南沙群岛珊湖礁潟湖垂直沉降颗粒物中主要元素的生物地球化学过程研究

本文首次报道用沉积物捕捉器（ＳＴ）研究南沙群岛珊瑚礁湖沉降颗粒物中主要元素垂直通量、垂直转移形态、再循环过程及垂直通量与表层海水温度的关系。结果显示,作为生物化学沉积标志的Ｃａ、Ｍｇ具有最高的垂直通量,达１．４和０．１ｇ／（ｍ２·ｄ）以上,作为生物富集标志的Ｂｒ、Ⅰ也有较高的垂直转移量;垂直转移形态的研究表明Ｎａ、Ｋ、Ｃａ、Ｍｇ、Ｓｒ主要以碳酸盐结合态向海底转移,其中Ｃａ、Ｍｇ、Ｓｒ占９９％以上,Ｆｅ、Ｉ、Ｂａ主要以铁锰氧化物结合态向海底输送,在垂直沉降颗粒物到达海底后,有相当部分的主要元素可再循环进入水体中,Ｂｒ、Ｉ、Ｋ、Ａｌ的绝大部分进入再循环,Ｍｇ、Ｎａ、Ｃｌ有一半左右进入再循环,Ｃａ、Ｓｒ、Ｂａ、Ｆｅ大部分被埋葬;Ｎａ等９种元素的垂直转移量随ＳＳＴ呈指数降低响应,对ＳＳＴ的敏感性Ｆｅ＞Ｂｒ＞Ｓｒ＞Ｃａ＞Ｎａ＞Ｃｌ＞Ｍｇ＞Ｉ＞Ａｌ,这再一次验证了ＣａＣＯ３随温度升高,其溶解度降低、化学沉积量增加这一自然界的普遍规律,表明在珊瑚礁海水的垂直沉降颗粒物中主要元素是作为珊瑚的重要成分与ＣａＣＯ３一同被沉积下来的,ＣａＣＯ３起到稀释剂的作用。